3-[Bis[di(propan-2-yl)amino]-dihydroxy-lambda5-phosphanyl]oxypropanenitrile

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 3-[Bis[di(propan-2-yl)amino]-dihydroxy-lambda5-phosphanyl]oxypropanenitrile
• 英文别名: 3-[bis[di(propan-2-yl)amino]-dihydroxy-λ5-phosphanyl]oxypropanenitrile
• 化学式: C₁₅H₃₄N₃O₃P
• 分子量: 335.42
• InChiKey: GQLUMYUTVMQPGF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  22
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.93
• 拓扑面积：
  80
• 氢给体数：
  2
• 氢受体数：
  6

文献信息

• PROCESS FOR PREPARING POLYETHER CARBONATE POLYOLS
  申请人：Covestro Intellectual Property GmbH & Co. KG

  公开号：US20210054145A1

  公开（公告）日：2021-02-25

  A process for preparing polyethercarbonate polyols by adding alkylene oxide and carbon dioxide onto an H-functional starter substance, wherein, (a) a reactor is initially charged with a portion of H-functional starter substance, optionally together with DMC catalyst and (γ) an H-functional starter substance and a suspension medium having no H-functional groups are metered continuously into the reactor during the reaction.
• PROCESS FOR PRODUCING POLYOL
  申请人：Covestro Intellectual Property GmbH & Co. KG

  公开号：US20210171426A1

  公开（公告）日：2021-06-10

  A process for preparing polyol, wherein, in a first process stage, a diol is prepared by a process comprising: (1-i) adding alkylene oxide and carbon dioxide onto an H-functional starter substance in the presence of a catalyst to obtain polyethercarbonate polyol and a cyclic carbonate, (1-ii) separating the cyclic carbonate from the resulting reaction mixture from step (1-i), (1-iii) hydrolyzing the cyclic carbonate separated from step (1-ii) to carbon dioxide and diol, and (1-iv) optionally purifying the diol resulting from step (1-iii) by distillation.
• PROCESS FOR SEPARATING GASEOUS CONSTITUENTS
  申请人：Covestro Intellectual Property GmbH & Co. KG

  公开号：US20210277181A1

  公开（公告）日：2021-09-09

  The present invention provides a process for removing gaseous constituents dissolved in liquid reaction mixtures in the copolymerization of alkylene oxide and carbon dioxide, characterized in that (η) prior to decompression the liquid reaction mixture has a pressure of 5.0 to 100.0 bar (absolute), wherein the following process stages are performed in the specified sequence: (i) decompression of the reaction mixture by at least 50% of the prevailing pressure, (ii) subsequent droplet separation with first defoaming and (iii) subsequent bubble separation with second defoaming to clarify the liquid phase, wherein the process stages (i) to (iii) are performed one or more times until the resulting reaction mixture has a pressure of 0.01 to <5.00 bar (absolute), and also a process for preparing polyethercarbonate polyols comprising the process stages (i)-(iii).
• PROCESS FOR PRODUCING POLYETHER CARBONATE POLYOLS
  申请人：Covestro Intellectual Property GmbH & Co. KG

  公开号：US20220411578A1

  公开（公告）日：2022-12-29

  A process for continuous production of polyether carbonate polyols by the addition of alkylene oxide and carbon dioxide in the presence of a DMC catalyst or a metal complex catalyst based on the metals cobalt and/or zinc, onto an H-functional starter substance is provided. Wherein (γ) the H-functional starter substance, alkylene oxide and catalyst are continuously metered into the reaction during the addition and the resulting reaction mixture is continuously discharged from the reactor, wherein (i) before step (γ), a suspension of catalyst in suspension medium and/or H-functional starter substance in the reactor is adjusted to a temperature T 1 ranging from 100° C. to 150° C., wherein T 1 is at least 10% above a temperature T 2 and T 2 is a temperature ranging from 50° C. to 135° C., and (ii) from commencement of the addition of alkylene oxide in step (γ) the temperature is continuously reduced to the temperature T 2 .