5-甲基壬烷-1,9-二胺 | 45024-21-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 5-甲基壬烷-1,9-二胺
• 英文名称: 5-methylnonamethylenediamine
• 英文别名: 5-methylnonane-1,9-diamine；5-methyl-nonanediyldiamine；5-Methyl-nonandiyldiamin；1,9-diamino-5-methyl-nonane
• CAS: 45024-21-3
• 化学式: C₁₀H₂₄N₂
• 分子量: 172.314
• InChiKey: MBRGOFWKNLPACT-UHFFFAOYSA-N

物化性质

• 沸点：
  114-116 °C(Press: 4.5 Torr)
• 密度：
  0.855±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  12
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

安全信息

• 海关编码：
  2921290000

反应信息

• 作为产物：
  描述：

  5-Methyl-nonan-dinitril 在 aluminum oxide 、 氨 、 钴 作用下， 125.0 ℃ 、13.73 MPa 条件下， 生成 5-甲基壬烷-1,9-二胺
  参考文献：
  名称：

  Thermal Addition of Menoölefins to Dienophiles

  摘要：

  DOI：

  10.1021/ja01592a085

文献信息

• [EN] FLAME RETARDANTS, PREPARATION METHODS, AND THERMOPLASTIC COMPOSITIONS THEREOF<br/>[FR] AGENTS IGNIFUGEANTS, LEURS PROCÉDÉS DE PRÉPARATION ET COMPOSITIONS THERMOPLASTIQUES ASSOCIÉES
  申请人：DUPONT CHINA RES & DEV AND MAN CO LTD

  公开号：WO2015180165A1

  公开（公告）日：2015-12-03

  Disclosed are flame retardants comprising compounds of Formula (1), wherein the polyol is a disaccharide or a C12 sugar alcohol, which has at least one glucose or one fructose unit per molecule, R1is H or CH3;R2is H or CH3;mis an integer ranging from 6 to 9; and n is an integer ranging from 2 to 9. Also disclosed are methods for producing the inventive flame retardants, thermoplastic compositions and articles comprising the same, and methods for improving flame retardancy of thermoplastic polymers using the same.

  揭示了包括式（1）化合物的阻燃剂，其中多元醇是二糖或C12糖醇，每个分子至少含有一个葡萄糖或一个果糖单位，R1为H或CH3；R2为H或 ；m为6至9的整数；n为2至9的整数。还公开了制备新型阻燃剂的方法，含有该阻燃剂的热塑性组合物和制品，以及利用该阻燃剂改善热塑性聚合物的阻燃性的方法。
• CYCLIC CARBODIIMIDE COMPOUNDS
  申请人：Shoji Shinichiro

  公开号：US20110251384A1

  公开（公告）日：2011-10-13

  A cyclic carbodiimide compound which is useful as an end-sealing agent for polymer compounds. The cyclic carbodiimide compound is represented by the following formula (i): In the above formula, X is a divalent group or a tetravalent group represented by the following formula (i-4). When X is divalent, q is 0 and when X is tetravalent, q is 1. Ar 1 to Ar 4 are each independently an aromatic group. They may be substituted by an alkyl group having 1 to 6 carbon atoms or phenyl group.

  一种环状羰基胺化合物，可用作聚合物化合物的端封剂。该环状羰基胺化合物由以下式(i)表示：在上述式中，X是由以下式(i-4)表示的二价基团或四价基团。当X为二价时，q为0；当X为四价时，q为1。Ar1至Ar4分别是独立的芳香基团。它们可以被具有1至6个碳原子的烷基基团或苯基取代。
• CYCLIC CARBODIIMIDE COMPOUND
  申请人：Shoji Shinichiro

  公开号：US20130079510A1

  公开（公告）日：2013-03-28

  Disclosed is a cyclic carbodiimide compound useful as an end-capping agent for polymer compounds. The cyclic carbodiimide compound is represented by the following formula (i): wherein X is a specific divalent group or tetravalent group, q is 0 when X is a divalent group, while q is 1 when X is a tetravalent group, and Ar 1 to Ar 4 are selected from aromatic groups each independently optionally substituted with a group that serves as X.

  揭示了一种循环脲醛化合物，可用作聚合物化合物的末端封端剂。该循环脲醛化合物由以下式（i）表示：其中X是特定的二价基团或四价基团，当X是二价基团时，q为0，而当X是四价基团时，q为1，Ar1至Ar4选择自各自独立地可选择地取代为X的基团的芳香族基团。
• SYNTHETIC METHOD AND SYNTHETIC SYSTEM
  申请人：SEKISUI CHEMICAL CO., LTD.

  公开号：US20200095692A1

  公开（公告）日：2020-03-26

  Provided is a synthesis method comprising a first step of producing a carbonate compound from carbon monoxide and an alcohol-based compound at an anode of a first electrochemical cell comprising a cathode and the anode, and a second step of synthesizing a first product by a dealcoholization reaction of the carbonate compound, wherein an alcohol-based compound eliminated in the second step is recycled in the first step.

  提供的是一种合成方法，包括以下步骤：在第一个包括阴极和阳极的第一个电化学电池的阳极上，从一氧化碳和一种基于醇的化合物生成碳酸盐化合物的第一步骤，以及通过碳酸盐化合物的脱醇反应合成第一产品的第二步骤，其中在第二步骤中消除的基于醇的化合物在第一步骤中被回收利用。
• COMPOSITIONS AND METHODS FOR POLYMER COMPOSITES
  申请人：Chan Pong Kwok

  公开号：US20080021175A1

  公开（公告）日：2008-01-24

  This invention relates to organic salt compositions useful in the preparation of organoclay compositions, polymer-organoclay composite compositions, and methods for the preparation of polymer nanocomposites. In one embodiment, the present invention provides a pyridinium salt having structure XV wherein Ar 6 , Ar 7 , and Ar 8 are independently C 2 -C 50 aromatic radicals; “b” is a number from 0 to 2; “d” is a number from 0 to 4; R 3 and R 4 are independently at each occurrence a halogen atom, a C 1 -C 20 aliphatic radical, a C 5 -C 20 cycloaliphatic radical, or a C 2 -C 20 aromatic radical; Z is a bond, a divalent C 1 -C 20 aliphatic radical, a divalent C 5 -C 20 cycloaliphatic radical, a divalent C 2 -C 20 aromatic radical, an oxygen linking group, a sulfur linking group, a SO 2 linking group, or a Se linking group; Ar 9 is a C 10 -C 200 aromatic radical, or a polymer chain comprising at least one aromatic group; and X − is a charge balancing counterion.

  这项发明涉及有机盐组合物，用于制备有机粘土组合物、聚合物-有机粘土复合物组合物，以及制备聚合物纳米复合材料的方法。在一个实施例中，本发明提供了一种具有结构XV的吡啶盐，其中Ar6、Ar7和Ar8分别是C2-C50芳香基团；“b”是从0到2的数字；“d”是从0到4的数字；R3和R4在每次出现时独立地是卤素原子、C1-C20脂肪基、C5-C20环脂肪基或C2-C20芳香基；Z是一个键合、二价的C1-C20脂肪基、二价的C5-C20环脂肪基、二价的C2-C20芳香基、氧链连接基、硫链连接基、SO2链连接基或Se链连接基；Ar9是一个C10-C200芳香基团，或者包含至少一个芳香基团的聚合物链；X^−是一个电荷平衡的对离子。