11,23-Dimethyl-3,7,15,19-tetrazatricyclo[19.3.1.19,13]hexacosa-1(24),9,11,13(26),21(25),22-hexaene-25,26-diol | 103776-07-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 11,23-Dimethyl-3,7,15,19-tetrazatricyclo[19.3.1.19,13]hexacosa-1(24),9,11,13(26),21(25),22-hexaene-25,26-diol
• CAS: 103776-07-4
• 化学式: C₂₄H₃₆N₄O₂
• 分子量: 412.575
• InChiKey: YCBVLNLTRPTDQD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  30
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  88.6
• 氢给体数：
  6
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  11,23-Dimethyl-3,7,15,19-tetrazatricyclo[19.3.1.19,13]hexacosa-1(24),9,11,13(26),21(25),22-hexaene-25,26-diol 在 triethylamine 作用下， 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  Macrocyclic oxovanadium(IV) complexes: structure, magnetochemistry and electrochemistry

  摘要：

  The oxovanadium(IV) complexes, [VO(L)].H2O 1, [VO(H2L)(SO4)].3H2O 2, [(VO)2L(mu-SO4)]-MeOH.3H2O 3 and [Zn(L)VO(SO4)].4H2O 4 have been synthesised from the dinucleating tetraaminodiphenol macrocyclic ligand H2L. The ESR and IR spectra of 1 have indicated stacking of the molecules due to ... V=O ... V=O ... interactions. In complexes 2 and 4 the unidentate sulfate is bound to the octahedral vanadium and two of the secondary amino groups in 2 are protonated. Both of these complexes undergo oxidation to produce oxovanadium(V) species with E1/2 = 0.40 V (2), 0.455 V (4) vs. saturated calomel electrode (SCE). Fairly strong antiferromagnetic exchange interaction has been found in 3 from variable-temperature susceptibility measurements, J = -1 28 cm 1. The crystal structure of 3 has been determined; tetragonal, space group P4(1)22, a = b = 1 2.252(2), c = 40.819(5) angstrom and Z = 8; refinement led to R = 0.053 and R' = 0.055 using 1825 unique reflections with I > 3sigma(I). The two octahedral vanadium centres in the complex, separated by 3.077 angstrom, are bridged by sulfate and have syn oxo configuration.

  DOI：

  10.1039/dt9930002241
• 作为产物：
  描述：

  11,23-Dimethyl-3,7,15,19-tetrazatricyclo[19.3.1.19,13]hexacosa-1(24),2,7,9,11,13(26),14,19,21(25),22-decaene-25,26-diol 在 sodium tetrahydroborate 作用下， 以 甲醇 为溶剂， 生成 11,23-Dimethyl-3,7,15,19-tetrazatricyclo[19.3.1.19,13]hexacosa-1(24),9,11,13(26),21(25),22-hexaene-25,26-diol
  参考文献：
  名称：

  通过改变孔的大小形成混合的自旋态大环二镍（II）配合物

  摘要：

  两个四氨基二酚大环配体的双核镍（II）配合物，其中一个（H 2 L 1）具有两个–NH（CH 2）3 NH–单元，另一个（H 2 L 2）包含一个–NH（CH 2）3已研究了NH–和一个–NH（CH 2）2 NH–部分。夹杂物中的[Ni 2 L 1（H 2 O）4 ] [ClO 4 ] 2 ·4NH 2 CONH 2 1，两个金属中心均为八面体配置。与吡啶（py）反应时，配合物1转变为方形-金字塔形的配合物[Ni 2 L 1（py）2 ] [ClO 4 ] 2。大环H 2 L 2形成混合自旋络合物[Ni 2 L 2（H 2 O）2 ] I 2 2，其中一个金属中心为正方形，另一金属中心为八面体。与吡啶反应时，配合物2产生正方形-平面-正方形-金字塔形的配合物[Ni 2 L 2（py）] I 24; 低自旋的Ni 2+的两个2和4由更小的收纳Ñ 2 Ó 2由酚氧和-NH（CH提供空腔2）2

  DOI：

  10.1039/dt9930002515

文献信息

• Hydroxide-bridged diiron(III) complexes of tetraaminodiphenol macrocyclic ligands: structure and properties
  作者：Kausik K. Nanda、Sujit K. Dutta、Sujoy Baitalik、Krishnan Venkatsubramanian、Kamalaksha Nag

  DOI：10.1039/dt9950001239

  日期：——

  Some dinuclear iron(III) complexes derived from two tetraaminodiphenol macrocyclic ligands, one (H2L1) contains two –NH(CH2)3NH– and the other (H2L2) one –NH(CH2)3NH– and one –NH(CH2)2NH– units, and an acyclic tetradentate ligand H2L3N,N′-bis(2-hydroxybenzyl)-1,3-diaminopropane} have been synthesised and studied. In all of the macrocyclic complexes [Fe2(µ-OH)2(HL1)2][ClO4]21, [Fe2(µ-OH)2L12]·2H2O

  Some dinuclear iron(III) complexes derived from two tetraaminodiphenol macrocyclic ligands, one (H2L1) contains two –NH(CH2)3NH– and the other (H2L2) one –NH(CH2)3NH– and one –NH(CH2)2NH– units, and an acyclic tetradentate ligand H2L3N,N′-bis(2-hydroxybenzyl)-1,3-diaminopropane} have been synthesised and studied. In all of the macrocyclic complexes [Fe2(µ-OH)2(HL1)2][ClO4]21, [Fe2(µ-OH)2L12]·2H2O
• Design and Synthesis of Compartmental Ligands and their Complexes for the Production of Catalytic Antibodies
  作者：Séverine Duclos、Helen Stoeckli-Evans、Thomas R. Ward

  DOI：10.1002/1522-2675(20011017)84:10<3148::aid-hlca3148>3.0.co;2-w

  日期：2001.10.17

  were designed to mimic transition-state analogs for the production of catalytic antibodies for C−H activation reactions. Reaction of 8 with vanadyl cations yields the dinuclear complex 9, which was characterized by X-ray crystallography. Amputated ligands 17 and 18 react with various transition-metal cations to yield complexes designed to act as coenzymes for the catalytic antibodies. The Ni complex

  描述了混合 N、O 配体的合成和配位特性。大环配体 8 和 15 旨在模拟过渡态类似物，用于生产用于 C-H 活化反应的催化抗体。8 与氧钒阳离子反应产生双核配合物 9，其特征在于 X 射线晶体学。截断的配体 17 和 18 与各种过渡金属阳离子反应生成复合物，用作催化抗体的辅酶。17 (19) 的 Ni 配合物也通过 X 射线晶体学进行了结构表征。
• Macrocyclic dimeric vanadium(<scp>IV</scp>) and heterodinuclear vanadium(<scp>IV</scp>)–nickel(<scp>II</scp>) complexes. Structure, magnetic, electronic and redox properties
  作者：Sasankasekhar Mohanta、Kausik K. Nanda、Soma Ghosh、Monika Mukherjee、Madeleine Helliwell、Kamalaksha Nag

  DOI：10.1039/dt9960004233

  日期：——

  The oxovanadium(IV) complexes [VO(H2L1)}2(µ-SO4)][NO3]2, [(VO)L1Ni(H2O)2(SO4)]·H2O and [(VO)L1Ni(µ-SO4)(H2O)]·2H2O have been synthesized from the dinucleating tetraaminodiphenol macrocycle H2L1. The crystal structure of the first, in which two unco-ordinated amino nitrogens are protonated, has been determined. The two distorted-octahedral vanadium centres in the complex, separated by 6.741(4)Å, are

  氧钒（IV）络合物[VO（H 2 L 1）} 2（µ-SO 4）] [NO 3 ] 2，[（VO）L 1 Ni（H 2 O）2（SO 4）]·H 2 O和[（VO）L- 1的Ni（μ-SO 4）（H 2 O）]·2H 2 O，使其脱离dinucleating tetraaminodiphenol大环化合物H与被合成2大号1。已经确定了其中两个未配位的氨基氮被质子化的第一个的晶体结构。络合物中的两个扭曲的八面体钒中心被6.741（4）Å隔开，被硫酸盐桥接并具有抗氧羰基构型。在固态下，随着温度从299 K降低到5 K，该钒的络合物的磁矩从1.71降低到1.64 µ B，这表明分子间/分子间的相互作用非常弱。然而，它在流体溶液和玻璃中的ESR光谱表明不存在VO⋯VO电子自旋相互作用。该配合物经过逐步氧化，生成具有E的VO IV VO V和VO V VO V物质。1/2（1）= 0.445 V和ë
• Dicopper(<scp>II</scp>,<scp>II</scp>) and dicopper(<scp>I</scp>,<scp>II</scp>) complexes of a series of dinucleating macrocycles
  作者：Hisashi Ōkawa、Makoto Tadokoro、Yuichiro Aratake、Masaaki Ohba、Kenji Shindo、Minoru Mitsumi、Masayuki Koikawa、Mie Tomono、David E. Fenton

  DOI：10.1039/dt9930000253

  日期：——

  between the copper(II) ions within each complex (J based on ℋ=–2JS1S2 in the range –345 to –255 cm–1). The cyclic voltammograms show two reduction couples, CuIICuII–CuICuII and CuICuII–CuICuI. The comproportionation constants Kcom for the mixed-valence CuICuII complexes have been determined electrochemically. The Kcom value increase in the order of the macrocycles (L2,3)2– < (L2,4)2– < (L2,5)2– and (L3

  所述大环化合物dinucleatingħ 2大号米，Ñ通过两个烷烃链结合含有两个2,6-二（氨基甲基）-4-甲基苯酚的实体，（CH 2）米和（CH 2）Ñ，在胺氮已被用于制备（m，n）设置（2,3），（2,4），（2,5），（3,3）和（3,4）。已经制备了具有通式[Cu 2 L m，n ] [ClO 4 ] 2的双核铜（II）配合物。低温磁研究（80–300 K）显示，铜之间有很强的反铁磁自旋交换（II）每个络合物中的离子（J基于ℋ= –2 JS 1 S 2在–345至–255 cm –1范围内）。循环伏安显示两个减少夫妻，铜II铜II -Cu我铜II和Cu我铜II -Cu我的Cu我。混合价Cu I Cu II配合物的配位常数K com已通过电化学方法确定。所述ķ COM在大环化合物的顺序值增加（L 2,3）2– <（L 2,4）2– <（L 2,5）2–和（L 3,3）2– <（L 3
• CATHODE CATALYST FOR AIR SECONDARY BATTERY AND AIR SECONDARY BATTERY
  申请人：Koshino Nobuyoshi

  公开号：US20140066290A1

  公开（公告）日：2014-03-06

  The present invention provides a cathode catalyst for an air secondary cell having both excellent oxygen reduction activity and excellent water oxidation activity, and an air secondary cell that uses the catalyst. The present invention relates to a cathode catalyst for an air secondary cell in which the catalyst contains a polynuclear metal complex.

  本发明提供了一种空气二次电池的阴极催化剂，具有优异的氧还原活性和优异的水氧化活性，并且使用该催化剂的空气二次电池。本发明涉及一种空气二次电池的阴极催化剂，其中该催化剂包含多核金属配合物。