2-Morpholinomethyl-hydrochinon | 6452-80-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 2-Morpholinomethyl-hydrochinon
• 英文别名: 2-[(Morpholin-4-yl)methyl]benzene-1,4-diol；2-(morpholin-4-ylmethyl)benzene-1,4-diol
• CAS: 6452-80-8
• 化学式: C₁₁H₁₅NO₃
• 分子量: 209.245
• InChiKey: QAKVHMJOVNEJFX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.7
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  52.9
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-Morpholinomethyl-hydrochinon 以 甲醇 为溶剂， 生成 4-Acetoxy-2-morpholinomethyl-phenol
  参考文献：
  名称：

  Methanolysis, Acetolysis, and Rearrangement of ortho-Substituted Phenyl Acetates

  摘要：

  DOI：

  10.1021/jo01012a057

文献信息

• Photographic material containing a new type of hydrazide
  申请人：AGFA-GEVAERT naamloze vennootschap

  公开号：EP0671654A1

  公开（公告）日：1995-09-13

  A new type of hydrazide compounds is disclosed corresponding to general formula (A) : the symbols of which are explained in the description. Examples of synthesis are given. Incorporation of these diacyl hydrazides into the silver halide emulsion layer(s) of a photographic material causes a significant increase in sensitivity.

  与通式 (A) 相对应的新型酰肼化合物已被公开： 的符号已在说明中解释。给出了合成实例。将这些二酰肼掺入感光材料的卤化银乳剂层中可显著提高感光度。
• Compositions and methods for crosslinking polymers in the presence of atmospheric oxygen
  申请人：Arkema Inc.

  公开号：US10316154B2

  公开（公告）日：2019-06-11

  Embodiments of organic peroxide formulations provide significant improvements in surface tackiness (often including tack-free surfaces) when curing elastomers in the presence of oxygen. The peroxide formulations may include, for example, one or more compounds selected from sulfur-containing compounds, organophosphite compounds, HALS (Hindered Amine Light Stabilizer) compounds, aliphatic allyl urethane compounds, and blends comprising nitroxides (e.g., 4-hydroxy-TEMPO) and quinones (e.g., mono-tert-butylhydroquinone).

  在有氧气存在的情况下固化弹性体时，有机过氧化物配方的实施方案可显著改善表面粘性（通常包括无粘性表面）。例如，过氧化物配方可包括一种或多种选自含硫化合物、有机亚磷酸盐化合物、HALS（受阻胺光稳定剂）化合物、脂肪族烯丙基聚氨酯化合物以及由亚硝基化合物（例如 4-羟基-TEMPO）和醌类化合物（例如单叔丁基对苯二酚）组成的混合物。
• Liquid and meltable solid grades of scorch protected peroxides
  申请人：Arkema Inc.

  公开号：US10344142B2

  公开（公告）日：2019-07-09

  Embodiments of organic peroxide formulations provide longer scorch time protection and require fewer additives. The peroxide formulations may include, for example, at least one organic peroxide, at least one nitroxide-containing compound (e.g., 4-hydroxy-TEMPO), and at least one quinone-containing compound (e.g., mono-tert-butylhydroquinone). Embodiments of the present invention relate to organic peroxide compositions comprising scorch retarders. Embodiments of the invention also relate to crosslinkable elastomer compositions, processes for curing the elastomers, and products made by such processes.

  有机过氧化物制剂的实施方案可提供更长的焦烧保护时间，所需的添加剂也更少。例如，过氧化物制剂可包括至少一种有机过氧化物、至少一种含亚硝基化合物（如 4-羟基-TEMPO）和至少一种含醌化合物（如单对叔丁基对苯二酚）。本发明的实施例涉及含有焦烧延缓剂的有机过氧化物组合物。本发明的实施例还涉及可交联弹性体组合物、固化弹性体的工艺以及由这些工艺制成的产品。
• Preparation of Acetoxybenzyl Bromides
  作者：D. L. Fields、J. B. Miller、D. D. Reynolds

  DOI：10.1021/jo01032a040

  日期：1964.9
• COMPOSITIONS AND METHODS FOR CROSSLINKING POLYMERS IN THE PRESENCE OF ATMOSPHERIC OXYGEN
  申请人：Arkema, Inc.

  公开号：EP3230356B1

  公开（公告）日：2021-06-30