2-Dimethoxymethyl-5,10-diphenyl-5,10-dihydro-phenazine | 653593-30-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 2-Dimethoxymethyl-5,10-diphenyl-5,10-dihydro-phenazine
• 英文别名: 2-(Dimethoxymethyl)-5,10-diphenyl-5,10-dihydrophenazine；2-(dimethoxymethyl)-5,10-diphenylphenazine
• CAS: 653593-30-7
• 化学式: C₂₇H₂₄N₂O₂
• 分子量: 408.5
• InChiKey: UKDUREAYKGSNDW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  31
• 可旋转键数：
  5
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  24.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-Dimethoxymethyl-5,10-diphenyl-5,10-dihydro-phenazine 在 4-甲基苯磺酸吡啶 、 silver(l) oxide 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  A Stable Radical-Substituted Radical Cation with Strongly Ferromagnetic Interaction:  Nitronyl Nitroxide-Substituted 5,10-Diphenyl-5,10-dihydrophenazine Radical Cation

  摘要：

  A stable radical-substituted radical ion with strongly ferromagnetic intramolecular interaction (J) between the radical and radical ion sites is an attractive spin building block of organic magnets. We prepared 2-nitronyl nitroxide-substituted 5,10-diphenyl-5,10-dihydrophenazine radical cation, 1+. The 1+ salt was stable under aerated conditions at room temperature and had a large J/kB value (>/=+700 K).

  DOI：

  10.1021/ja0367748

文献信息

• A Stable Radical-Substituted Radical Cation with Strongly Ferromagnetic Interaction:  Nitronyl Nitroxide-Substituted 5,10-Diphenyl-5,10-dihydrophenazine Radical Cation
  作者：Shinsuke Hiraoka、Toshihiro Okamoto、Masatoshi Kozaki、Daisuke Shiomi、Kazunobu Sato、Takeji Takui、Keiji Okada

  DOI：10.1021/ja0367748

  日期：2004.1.1

  A stable radical-substituted radical ion with strongly ferromagnetic intramolecular interaction (J) between the radical and radical ion sites is an attractive spin building block of organic magnets. We prepared 2-nitronyl nitroxide-substituted 5,10-diphenyl-5,10-dihydrophenazine radical cation, 1+. The 1+ salt was stable under aerated conditions at room temperature and had a large J/kB value (>/=+700 K).