N-<2-(2-aminoethyl)amino-2,4,6-cycloheptatrienylidene>-1,2-ethanediamine | 143285-61-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-<2-(2-aminoethyl)amino-2,4,6-cycloheptatrienylidene>-1,2-ethanediamine
• CAS: 143285-61-4
• 化学式: C₁₁H₁₈N₄
• 分子量: 206.291
• InChiKey: JQCXHTDWEFVQBA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.08
• 重原子数：
  15.0
• 可旋转键数：
  5.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  76.43
• 氢给体数：
  3.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  cyclohepta<1,4>benzoxazine 、 N-<2-(2-aminoethyl)amino-2,4,6-cycloheptatrienylidene>-1,2-ethanediamine 生成 7,8,16,17,25,26-hexahydro-6H,15H,24H-tricyclohepta<1,4,7,10,13,16>hexaazacyclooctadecine
  参考文献：
  名称：

  Nozoe, Tetsuo; Shindo, Kimio; Wakabayashi, Hidetsugu, Heterocycles, 1992, vol. 34, # 5, p. 881 - 884

  摘要：

  DOI：
• 作为产物：
  描述：

  cyclohepta<1,4>benzoxazine 在 硫酸 作用下， 以 乙醇 为溶剂， 反应 50.0h， 生成 N-<2-(2-aminoethyl)amino-2,4,6-cycloheptatrienylidene>-1,2-ethanediamine
  参考文献：
  名称：

  Synthesis of Tris- and Tetrakis(tropocoronand)s Having Short Linker Chains

  摘要：

  The syntheses of tris- and tetrakis(tropocoronand)s, a kind of macrocycles derived three or four aminotropone imine moieties bridged by three or four short methylene linker chains are described. These tropocoronands were prepared by the reaction of bis(2-methoxytropone imine)salts with alpha,omega-alkanediamine using a template or with tropopodand derived from benzo[b]cyclohepta[e][1,4]oxazine with N-acetyl-1,2-ethanediamine by an intermolecular heterocycle exchange reaction.

  DOI：

  10.3987/com-94-s(b)56

文献信息

• Nozoe, Tetsuo; Shindo, Kimio; Wakabayashi, Hidetsugu, Heterocycles, 1992, vol. 34, # 5, p. 881 - 884
  作者：Nozoe, Tetsuo、Shindo, Kimio、Wakabayashi, Hidetsugu、Ishikawa, Sumio

  DOI：——

  日期：——
• Synthesis of Tris- and Tetrakis(tropocoronand)s Having Short Linker Chains
  作者：Kimio Shindo、Hidetsugu Wakabayashi、Luo-Cheng Zhang、Sumio Ishikawa、Tatsuo Nozoe

  DOI：10.3987/com-94-s(b)56

  日期：——

  The syntheses of tris- and tetrakis(tropocoronand)s, a kind of macrocycles derived three or four aminotropone imine moieties bridged by three or four short methylene linker chains are described. These tropocoronands were prepared by the reaction of bis(2-methoxytropone imine)salts with alpha,omega-alkanediamine using a template or with tropopodand derived from benzo[b]cyclohepta[e][1,4]oxazine with N-acetyl-1,2-ethanediamine by an intermolecular heterocycle exchange reaction.