[Hydroxy-[6-[hydroxy(diphosphono)methyl]pyridin-2-yl]-phosphonomethyl]phosphonic acid

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机膦酸及其衍生物
• 英文名称: [Hydroxy-[6-[hydroxy(diphosphono)methyl]pyridin-2-yl]-phosphonomethyl]phosphonic acid
• 英文别名: [hydroxy-[6-[hydroxy(diphosphono)methyl]pyridin-2-yl]-phosphonomethyl]phosphonic acid
• 化学式: C₇H₁₃NO₁₄P₄
• 分子量: 459.07
• InChiKey: RXSWRWNEXSXOEJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -8.1
• 重原子数：
  26
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  284
• 氢给体数：
  10
• 氢受体数：
  15

文献信息

• PHOSPHONIC ACID-CONTAINING BLENDS AND PHOSPHONIC ACID-CONTAINING POLYMERS
  申请人：Häring Thomas

  公开号：US20140213672A1

  公开（公告）日：2014-07-31

  The invention relates to blends and blend membranes from low-molecular hydroxymethylene-oligo-phosphonic acids R—C(PO 3 H 2 ) x (OH) y and polymers, the group R representing any organic group and the polymers containing the following functional groups: cation exchanger groups or their nonionic precursors of the type SO 2 X, X═HaI, OH, OMe, NR 1 R 2 , OR 1 with Me=any metal cation or ammonium cation, R 1 , R 2 =H or any aryl- or alkyl group, POX 2 , COX and/or basic groups such as primary, secondary or tertiary amino groups, imidazole groups, pyridine groups, pyrazole groups etc. and/or OH groups. Low molecular hydroxymethylene-oligo-phosphonic acids R—C(PO 3 H 2 ) x (OH) y are preferred in which x=2 and y=1. The invention also relates to low-molecular hydroxymethylene-oligo-phosphonic acids R—C(PO 3 H 2 ) 2 (OH) 1 and polymers, wherein the group R of the hydroxymethylene-oligophosphonic acid contains an aliphatic or aromatic basic group which ionically interacts with the acidic groups of the polymer or of the polymer mixture. The invention further relates to blends and blend membranes from low-molecular hydroxymethylene-oligo-phosphonic acids R—C(PO 3 H 2 ) 2 (OH) 1 and polymers, wherein the OH groups of the low-molecular hydroxymethylene-1,1-bisphosphonic acid are covalently cross-linked with each other or optionally with OH groups of the polymer. The invention also relates to polymers that are modified with the 1-hydroxymethylene-1,1-bisphosphonic acid group. The polymers are produced by reacting polymers which contain carboxylic acid groups or carboxylic halide groups —COHaI (Hal═F, Cl, Br, I) with phosphite compounds or by reacting polymeric aldehydes or polymeric keto compounds with phosphite esters while carrying out an amine catalysis, an oxidation of the intermediary hydroxyphosphonic acid with MnO 2 or any other oxidant. The invention finally relates to methods for producing the aforementioned materials and to the use of membranes of the aforementioned materials in membrane processes and especially in fuel cells, even at temperatures of >100° C.