5,5'-bis-(1-methyl-1-phenyl-ethyl)-2,2'-thiophene-2,5-diyl-bis-benzooxazole | 65999-94-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并恶唑类
• 英文名称: 5,5'-bis-(1-methyl-1-phenyl-ethyl)-2,2'-thiophene-2,5-diyl-bis-benzooxazole
• 英文别名: 2,2'-Thiene-2,5-diylbis[5-(2-phenylpropan-2-yl)-1,3-benzoxazole]；5-(2-phenylpropan-2-yl)-2-[5-[5-(2-phenylpropan-2-yl)-1,3-benzoxazol-2-yl]thiophen-2-yl]-1,3-benzoxazole
• CAS: 65999-94-2
• 化学式: C₃₆H₃₀N₂O₂S
• 分子量: 554.712
• InChiKey: LMUHJAGEJKLICH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.3
• 重原子数：
  41
• 可旋转键数：
  6
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  80.3
• 氢给体数：
  0
• 氢受体数：
  5

文献信息

• Organic electroluminescent devices having improved power conversion efficiencies
  申请人：EASTMAN KODAK COMPANY (a New Jersey corporation)

  公开号：EP0120673A2

  公开（公告）日：1984-10-03

  Electroluminescent devices are disclosed comprising a hole-injecting zone and an adjacent organic luminescent zone, having a combined thickness no greater than about 1 micron, which have a power conversion efficiency of at least 9 x 10-5 w/w. Preferred electron-transporting compounds for the luminescentzone provide a maximum electroluminescent quantum efficiency of at least 5 ×10-4 photons/electron when tested as described.

  已公开的电致发光器件包括一个空穴注入区和一个相邻的有机发光区，其总厚度不超过约 1 微米，功率转换效率至少为 9 x 10-5 w/w。用于发光区的优选电子传递化合物在进行所述测试时，可提供至少 5 ×10-4 光子/电子的最大电致发光量子效率。
• Electroluminescent device with modified thin film luminescent zone
  申请人：EASTMAN KODAK COMPANY (a New Jersey corporation)

  公开号：EP0281381A2

  公开（公告）日：1988-09-07

  An electroluminescent device is disclosed having a luminescent zone of less than one µm in thickness comprised of an organic host material capa­ble of sustaining hole-electron recombination and a fluorescent material capable of emitting light in response to energy released by hole-electron recombi­nation.

  本发明公开了一种电致发光器件，该器件具有厚度小于 1 微米的发光区，发光区由能够维持空穴-电子重组的有机主材料和能够响应空穴-电子重组释放的能量而发光的荧光材料组成。
• An electroluminescent element
  申请人：ASAHI KASEI KOGYO KABUSHIKI KAISHA

  公开号：EP0532798A1

  公开（公告）日：1993-03-24

  Disclosed is an electroluminescent element comprising an anode, a cathode and, disposed therebetween, an organic luminescent layer comprising a mixture of a fluorescent luminescent agent, at least one hole moving and donating agent capable of moving holes and donating the same to the luminescent agent and at least one electron moving and donating agent capable of moving electrons and donating the same to the luminescent agent. In the element, the components of the luminescent layer have specific oxidation potential and reduction potential relationships. The element emits light in response to electrical signals. The element exhibits high luminescence efficiency and brightness even at low voltages, and it can efficiently be produced at low cost.

  本发明公开了一种电致发光元件，该元件包括阳极、阴极和置于其间的有机发光层，有机发光层包括荧光发光剂、至少一种能够移动空穴并将空穴捐献给发光剂的空穴移动和捐献剂以及至少一种能够移动电子并将电子捐献给发光剂的电子移动和捐献剂的混合物。在元件中，发光层的各组分具有特定的氧化电位和还原电位关系。该元件在电信号的作用下发光。这种元件即使在低电压下也能表现出很高的发光效率和亮度，而且能以低成本高效生产。
• ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0548366A1

  公开（公告）日：1993-06-30

  An organic electroluminescent element with high luminance, high light emission efficiency and long service life, comprising a specified oxadiazole or thiadiazole compound, and usable effectively in the field of chemical industry.

  一种具有高亮度、高发光效率和长使用寿命的有机电致发光元件，由特定的噁二唑或噻二唑化合物组成，可有效用于化学工业领域。
• White light emitting internal junction organic electroluminescent device
  申请人：EASTMAN KODAK COMPANY

  公开号：EP0643549A1

  公开（公告）日：1995-03-15

  An internal junction organic electroluminescent device (100) comprises, in sequence, an anode (110), an organic electroluminescent medium (120), and a cathode (160), the organic electroluminescent medium further comprising a hole injecting and transporting zone (130) contiguous with the anode (110) and an electron injecting and transporting zone (140) contiguous with the cathode (160), the electron injecting and transporting zone (140) further comprising an electron injecting layer (142) in contact with the cathode (160), characterized in that the portion of the organic electroluminescent medium (120) that is interposed between the electron injecting layer (142) and the hole injecting and transporting zone (130) is capable of emitting white light in response to hole-electron recombination and comprises a fluorescent material and a mixed ligand aluminum chelate of the formula         (RS-Q)₂-A1-O-L where Q in each occurrence represents a substituted 8-quinolinolato ligand, Rs represents an 8-quinolinolato ring substituent chosen to block sterically the attachment of more than two substituted 8-quinolinolato ligands to the aluminum atoms, O-L is a phenolato ligand, and L is a hydrocarbon group that includes a phenyl moiety.

  一种内部结有机电致发光器件（100）依次包括阳极（110）、有机电致发光介质（120）和阴极（160），有机电致发光介质进一步包括与阳极（110）相邻的空穴注入和传输区（130）以及与阴极（160）相邻的电子注入和传输区（140）、电子注入和传输区（140）进一步包括与阴极（160）接触的电子注入层（142），其特征在于，位于电子注入层（142）和空穴注入和传输区（130）之间的有机电致发光介质（120）部分能够在空穴-电子重组时发出白光，并包括荧光材料和式中的混合配体铝螯合物 (RS-Q)₂-A1-O-L 其中每次出现的 Q 代表取代的 8-喹啉配体，Rs 代表 8-喹啉环取代基，选择该取代基是为了在立体上阻断两个以上取代的 8-喹啉配体与铝原子的连接，O-L 是苯酚配体，L 是包括苯基的烃基。