hexahydro-dispiro[cyclohexane-1,2'-quinazoline-4',1''-cyclohexane] | 59108-80-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: hexahydro-dispiro[cyclohexane-1,2'-quinazoline-4',1''-cyclohexane]
• 英文别名: 2,2,4,4-dipentamethylene-5,6-tetramethylene hexahydropyrimidine
• CAS: 59108-80-4
• 化学式: C₁₈H₃₂N₂
• 分子量: 276.465
• InChiKey: BCSNJESSBMVAGO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  20
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  24.1
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  5',6',7',8'-四氢二螺[环己烷-1,2'(3'H)-喹唑啉-4'(4a'H),1''-环己烷] 在 甲酸 、 三乙胺 作用下， 以 水 为溶剂， 生成 hexahydro-dispiro[cyclohexane-1,2'-quinazoline-4',1''-cyclohexane]
  参考文献：
  名称：

  Hexahydropyrimidines

  摘要：

  本发明涉及六氢嘧啶（HHP）及其通过还原四氢嘧啶（THP）制备的方法。首选方法是在存在甲酸铵的情况下，将羰基，如酮和醛，与氨反应形成THP，然后将THP还原为HHP。首选的羰基是环烷基酮，如环己基酮或取代环己基酮。

  公开号：

  US04085105A1

文献信息

• Process of preparing hexahydropyrimidines
  申请人：Petrolite Corporation

  公开号：US04311841A1

  公开（公告）日：1982-01-19

  This invention relates to hexahydropyrimidines (HHP) of the formula ##STR1## where R' is a substituted group and R is hydrogen or a substituted group; the process of preparing and the uses therefor, particularly as deterioration inhibitors in hydrocarbon fuels.

  这项发明涉及到式子为##STR1##的六氢嘧啶（HHP），其中R'是一个取代基团，R是氢或一个取代基团；其制备过程和用途，特别是作为烃类燃料中的防腐蚀剂。
• Hexahydropyrimidines as anti-oxidants in natural and synthetic rubbers
  申请人：Petrolite Corporation

  公开号：US04104249A1

  公开（公告）日：1978-08-01

  This invention relates to the use of hexahydropyrimidines (HHP) as anti-oxidants for elastic materials such as rubber. The preferred hexahydropyrimidines contain at least one cycloalkylene or substituted cycloalkylene group and most preferably three cycloalkylene groups as illustrated by 2,2,4,4-dipentamethylene-5,6-tetramethylene hexahydropyrimidine.

  本发明涉及将六氢嘧啶（HHP）用作橡胶等弹性材料的抗氧化剂。首选的六氢嘧啶至少包含一个环烷基或取代环烷基基团，最好是三个环烷基基团，如2,2,4,4-二戊亚甲基-5,6-四亚甲基六氢嘧啶所示。
• Additives to control hydrogen sulfide release of sulfur containing and/or phosphorus containing corrosion inhibitors
  申请人：Baker Hughes, a GE company, LLC

  公开号：US10655232B2

  公开（公告）日：2020-05-19

  An additive, such as an aminal, a dibutylamine, or combinations thereof, may treat a system having a corrosion inhibitor in the form of at least one sulfur species and/or at least one phosphorous-containing compound. The additive may be introduced or added to the corrosion inhibitor within an aqueous system, an aerobic system, and/or an anaerobic system to inactivate the sulfur species and/or the phosphorous-containing compounds.

  添加剂，如氨基胺、二丁基胺或其组合，可处理具有至少一种硫物种和/或至少一种含磷化合物形式的缓蚀剂的系统。添加剂可引入或添加到水系统、好氧系统和/或厌氧系统中的缓蚀剂中，以灭活硫物种和/或含磷化合物。
• ADDITIVES TO CONTROL HYDROGEN SULFIDE RELEASE OF SULFUR CONTAINING AND/OR PHOSPHORUS CONTAINING CORROSION INHIBITORS
  申请人：Baker Hughes Holdings LLC

  公开号：EP3737781A1

  公开（公告）日：2020-11-18
• SCAVENGERS FOR SULFUR SPECIES AND/OR PHOSPHORUS CONTAINING COMPOUNDS
  申请人：BAKER HUGHES INCORPORATED

  公开号：US20160060520A1

  公开（公告）日：2016-03-03

  A scavenger additive, treated system, and method of using the same may treat a system having at least one sulfur species and/or at least one phosphorous-containing compound. At least one scavenger compound may be circulated or added to the system and may include, but is not limited to, aminals, dibutylamine, and combinations thereof. The scavenger compound(s) may increase the amount of inactivated sulfur species and/or inactivated phosphorous-containing compounds.