2-Hydroxyethyl-dimethyl-octadecylazanium | 45280-10-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 2-Hydroxyethyl-dimethyl-octadecylazanium
• CAS: 45280-10-2
• 化学式: C22H48NO+
• 分子量: 342.6
• InChiKey: KDOKFXJQGPCGLT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.4
• 重原子数：
  24
• 可旋转键数：
  19
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

文献信息

• GLYPHOSATE DIMETHYLAMINE SALT CRYSTAL, PREPARATION METHOD AND USE THEREOF
  申请人：Wang Wei

  公开号：US20150307528A1

  公开（公告）日：2015-10-29

  This invention provides the herbicidal active ingredient, a dimethylamine salt crystal of N-phosphonomethyl glycine (glyphosate), its preparation process and a solid formulation containing the crystalline dimethylamine salt of glyphosate as well as its application. Said preparation process comprises adding glyphosate and a suitable amount of solvent into a conventional reactor and introducing a dimethylamine gas for reaction, wherein the reaction temperature is controlled between 5 and 90° C. After the completion of the reaction, the temperature is reduced slowly to a certain value, a crystalline dimethylamine salt of glyphosate is precipitated (or precipitated after a crystal seed is added).

  本发明提供了除草活性成分，即N-磷酸甲基甘氨酸（草甘膦）的二甲胺盐晶体，其制备过程和含有草甘膦二甲胺盐晶体的固体配方以及其应用。所述制备过程包括将草甘膦和适量的溶剂加入常规反应器中，并引入二甲胺气体进行反应，其中反应温度在5至90°C之间控制。反应完成后，温度缓慢降至一定值，沉淀出草甘膦的二甲胺盐晶体（或在添加晶种后沉淀）。
• The production of haploid seed, of doubled haploids and of homozygous plant lines therefrom
  申请人：CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS)

  公开号：EP0127313A1

  公开（公告）日：1984-12-05

  In a process for producing haploid seed haploids are induced in an angiosperm by applying an apomixic agentto a plant at a time which is between the occurrence of flower initiation and anthesis in an amount sufficient to cause apomixis, allowing the plant to produce seed and collecting from the seed, viable, haploid seed. The process may be used to produce doubled haploids in an angiosperm by further growing the haploid seed in an environment which fosters the development of the embryo into a plant which is capable of producing doubled haploid seed. The process enables homozygous plant lines to be obtained. The process may usefully be applied to cereal grain and forage crop plants.

  在一种生产单倍体种子的工艺中，通过在植物开花和开花之间的时间向植物施用足以引起凋萎的凋萎剂，使植物产生种子并从种子中收集有活力的单倍体种子，从而在被子植物中诱导单倍体。该过程可用于在被子植物中产生加倍单倍体，具体方法是让单倍体种子在一种能促进胚胎发育成能产生加倍单倍体种子的植物的环境中进一步生长。这一过程可以获得同源植物品系。 该过程可用于谷物和饲料作物。
• Novel herbicidal substituted pyridyl phenyl and diphenyl ethers, herbicidal compositions containing them, processes for the preparation thereof and the use thereof for combating weeds
  申请人：ROHM AND HAAS COMPANY

  公开号：EP0130041A1

  公开（公告）日：1985-01-02

  The novel ethers are of those having two aromatic rings attached to the ether oxygen atom and having a substituted amino group attached to a phenyl ring and are characterized as being of the formula: wherein Q is a group of the formula X' is a hydrogen atom, a cyano group, or a halogen atom; X2 is a haloalkyl group or a halogen atom, X3 is a hydrogen atom or a halogen atom; Y is a nitro group, a cyano group, or a halogen atom; R is a group of the formula R' and R2, independently of each other and in each (CHR') and (CHR2) group, are a hydrogen atom, an unsubstituted or substituted (C,-C.) alkyl group, a (C1-C6) alkoxy group, or a (C1-C6) alkylthio group, provided that R' and R2 may not be alkoxy or alkylthio alpha to an -NH- moiety; A is -N(R1)-, -N(O)-, -0-, -S-, -S(O)-, -S(0)2, -C(O)-, -C(O)B-, or -N(H)S(O)2-; B is a straight- or branched-chain (C1-C6) alkylene group, -O-, -S-, or -N(R4)-; R3 is a cyano group, a halogen atom, or a group of the formula -C(O)Z; R4 is a hydrogen atom or an unsubstituted or substituted (C1-C5) alkyl group; Z is a hydrogen atom, an unsubstituted or substituted (C1-C6) alkyl group, -N(R')2, -OR', -SR5, or -N(R4)SO2R6; R5 is a hydrogen atom, an unsubstituted or substituted (C1-C6) alkyl group or an agronomically-acceptable cation; R6 is an unsubstituted (C1-C5) alkyl group, a hydroxy group or an agronomically-acceptable salt formed with such group, an unsubstituted or substituted phenyl group with up to three substituents which can be the same or different and are selected from chlorine, bromine, fluorine, (C1-C5) alkoxy and (C1-C5) alkyl which alkyl group is unsubstituted or substituted with up to three substituents which can be the same or different and are selected from chlorine, bromine, and (C1-C5) alkoxy; m is an integer from 2 to 10; and n is an integer from 1 to 3; and wherein when R1, R2, R4, or R5 is substituted alkyl group, there can be up to three substituents which can be the same or different and are selected from chlorine, bromine, fluorine, hydroxy, (C1-C6) alkoxy, (C1-C6) alkylthio, (C1-C6) alkylcarbonyl (C1-C6) alkoxycarbonyl, amino, mono- or di-(C,-Cs) alkylamino, (C1-C6) alkylcarbonyloxy and unsubstituted or substituted phenyl, phenoxy, or phenylthio each of these aromatic groups having up to three substituents which can be the same or different and are selected from chlorine, bromine, fluorine, hydroxy, (C1-C6) alkoxy, (C1-C6) alkylthio and (C1-C6) alkyl which is unsubstituted or substituted with up to three substituents which can be the same or different and are selected from chlorine, bromine, fluorine, hydroxy and (C,-C.) alkoxy.

  新型醚类是那些在醚氧原子上连接有两个芳香环并在苯环上连接有一个取代氨基的醚类，其特征在于它们具有以下式子： 其中 Q 是式中的基团 X'是氢原子、氰基或卤素原子； X2 是卤代烷基或卤原子 X3 是氢原子或卤素原子； Y 是硝基、氰基或卤素原子； R 是式中的一个基团 R'和 R2 相互独立且在每个 (CHR') 和 (CHR2) 基团中为氢原子、未取代或取代的 (C,-C.) 烷基、(C1-C6) 烷氧基或 (C1-C6) 烷硫基，条件是 R' 和 R2 不得是烷氧基或烷硫基α-NH-分子； A 是-N(R1)-、-N(O)-、-0-、-S-、-S(O)-、-S(0)2、-C(O)-、-C(O)B- 或-N(H)S(O)2-； B 是直链或支链（C1-C6）亚烷基、-O-、-S-或-N(R4)-； R3 是氰基、卤素原子或式 -C(O)Z 的基团； R4 是氢原子或未取代或取代的（C1-C5）烷基； Z 是氢原子、未取代或取代的 (C1-C6) 烷基、-N(R')2、-OR'、-SR5 或 -N(R4)SO2R6； R5 是氢原子、未取代或取代的 (C1-C6) 烷基或农艺学上可接受的阳离子； R6是未取代的(C1-C5)烷基、羟基或与此类基团形成的农艺学上可接受的盐、未取代的或取代的苯基，其最多有三个取代基，这些取代基可以相同或不同，选自氯、溴、氟、(C1-C5)烷氧基和(C1-C5)烷基，其中烷基未被取代或被最多三个取代基取代，这些取代基可以相同或不同，选自氯、溴和(C1-C5)烷氧基； m 是 2 到 10 的整数；以及 n 是 1 至 3 的整数；其中 当 R1、R2、R4 或 R5 为取代的烷基时，最多可以有三个取代基，这些取代基可以相同或不同，选自氯、溴、氟、羟基、（C1-C6）烷氧基、（C1-C6）烷硫基、（C1-C6）烷基羰基（C1-C6）烷氧基羰基、氨基、单-或二-（C,-Cs）烷基氨基、（C1-C6）烷基羰氧基和未取代或取代的苯基、苯氧基、或苯硫基，其中每个芳香基团最多有三个取代基，取代基可以相同或不同，选自氯、溴、氟、羟基、（C1-C6）烷氧基、（C1-C6）烷硫基和未取代或被最多三个取代基取代的（C1-C6）烷基，取代基可以相同或不同，选自氯、溴、氟、羟基和（C,-C.)烷氧基。
• Herbicidally active enols
  申请人：ROHM AND HAAS COMPANY

  公开号：EP0213892A2

  公开（公告）日：1987-03-11

  Eriols having the formula wherein A, B, O, V and W are as defined herein, their geometric isomers and tautomers, halogen addition products thereof, and agriculturally acceptable salts of the foregoing and compositions containing these compounds, exhibit herbicidal activity.

  具有以下式子的烯醇 其中 A、B、O、V 和 W 如本文所定义，它们的几何异构体和同素异形体、它们的卤素加成产物，以及上述化合物的农业上可接受的盐和含有这些化合物的组合物具有除草活性。
• Insecticidal 6-aryl-pyridine thiosemicarbazones
  申请人：ROHM AND HAAS COMPANY

  公开号：EP0243101A2

  公开（公告）日：1987-10-28

  6-aryl-pyrdine-thiosemicarbazones of the formula where R1 is hydrogen or methyl; R2 is (C1-C4)alkyl; R3 is (C1-C4)alkyl; or R2 and R3 may be taken together with the nitrogen atom to which they are attached to form a 3 to 6 membered heterocycle having 2 to 5 nuclear carbon atoms; X is halo, nitro, (C1-C4)alkyl, (C1-C4)haloalkyl or (C1-C4)alkoxy; Y is hydrogen, halo, N02, (C1-C4)alkyl or (C1-C4) alkoxy; or when two adjacent positions on the phenyl ring are substituted with alkoxy groups, these alkoxy groups may be joined to form, together with the carbon atoms to which they are attached, a dioxolano or dioxano heterocyclic ring; n is 0, 1 or 2; and agronomically acceptable salts thereof are useful as insecticides especially against insects from the order Lepidoptera.

  式中的 6-芳基吡啶-硫代氨基甲酸盐 式中 R1 是氢或甲基 R2 是(C1-C4)烷基 R3是(C1-C4)烷基；或 R2和R3可与它们所连接的氮原子一起 或 R2 和 R3 可与它们所连接的氮原子一起形成具有 2 至 5 个核碳原子的 3 至 6 分子杂环； X 是卤代、硝基、(C1-C4)烷基、(C1-C4)卤代烷基或(C1-C4)烷氧基； Y 是氢、卤素、N02、(C1-C4)烷基或 (C1-C4) 烷氧基；或者，当苯基环上的两个相邻位置被烷氧基取代时，这些烷氧基可与其所连接的碳原子一起形成二氧杂环或二氧杂环； n 为 0、1 或 2； 及其农艺学上可接受的盐类可用作杀虫剂，特别是对付鳞翅目昆虫。