(3Z,5E)-3,5-bis[[4-(diethylamino)phenyl]methylidene]-1-methylpiperidin-4-one

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: (3Z,5E)-3,5-bis[[4-(diethylamino)phenyl]methylidene]-1-methylpiperidin-4-one
• 化学式: C₂₈H₃₇N₃O
• 分子量: 431.6
• InChiKey: CSZGWTIIEDCAOM-ZFQRDYFNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  32
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.39
• 拓扑面积：
  26.8
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• Photosensitive resin composition
  申请人：Hitachi Chemical DuPont MicroSystems Ltd.

  公开号：US20020037991A1

  公开（公告）日：2002-03-28

  A 6,6′-dialkyl-3,3′,4,4′-biphenyltetracarboxylic dianhydride is prepared by brominating a 4-alkylphthalic anhydride at its 5-position, and coupling the bromination product in the presence of a nickel catalyst; A photosensitive resin composition containing a polyimide precursor having repetitive units of general formula (7) is applied onto a substrate, exposed to 1 -line, developed and heated to form a polyimide relief pattern. 1 wherein Y is a divalent organic group, R 7 and R 8 are OH or a monovalent organic group, R 9 and R 10 are a monovalent hydrocarbon group, R 11 , R 12 and R 13 are a monovalent hydrocarbon group, a and b are an integer of 0 to 2, c is an integer of 0 to 4, and m is an integer of 0 to 3.

  制备了一种6,6'-二烷基-3,3'，4,4'-联苯四羧酐，方法为在4-烷基邻苯二甲酸酐的5位进行溴化反应，然后在镍催化剂存在下耦合溴化产物；将含有通式（7）重复单元的聚酰亚胺前驱体的光敏树脂组合物涂覆在基板上，暴露于1线，经显影和加热形成聚酰亚胺浮雕图案。其中，Y是双价有机基团，R7和R8是OH或单价有机基团，R9和R10是单价碳氢基团，R11、R12和R13是单价碳氢基团，a和b为0到2的整数，c为0到4的整数，m为0到3的整数。
• Binder-mixtures for optical recording layers and elements
  申请人：EASTMAN KODAK COMPANY (a New Jersey corporation)

  公开号：EP0118881A2

  公开（公告）日：1984-09-19

  A solid, nonpolymeric amorphous mixture of compounds which is useful as a binder in optical recording elements is disclosed. The mixture comprises at least two different compounds each having at least two linking groups joining one multivalent organic nucleus with at least two organic nuclei wherein at least one of the multivalent organic nucleus and the organic nuclei is multicyclic. Methods for making such mixtures are also disclosed.

  本发明公开了一种固态非聚合无定形混合物，可用作光学记录元件的粘合剂。该混合物包括至少两种不同的化合物，每种化合物至少有两个连接基团，连接一个多价有机核和至少两个有机核，其中多价有机核和有机核中至少有一个是多环的。还公开了制造这种混合物的方法。
• Photoinitiator and photopolymerizable composition using the same
  申请人：Hitachi Chemical Co., Ltd.

  公开号：EP0295044A2

  公开（公告）日：1988-12-14

  A photoinitiator composition comprising (1) an aminobenzylidene carbonyl compound and (2) an N-­aryl-α-amino acid is suitable for use in a photo­polymerizable composition comprising (a) an addition-­polymerizable compound having a boiling point of 100°C or higher at an atmospheric pressure and (b) said photoinitiator composition.

  由(1)亚氨基苄基羰基化合物和(2)N-芳基-α-氨基酸组成的光引发剂组合物适用于光聚合组合物，该组合物包括(a)在大气压下沸点为 100°C 或更高的可加成聚合的化合物和(b)所述光引发剂组合物。
• Photosensitive resin composition and photosensitive element using the same
  申请人：Hitachi Chemical Co., Ltd.

  公开号：EP0373952A2

  公开（公告）日：1990-06-20

  A photosensitive resin composition comprising a photoinitiator and polymer containing a repeating unit of formula (I) wherein R1 is a tetravalent organic group, R2 is a divalent organic group, either one or both of R1 and R2 contains at least one silicon atom and/or at least one fluorine atom, Y, is a monovalent group having an ethylenic unsaturated group; n is zero or 1, m is 1 or 2, and n + m = 2.

  一种光敏树脂组合物，包括一种光引发剂和含有式(I)重复单元的聚合物 其中 R1 是四价有机基团，R2 是二价有机基团，R1 和 R2 中的一个或两个含有至少一个硅原子和/或至少一个氟原子，Y 是具有乙烯基不饱和基团的一价基团；n 是 0 或 1，m 是 1 或 2，n + m = 2。
• Photoinitiator system and photopolymerizable composition using the same
  申请人：HITACHI CHEMICAL CO., LTD.

  公开号：EP0551697A1

  公开（公告）日：1993-07-21

  A photoinitiator system comprising (a) an aminobenzylidenecarbonyl compound, (b) an N-aryl-α-amino acid and (c) a titanocene compound, is highly sensitive to visible light and can provide a photopolymerizable composition together with an addition polymerizable compound having a boiling point of 100°C or higher under normal pressure.

  由(a)氨基亚苄基羰基化合物、(b)N-芳基-α-氨基酸和(c)二茂钛化合物组成的光引发剂体系对可见光高度敏感，可以提供一种可光聚合的组合物以及一种在常压下沸点为 100°C 或更高的可添加聚合的化合物。