2-Octyl-7-phenyl-benzo[d][1]benzothieno[3,2-b]thiophene [for organic electronics]

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻吩类
• 英文名称: 2-Octyl-7-phenyl-benzo[d][1]benzothieno[3,2-b]thiophene [for organic electronics]
• 英文别名: 7-octyl-2-phenyl-[1]benzothiolo[3,2-b][1]benzothiole
• 化学式: C₂₈H₂₈S₂
• 分子量: 428.662
• InChiKey: JNKNXBSGHUYBAT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.1
• 重原子数：
  30
• 可旋转键数：
  8
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  56.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  苯并[B]苯并[4,5]噻吩并[2,3-D]噻吩 在 aluminum (III) chloride 、 四(三苯基膦)钯 、 sodium chloride dihydrate 、 三叔丁基膦 、 溴 、 potassium carbonate 、 potassium hydroxide 作用下， 以 1,4-二氧六环 、 二氯甲烷 、 氯仿 、 水 、 二乙二醇 为溶剂， 反应 15.25h， 生成 2-Octyl-7-phenyl-benzo[d][1]benzothieno[3,2-b]thiophene [for organic electronics]
  参考文献：
  名称：

  ２，７置換［１］ベンゾチエノ［３，２−ｂ］［１］ベンゾチオフェン誘導体の製造方法

  摘要：

  当前情况是，尚不清楚有机半导体中非常有用的、具有不同取代基的2,7-置换[1]苯并噻吩[3,2-b][1]苯并噻吩衍生物的高效制备方法。因此，本发明的课题在于提供2,7-置换[1]苯并噻吩[3,2-b][1]苯并噻吩衍生物的高效制备方法。通过将苯并噻吩[3,2-b][1]苯并噻吩进行卤代反应，然后进行偶联反应，再经酰化反应，最后进行还原反应，找到了解决本发明课题的方法，从而完成了本发明。

  公开号：

  JP2015129098A

文献信息

• NOVEL COMPOUND AND SEMICONDUCTOR MATERIAL CONTAINING SAME
  申请人：DIC Corporation

  公开号：US20190077732A1

  公开（公告）日：2019-03-14

  There is provided a compound which provides a semiconductor material. The compound is represented by General Formula (1) wherein Ar represents an aryl group which may have a substituent or a heteroaryl group which may have a substituent, and R 1 represents an acyclic alkyl group having 1 to 20 carbon atoms wherein hydrogen atom in the alkyl group may be replaced by a halogeno group, a nitrile group or an aryl group, and —CH 2 — in the alkyl group may be replaced by —O—, —R′C═CR′—, —CO—, —OCO—, —COO—, —S—, —SO 2 —, —SO—, —NH—, —NR′— or —C≡C— provided that, with respect to each of an oxygen atom, a sulfur atom and a nitrogen atom, the same atoms are not directly bonded to each other, wherein R′ represents an acyclic or cyclic alkyl group having 1 to 20 carbon atoms.

  提供了一种化合物，可提供半导体材料。该化合物由通式（1）表示，其中Ar代表可能具有取代基的芳基基团或可能具有取代基的杂环基团，而R1代表具有1到20个碳原子的非环状烷基基团，其中烷基基团中的氢原子可以被卤素基团、腈基团或芳基基团取代，而烷基基团中的—CH2—可以被—O—、—R′C═CR′—、—CO—、—OCO—、—COO—、—S—、—SO2—、—SO—、—NH—、—NR′—或—C≡C—取代，前提是针对每个氧原子、硫原子和氮原子，相同的原子不能直接相连，其中R′代表具有1到20个碳原子的非环状或环状烷基基团。
• Compound and semiconductor material containing same
  申请人：DIC Corporation

  公开号：US11352308B2

  公开（公告）日：2022-06-07

  There is provided a compound which provides a semiconductor material. The compound is represented by General Formula (1) wherein Ar represents an aryl group which may have a substituent or a heteroaryl group which may have a substituent, and R1 represents an acyclic alkyl group having 1 to 20 carbon atoms wherein hydrogen atom in the alkyl group may be replaced by a halogeno group, a nitrile group or an aryl group, and —CH2— in the alkyl group may be replaced by —O—, —R′C═CR′—, —CO—, —OCO—, —COO—, —S—, —SO2—, —SO—, —NH—, —NR′— or —C≡C— provided that, with respect to each of an oxygen atom, a sulfur atom and a nitrogen atom, the same atoms are not directly bonded to each other, wherein R′ represents an acyclic or cyclic alkyl group having 1 to 20 carbon atoms.

  本发明提供了一种可用作半导体材料的化合物。该化合物由通式（1）表示 其中 Ar 代表可具有取代基的芳基或可具有取代基的杂芳基，R1 代表具有 1 至 20 个碳原子的无环烷基，其中烷基中的氢原子可被卤代基、腈基或芳基取代，烷基中的-CH2-可被-O-取代、-R′C═CR′-、-CO-、-OCO-、-COO-、-S-、-SO2-、-SO-、-NH-、-NR′-或-C≡C-取代，条件是对于氧原子、硫原子和氮原子中的每一个，相同的原子彼此不直接结合，其中R′代表具有1至20个碳原子的无环或环状烷基。
• ORGANIC THIN FILM, AND ORGANIC SEMICONDUCTOR DEVICE AND ORGANIC TRANSISTOR USING SAME
  申请人：DIC CORPORATION

  公开号：US20160049596A1

  公开（公告）日：2016-02-18

  The present invention provides an organic thin film and an organic transistor having high performance stability and mobility. Specifically, there are provided an organic thin film including a compound containing a charge transporting molecular unit A having a structure of an aromatic fused ring system and a unit B serving as a side chain, the compound having a bilayer structure; an organic semiconductor device including the organic thin film; and an organic transistor including the organic thin film used as an organic semiconductor layer.