Ethane;3-phenylprop-2-enal

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 肉桂醛
• 英文名称: Ethane;3-phenylprop-2-enal
• 英文别名: ethane;3-phenylprop-2-enal
• 化学式: C11H14O
• 分子量: 162.23
• InChiKey: HEBWMRLUEJCRGH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.92
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• Process for hydrogenation of 2,6,6-trimethyl cyclohexene derivatives, products produced thereby and organoleptic uses of said products
  申请人：INTERNATIONAL FLAVORS & FRAGRANCES INC.

  公开号：EP0012436A1

  公开（公告）日：1980-06-25

  Process for synthesizing compounds of the formula (II) wherein, in the cyclohexyl moiety of structure II, at least two of the dashed lines are carbon-carbon single bonds and the other of the dashed lines is either a carbon-carbon double bond or a carbon-carbon single bond.

  合成式（II）化合物的工艺，其中在结构 II 的环己基分子中，至少两条虚线为碳碳单键，另一条虚线为碳碳双键或碳碳单键。
• Process for preparing acyl trimethyl cyclohexene derivatives and use of intermediates therefor in augmenting or enhancing the aroma or taste of a consumable material
  申请人：INTERNATIONAL FLAVORS & FRAGRANCES INC.

  公开号：EP0032287A1

  公开（公告）日：1981-07-22

  Described is a process for preparing β-damascone starting with 2,6,6-trimethyl cyclohex-2-enone according to the reaction sequence: wherein Z is hydrogen, MgX', Li, Na or K; Y is MgX', Li, Na or K; X' is Cl, Br or I; R is C1-C3 lower alkyl such as methyl, ethyl, n-propyl or i-propyl; K is Cl, Br or i. Also described are the organoleptic uses of the compound having the structure: in augmenting or enhancing the taste or aroma of a consumable material, e.g., foodstuff, chewing gum, medicinal product, chewing tobacco, smoking tobacco, perfume, perfumed article (e.g., drier-added fabric softener articles and solid or liquid anionic, cationic or nonionic detergents) and cologne.

  描述了一种以 2,6,6-三甲基环己-2-烯酮为原料，按照以下反应顺序制备 β-大马酮的工艺： 其中 Z 是氢、MgX'、Li、Na 或 K；Y 是 MgX'、Li、Na 或 K；X'是 Cl、Br 或 I；R 是 C1-C3 低级烷基，如甲基、乙基、正丙基或 i-丙基；K 是 Cl、Br 或 i。 还描述了具有以下结构的化合物的感官用途： 用于增加或提高消费品的味道或香气，例如食品、口香糖、医药产品、咀嚼烟草、 吸烟烟草、香水、加香物品（例如干燥剂添加织物柔软剂物品和固体或液体阴离子、阳离子或 非离子洗涤剂）和古龙水。
• Branched-chain ketones, process of organoleptically modifying, augmenting or enhancing therewith and a process for producing a staple single phase aqueous alkaline metal hypochlorite solution containing the same
  申请人：INTERNATIONAL FLAVORS & FRAGRANCES INC.

  公开号：EP0047572A1

  公开（公告）日：1982-03-17

  Branched-chain ketones, process of organoieptic- ally modifying augmenting or enhancing therewith and a process for producing a staple single phase aqueous alkallin metal hypochlorite soiution containing the same. C -C3 branched aliphatic unsaturated ketones are described, as well as a process of organoleptically modifying augmenting or enhancing therewith and a process for producing a sstaple single phase aqueous metal hypochlorite solution containing the same.

  支链酮、用其进行有机改性、增强或提高的工艺以及生产含有支链酮的主食单相水性碱金属次氯酸盐溶液的工艺。 描述了 C -C3 支链脂肪族不饱和酮，以及用其进行有机改性、增强或提高的工艺和生产含有上述物质的主食单相烷烃类金属次氯酸盐水溶液的工艺。
• Phenethylether derivatives, process for preparing same and uses thereof in combatting tobacco beetles and in augmenting or enhancing the aroma of perfumes, colognes and perfumed articles
  申请人：INTERNATIONAL FLAVORS & FRAGRANCES INC.

  公开号：EP0049120A1

  公开（公告）日：1982-04-07

  The present invention proposes the use of phenethylether derivatives defined according to the structure: wherein R5 represents C3 or C6 secondary alkyl; C4 alkenyl or cyclohexyl or substituted cyclohexyl defined according to the moiety: wherein R1, R2, R3, R4 and R6 are the same or different and each represents methyl or hydrogen with the proviso that when one of R2, R3 and R4 is methyl, the other two of R2, R3 and R4 are hydrogen.

  本发明建议使用根据以下结构定义的苯醚衍生物： 其中R5代表C3或C6仲烷基；C4烯基或环己基或取代的环己基，根据分子式定义： 其中 R1、R2、R3、R4 和 R6 相同或不同，各自代表甲基或氢，但当 R2、R3 和 R4 中的一个是甲基时，R2、R3 和 R4 中的另外两个是氢。
• Carbonyl norbornanes, organoleptic uses thereof and processes for preparing same
  申请人：INTERNATIONAL FLAVORS & FRAGRANCES INC.

  公开号：EP0037644A1

  公开（公告）日：1981-10-14

  Described are a series of compounds defined according to structure: wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond; wherein Z is in the alternative one of the moieties: wherein R1, R2, R3, R4, R5. R6 and R7 are each inthe alternative hydrogen or methyl; wherein R8 and R9 are in the alternative the same or different and are hydrogen orC1-C4 alkyl; with the proviso that one of R1, R2, R5, R6 or R7 is methyl and the other of R1, R2, R5, R6 and R7 is hydrogen; and with the additional proviso that R3 and R4 are not both methyl and uses thereof for augmenting or enhancing the organoleptic properties of consumable materials including foodstuffs, chewing gums, toothpastes, medicinal products, smoking tobaccos, chewing tobaccos, perfumes, perfumed articles, colognes, smoking tobaccos or smoking tobacco articles, as well as catalytic and thermal processes for preparing such compounds by means of Diels-alder reactions between arcylic compounds and monomethyl substituted cyclopentadienes or mixtures thereof.

  所描述的是根据结构定义的一系列化合物： 其中，虚线代表碳碳单键或碳碳双键；其中，Z 是其中的一个分子： 其中 R1、R2、R3、R4、R5.R6和R7各自是氢或甲基；其中R8和R9是相同或不同的，并且是氢或C1-C4烷基；但R1、R2、R5、R6或R7中的一个是甲基，R1、R2、R5、R6和R7中的另一个是氢；另外，R3 和 R4 并非都是甲基，其用途是增加或提高消费品的感官特性，包括食品、口香糖、牙膏、医药产品、烟草、咀嚼烟草、香水、以及通过芳香族化合物与单甲基取代环戊二烯或其混合物之间的 Diels-alder 反应制备此类化合物的催化和热工艺。