1-(1-(o-tolyl)vinyl)naphthalene | 1147123-32-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-(1-(o-tolyl)vinyl)naphthalene
• 英文别名: Naphthyltolylethene；1-[1-(2-methylphenyl)ethenyl]naphthalene
• CAS: 1147123-32-7
• 化学式: C₁₉H₁₆
• 分子量: 244.336
• InChiKey: NVUUUVXXWCCPKX-UHFFFAOYSA-N

物化性质

• 沸点：
  388.0±17.0 °C(predicted)
• 密度：
  1.052±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  19
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1-(naphthalen-1-yl)vinyl diphenyl phosphate 、 O-甲苯基氯化镁 在 palladium dichloride 作用下， 以 四氢呋喃 为溶剂， 反应 22.0h， 以66%的产率得到1-(1-(o-tolyl)vinyl)naphthalene
  参考文献：
  名称：

  A Ligand Free and Room Temperature Protocol for Pd-Catalyzed Kumada−Corriu Couplings of Unactivated Alkenyl Phosphates

  摘要：

  Kumada-Corriu cross-couplings of nonactivated cyclic and acyclic vinyl phosphates with aryl magnesium reagents afforded a series of 1,1-disubtituted alkenes in good yields for most cases when the reactions were performed at room temperature with the simple palladium salt, PdCl2, without the presence of phosphine ligands.

  DOI：

  10.1021/jo900098a

文献信息

• Traceless directing group mediated branched selective alkenylation of unbiased arenes
  作者：Soumitra Agasti、Aniruddha Dey、Debabrata Maiti

  DOI：10.1039/c6cc07032a

  日期：——

  –COOH group assisted branched selective olefination of simple arenes.

  –COOH基团辅助简单芳烃的分支选择性烯基化。

• A Ligand Free and Room Temperature Protocol for Pd-Catalyzed Kumada−Corriu Couplings of Unactivated Alkenyl Phosphates
  作者：Delphine Gauthier、Stephan Beckendorf、Thomas M. Gøgsig、Anders T. Lindhardt、Troels Skrydstrup

  DOI：10.1021/jo900098a

  日期：2009.5.1

  Kumada-Corriu cross-couplings of nonactivated cyclic and acyclic vinyl phosphates with aryl magnesium reagents afforded a series of 1,1-disubtituted alkenes in good yields for most cases when the reactions were performed at room temperature with the simple palladium salt, PdCl2, without the presence of phosphine ligands.