1,12-diisocyanato-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10-hexadecafluorododecane | 130869-09-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1,12-diisocyanato-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10-hexadecafluorododecane
• 英文别名: 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10-Hexadecafluoro-1,12-diisocyanatododecane
• CAS: 130869-09-9
• 化学式: C₁₄H₈F₁₆N₂O₂
• 分子量: 540.204
• InChiKey: VTABSFVPBBZSMU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.9
• 重原子数：
  34
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  58.9
• 氢给体数：
  0
• 氢受体数：
  20

反应信息

• 作为产物：
  描述：

  光气 、 1,12-diamino-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10-hexadecafluorododecane dihydrochloride 以 邻二氯苯 为溶剂， 反应 2.0h， 以55%的产率得到1,12-diisocyanato-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10-hexadecafluorododecane
  参考文献：
  名称：

  Synthesis of fluorinated diisocyanates

  摘要：

  Fluorinated diisocyanates of the general structure OCN(CH2)2(CF2)n(CH2)2NCO were prepared from alpha,omega-diiodoperfluoroalkanes by insertion of ethylene into the CF2-I bond, displacement of the iodo groups with azide, reduction of the resulting azide groups to amines, and phosgenation of the diamine.

  DOI：

  10.1021/jo00009a021

文献信息

• Fluorinated reactive compositions for golf balls
  申请人：Rajagopalan Murali

  公开号：US20060199937A1

  公开（公告）日：2006-09-07

  A golf ball is disclosued, comprising: a core, the core having a diameter of 1.5 inches to 1.65 inches and a first coefficient of restitution of 0.8 or greater at 125 ft/s; an intermediate layer disposed about the core, the intermediate layer having a first Shore D hardness of 20 to 80 and comprising a blend of two or more ionomers; and an outer cover layer disposed about the intermediate layer; the outer cover layer having a thickness of 0.005 inches to 0.05 inches and a second Shore D hardness of 30 to 70, the outer cover layer being composed of a castable material formed from reactants comprising at least one fluorinated polyfunctional compound, wherein the golf ball has a second coefficient of restitution of 0.8 or greater at 125 ft/s and a compression of 50 to 120.
• US4942164A
  申请人：——

  公开号：US4942164A

  公开（公告）日：1990-07-17
• US7312298B2
  申请人：——

  公开号：US7312298B2

  公开（公告）日：2007-12-25
• US7358320B2
  申请人：——

  公开号：US7358320B2

  公开（公告）日：2008-04-15
• Synthesis of fluorinated diisocyanates
  作者：A. A. Malik、D. Tzeng、P. Cheng、K. Baum

  DOI：10.1021/jo00009a021

  日期：1991.4

  Fluorinated diisocyanates of the general structure OCN(CH2)2(CF2)n(CH2)2NCO were prepared from alpha,omega-diiodoperfluoroalkanes by insertion of ethylene into the CF2-I bond, displacement of the iodo groups with azide, reduction of the resulting azide groups to amines, and phosgenation of the diamine.