methyl-phosphonic acid ethyl ester-hexyl ester | 88795-47-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机膦酸及其衍生物
• 英文名称: methyl-phosphonic acid ethyl ester-hexyl ester
• 英文别名: Methyl-phosphonsaeure-aethylester-hexylester；Ethyl hexyl methylphosphonate；1-[ethoxy(methyl)phosphoryl]oxyhexane
• CAS: 88795-47-5
• 化学式: C₉H₂₁O₃P
• 分子量: 208.238
• InChiKey: DDZCZQWAZQKAHL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  13
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  甲基膦酸二乙酯 、 正己醇 在 sodium 作用下， 生成 methyl-phosphonic acid ethyl ester-hexyl ester
  参考文献：
  名称：

  Arbusow; Winogradowa, Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1952, p. 882,890; engl.Ausg.S.787,793

  摘要：

  DOI：

文献信息

• Cathode-catalyzed transesterification of alkylphosphonates
  作者：M. E. Niyazymbetov、B. Kostizella、I. Keitel、K. H. Schwartz

  DOI：10.1007/bf00959658

  日期：1991.1

  The cathodic electrolysis of aliphatic alcohols and alkylphosphonates in acetonitrile with 0.5 N Et4NClO4 as the base electrolyte leads to mono- and ditransesterified phosphonates. The yield and ratio of these products is a function of the nature of the starting reagents and amount of current passed.
• JUAN, CHENG-YE;YE, WEI-ZHEN;ZHOU, GUO-WEI, ACTA CHIM. SIN, 1983, 41, N 9, 834-842
  作者：JUAN, CHENG-YE、YE, WEI-ZHEN、ZHOU, GUO-WEI

  DOI：——

  日期：——
• ORGANOPHOSPHONATE OLIGOMERS
  申请人：Albemarle Corporation

  公开号：EP2205612A1

  公开（公告）日：2010-07-14
• [EN] ORGANOPHOSPHONATE OLIGOMERS<br/>[FR] OLIGOMÈRES D'ORGANOPHOSPHONATE
  申请人：ALBEMARLE CORP

  公开号：WO2009058572A1

  公开（公告）日：2009-05-07

  This invention provides chlorohydrocarbyloxy phosphonate oligomers, organophosphonate oligomers, and processes for the preparation of such oligomers. The chlorohydrocarbyloxy phosphonate oligomers can be represented by the formula (IV) where R1 is a linear or branched hydrocarbylene group or oxygen-containing hydrocarbylene group, which hydrocarbylene group has about two to about twenty carbon atoms, or a hydrocarbylene group having at least one cycloaliphatic or aromatic ring; R2 is an alkyl group or an aromatic group; and n is a number from about 2 to about 20.
• Arbusow; Winogradowa, Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1952, p. 882,890; engl.Ausg.S.787,793
  作者：Arbusow、Winogradowa

  DOI：——

  日期：——