1-[(2S)-2-(methoxymethoxy)-2,3-dihydronaphthalen-1-yl]-6,7-dihydronaphthalen-2-ol

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 1-[(2S)-2-(methoxymethoxy)-2,3-dihydronaphthalen-1-yl]-6,7-dihydronaphthalen-2-ol
• 化学式: C₂₂H₂₂O₃
• 分子量: 334.4
• InChiKey: OURRINDKMQWZED-FQEVSTJZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  25
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  38.7
• 氢给体数：
  1
• 氢受体数：
  3

文献信息

• Method for producing optically active aziridine compounds and amine compounds as well as complexes and their intermediates used in this method
  申请人：Katsuki Tsutomu

  公开号：US20100113815A1

  公开（公告）日：2010-05-06

  This invention provides a method for producing an optically active aziridine compound or amine compound, which uses as a catalyst a Ru(salen)(CO) complex represented by the following formula (I) or its enantiomer having a high stability, in a high turnover number (TON) and a high enantioselectivity. In the formula (I), Ar is represented by the following formula (VI) or (VII), wherein in the formula (VI), Xs are independently a halogen or a halogenated alkyl group and R 1 and R 2 s are independently hydrogen or an alkyl group or a trialkylsilyl group having a carbon number of 1-4, and in the formula (VII), R 3 is a bulky group.