申请人:DAI-ICHI KOGYO SEIYAKU CO., LTD.
公开号:EP1707265A1
公开(公告)日:2006-10-04
An ionic liquid with an extremely low content of an impurity such as halogen ions which can be obtained easily at a relatively reduced cost, the ionic liquid comprising a pair of a cation K+ and an anion A- represented by the general formula (1) in which the content of an alkali metal as an impurity is 5 ppm or less and the content of a halogen ion is 1 ppm or less, the cation being preferably selected from the group represented by the following general formula (2) obtained by quarternizing a tertiary amine compound or a tertiary phosphine compound by using an acid ester represented by the following general formula (3) and then conducting salt exchange:
General formula (2):
General formula (3): ROY
in which R1 to R4 in the formula (2) each independently represents a linear or branched alkyl group of 1 to 8 carbon atoms, X represents a hetero atom and R in the formula (3) represents a linear or branched alkyl group of 1 to 8 carbon atoms.
含有极低含量杂质(如卤素离子)的离子液体可以以相对较低的成本轻松获得,该离子液体包括一对由一般式(1)表示的阳离子K+和阴离子A-,其中碱金属杂质的含量为5 ppm或更少,卤素离子的含量为1 ppm或更少,首选选择的阳离子来自以下一般式(2)所代表的组,该组是通过使用以下一般式(3)所代表的酸酯对三级胺化合物或三级膦化合物进行季铵化,然后进行盐交换:一般式(2):一般式(3):ROY,其中一般式(2)中的R1至R4各自独立地表示1至8个碳原子的直链或支链烷基基团,X表示杂原子,一般式(3)中的R表示1至8个碳原子的直链或支链烷基基团。