Amylammoniumsulfat

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机硫酸及其衍生物
• 英文名称: Amylammoniumsulfat
• 英文别名: pentylazanium;sulfate
• 化学式: C10H28N2O4S
• 分子量: 272.41
• InChiKey: CPZDJDCKDKBJKJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.62
• 重原子数：
  17
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  135
• 氢给体数：
  4
• 氢受体数：
  6

文献信息

• Process for the production of fluorinated organic compounds and fluorinating agents
  申请人：——

  公开号：US20030176747A1

  公开（公告）日：2003-09-18

  A process for the production of a fluorinated organic compound, characterized by fluorinating an organic compound having a hydrogen atoms using IF 5 ; and a novel fluorination process for fluorinating an organic compound having a hydrogen atoms by using a fluorinating agent containing IF 5 and at least one member selected from the group consisting of acids, bases, salts and additives.

  一种用IF5对含有氢原子的有机化合物进行氟化的生产过程；以及一种新颖的氟化过程，通过使用含有IF5和来自酸、碱、盐和添加剂组成的至少一种成员的氟化剂对含有氢原子的有机化合物进行氟化。
• PROCESSES FOR THE PRODUCTION OF FLUORINATED ORGANIC COMPOUNDS AND FLUORINATING AGENTS
  申请人：Daikin Industries, Ltd.

  公开号：EP1304316A1

  公开（公告）日：2003-04-23

  A process for the production of a fluorinated organic compound, characterized by fluorinating an organic compound having a hydrogen atoms using IF5; and a novel fluorination process for fluorinating an organic compound having a hydrogen atoms by using a fluorinating agent containing IF5 and at least one member selected from the group consisting of acids, bases, salts and additives.

  一种生产含氟有机化合物的工艺，其特征在于使用 IF5 对具有氢原子的有机化合物进行氟化；以及一种新型氟化工艺，通过使用含有 IF5 的氟化剂和至少一种选自酸、碱、盐和添加剂组成的组的成员，对具有氢原子的有机化合物进行氟化。
• COMPOSITION, FLUORINATING REAGENT, AND METHOD FOR PRODUCING FLUORINATED ORGANIC COMPOUND
  申请人：Daikin Industries, Ltd.

  公开号：EP3287431A1

  公开（公告）日：2018-02-28

  An object of the present invention is to provide a method for producing a fluorinated organic compound with a high yield without using carbon tetrachloride in view of the fact that the production of a fluorinated organic compound with a sufficient yield was impossible for a hitherto-known method that uses a fluorinating agent that contains IF5-pyridine-HF alone. Another object of the present invention is to provide a fluorinating reagent that is capable of achieving this object. The present invention provides a composition comprising (1) IF5 and (2) an aprotic solvent (with the proviso that carbon tetrachloride is excluded), wherein the aprotic solvent is contained in an amount within a range of 50 mass ppm to 20 mass%.

  本发明的一个目的是提供一种不使用四氯化碳就能高产率生产含氟有机化合物的方法，因为以前已知的仅使用含有 IF5-吡啶-HF的氟化剂的方法无法生产出足够产率的含氟有机化合物。本发明的另一个目的是提供一种能够实现这一目的的氟化试剂。本发明提供了一种组合物，该组合物包含 (1) IF5 和 (2) 一种壬烷溶剂（但不包括四氯化碳），其中壬烷溶剂的含量在 50 质量ppm 至 20 质量％的范围内。
• METHOD FOR PRODUCING DIFLUOROMETHYLENE COMPOUND
  申请人：DAIKIN INDUSTRIES, LTD.

  公开号：EP3786140A1

  公开（公告）日：2021-03-03

  The problem to be solved by the present invention is to provide a novel method for producing a difluoromethylene compound, in particular, a simple method for producing a difluoromethylene compound. This problem is solved by a method for producing a difluoromethylene compound (I) containing at least one -CF2-moiety, the method comprising step A of allowing IF5 and a disulfide compound (III) of the formula: RA-S-S-RA (wherein RA, in each occurrence, independently represents aryl optionally having at least one substituent or alkyl optionally having at least one substituent) to act on a carbonyl compound (II) containing at least one -C(O)- moiety.

  本发明要解决的问题是提供一种生产二氟亚甲基化合物的新方法，特别是一种生产二氟亚甲基化合物的简单方法。本发明通过一种生产含有至少一个-CF2-分子的二氟亚甲基化合物（I）的方法解决了这一问题，该方法包括步骤 A，允许 IF5 和式中的二硫化物（III）：RA-S-S-RA（其中RA在每次出现时独立地代表任选具有至少一个取代基的芳基或任选具有至少一个取代基的烷基）作用于含有至少一个-C(O)-分子的羰基化合物（II）。
• Composition, fluorinating reagent, and method for producing fluorinated organic compound
  申请人：DAIKIN INDUSTRIES, LTD.

  公开号：US11091432B2

  公开（公告）日：2021-08-17

  An object of the present invention is to provide a method for producing a fluorinated organic compound with a high yield without using carbon tetrachloride in view of the fact that the production of a fluorinated organic compound with a sufficient yield was impossible for a hitherto-known method that uses a fluorinating agent that contains IF5-pyridine-HF alone. Another object of the present invention is to provide a fluorinating reagent that is capable of achieving this object. The present invention provides a composition comprising (1) IF5 and (2) an aprotic solvent (with the proviso that carbon tetrachloride is excluded), wherein the aprotic solvent is contained in an amount within a range of 50 mass ppm to 20 mass %.

  本发明的一个目的是提供一种不使用四氯化碳就能高产率生产含氟有机化合物的方法，因为以前已知的仅使用含有 IF5-吡啶-HF的氟化剂的方法无法生产出足够产率的含氟有机化合物。本发明的另一个目的是提供一种能够实现这一目的的氟化试剂。本发明提供了一种组合物，该组合物包含 (1) IF5 和 (2) 一种烷基溶剂（但不包括四氯化碳），其中烷基溶剂的含量在 50 质量 ppm 至 20 质量 % 的范围内。