6-(1-萘基)-2-[(2,6-二异丙基苯基)亚氨基]吡啶 | 1169702-61-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: 6-(1-萘基)-2-[(2,6-二异丙基苯基)亚氨基]吡啶
• 英文名称: 6-(1-naphthyl)-2-[(2,6-diisopropylphenyl)imino]pyridine
• 英文别名: N-[2,6-di(propan-2-yl)phenyl]-6-naphthalen-1-ylpyridin-2-amine
• CAS: 1169702-61-7
• 化学式: C₂₇H₂₈N₂
• 分子量: 380.533
• InChiKey: BRDLOQAMBURYBF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.9
• 重原子数：
  29
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  24.9
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  N-[2,6-双(1-甲基乙基)苯基]-6-溴吡啶-2-胺 、 1-萘硼酸 在 三苯基膦钯 作用下， 以 乙醇 、 水 、 甲苯 为溶剂， 生成 6-溴吡啶-2-甲醛 、 6-(1-萘基)-2-[(2,6-二异丙基苯基)亚氨基]吡啶
  参考文献：
  名称：

  PROCESS OF MAKING ALUMINUM ALKYLS

  摘要：

  本发明通常涉及一种制备三烷基铝化合物的新工艺，其中至少一个烷基基团是来自内部烯烃或α-烯烃的初级烷基。该工艺采用异构化/氢铝化催化剂。

  公开号：

  US20100204500A1

文献信息

• Metallocene-Substituted Pyridyl Amines, Their Metal Complexes, And Processes For Production And Use Thereof
  申请人：Hagadorn John R.

  公开号：US20090227747A1

  公开（公告）日：2009-09-10

  This invention relates to new transition metal complexes for use in olefin polymerization and oligomerization. The active complex is a pyridine amide having a metallocenyl substituent as part of the ligand structure. The invention also relates to novel precursors for the ligand systems of such complexes obtained from metallocenyl-substituted pyridine compounds through sequences involving addition-condensation or lithium-halogen exchange (with subsequent metathesis) reactions.

  本发明涉及新的过渡金属配合物，用于烯烃聚合和寡聚化。活性配合物是一种吡啶酰胺，其具有金属茂基取代物作为配体结构的一部分。该发明还涉及从茂基取代的吡啶化合物获得的新型配体系统的前体，通过涉及加成缩合或锂卤素交换（随后进行交换反应）的序列获得。
• Composition Suitable for Thin-Wall Injection Molded Articles
  申请人：Henschke Olaf

  公开号：US20100055362A1

  公开（公告）日：2010-03-04

  Compositions suitable for manufacturing injection molded articles having a minimum wall thickness of from 500 μm to 2.0 mm comprise from: (A) 2 to 15% by weight of a propylene-ethylene copolymer having substantially isotactic propylene sequences; (B) 85 to 98% by weight of a random polypropylene copolymer having from 2.5 to 5.0% by weight units derived from ethylene and a melt flow rate of from 25 to 130 grams/10 minutes (g/10 min); and (C) 500 to 2500 ppm by weight of a nucleator/clarifier additive (based on the weight of the random polypropylene copolymer). Typically, the melt flow rate of the compositions is from 20 to 125 g/10 min, and the propylene-ethylene copolymer comprises at least 75% by weight propylene and has a melt flow rate from 4 to 30 g/10 min.

  适用于制造壁厚为500μm至2.0mm的注塑制品的组合物包括：（A）2至15％重量的丙烯-乙烯共聚物，其具有基本同形异构丙烯序列；（B）85至98％重量的随机聚丙烯共聚物，其含有来自乙烯的2.5至5.0％重量单位，并具有熔融流动速率为25至130克/10分钟（g/10分钟）;以及（C）500至2500 ppm重量的成核/澄清剂添加剂（基于随机聚丙烯共聚物的重量）。通常，组合物的熔融流动速率为20至125克/10分钟，丙烯-乙烯共聚物至少包含75％重量的丙烯，并具有4至30克/10分钟的熔融流动速率。
• Propylene-Based Elastomeric Composition
  申请人：Chang Andy C.

  公开号：US20110118418A1

  公开（公告）日：2011-05-19

  The present invention includes a polyolefin elastomeric composition comprising a propylene-based elastomer having at least seventy five weight percent units derived from propylene, the propylene-based elastomer exhibiting a heat of fusion of from 1 to 35 Joules/gram, a weight average molecular weight of from 5400 to 875000 g/mol, and a permanent set of less than 40%; and a homogeneous ethylene-alpha olefin interpolymer having a molecular weight distribution of less than 3.5, a density from 0.885 to 0.915 g/ml, and a heat of fusion of from 65 to 125 Joules/gram, wherein the ratio of the propylene-based elastomer to the homogeneous ethylene-alpha olefin interpolymer is from 97:3 to 80:20, and wherein the composition exhibits a heat of fusion from 2 to 55 Joules/gram, and a 2% secant flexural modulus of less than 69 MPa.

  本发明包括一种聚烯烃弹性组合物，包括至少75重量％来自丙烯的基础丙烯酸酯弹性体，该基础丙烯酸酯弹性体的熔融热为1至35焦耳/克，重均分子量为5400至875000克/摩尔，永久变形率小于40％；以及一种均相的乙烯-α烯烃互聚物，其分子量分布小于3.5，密度为0.885至0.915克/毫升，熔融热为65至125焦耳/克，其中基础丙烯酸酯弹性体与均相的乙烯-α烯烃互聚物的比例为97:3至80:20，组合物的熔融热为2至55焦耳/克，2％切线弯曲模量小于69兆帕。
• HIGH ACTIVITY, LOW MOLECULAR WEIGHT OLEFIN POLYMERIZATION PROCESS
  申请人：Boone Harold W.

  公开号：US20140066585A1

  公开（公告）日：2014-03-06

  Group 4 metal complexes comprising a polyvalent, heteroaryl donor ligand and their use as components of olefin polymerization catalysts, especially suited for preparing propylene copolymer products having high isotacticity and low molecular weight, are disclosed.

  本发明揭示了一种包括多价杂环供体配体的第四组金属配合物，并将其用作烯烃聚合催化剂的组分，特别适用于制备高等晶形性和低分子量的丙烯共聚物产品。
• Metallocene-Substituted Pyridyl Amines, Their Metal Complexes, and Processes for Production and Use Thereof
  申请人：Hagadorn John R.

  公开号：US20100305287A1

  公开（公告）日：2010-12-02

  This invention relates to new transition metal complexes for use in olefin polymerization and oligomerization. The active complex is a pyridine amide having a metallocenyl substituent as part of the ligand structure. The invention also relates to novel precursors for the ligand systems of such complexes obtained from metallocenyl-substituted pyridine compounds through sequences involving addition-condensation or lithium-halogen exchange (with subsequent metathesis) reactions.

  本发明涉及新的过渡金属配合物，用于烯烃聚合和寡聚化。活性配合物是一种含有金属茂基取代物作为配体结构的吡啶酰胺。本发明还涉及通过加成缩合或锂卤素交换（随后进行交换反应）反应序列从茂基取代的吡啶化合物获得这种配合物的配体系统的新前体。