Dihexoxyphosphorylmethylbenzene

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机膦酸及其衍生物
• 英文名称: Dihexoxyphosphorylmethylbenzene
• 英文别名: dihexoxyphosphorylmethylbenzene
• 化学式: C₁₉H₃₃O₃P
• 分子量: 340.4
• InChiKey: GHLQWMWVKWDOHN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  23
• 可旋转键数：
  14
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.68
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

文献信息

• THERMOPLASTIC RESIN AND OPTICAL MEMBER
  申请人：Teijin Limited

  公开号：EP3677614A1

  公开（公告）日：2020-07-08

  The purpose of the present invention is to provide a thermoplastic resin that has a high refractive index and enables low birefringence and balanced heat resistance and moldability. This thermosetting resin includes repeating units represented by formula (1). (In the formula, the rings Z are the same or different and represent an aromatic hydrocarbon ring, R1 and R2 independently represent a C1-C12 hydrocarbon group optionally including a hydrogen atom, a halogen atom, and an aromatic group, Ar1 and Ar2 represent a C6-C10 aromatic group optionally having a substituent, L1 and L2 independently represent a divalent linking group, j and k independently represent an integer of 0 or more, m and n independently represent 0 or 1, and W is at least one selected from the groups represented by formulae (2) and (3).) (In the formula, X represents a divalent linking group.)

  本发明的目的是提供一种热塑性树脂，它具有高折射率，可实现低双折射，并兼顾耐热性和成型性。这种热固性树脂包括由式（1）表示的重复单元。(式中，环 Z 相同或不同，代表芳香烃环；R1 和 R2 独立地代表 C1-C12 烃基，可选地包括氢原子、卤素原子和芳香基；Ar1 和 Ar2 代表 C6-C10 芳香基，可选地具有取代基；L1 和 L2 独立地代表二价连接基；j 和 k 独立地代表 0 或以上的整数；m 和 n 独立地代表 0 或 1；W 至少选自式（2）和（3）所代表的基团中的一个）。(式中，X 代表二价连接基团）。
• POLY(ESTER)CARBONATE AND METHOD FOR PRODUCING POLY(ESTER)CARBONATE
  申请人：Teijin Limited

  公开号：EP3733734A1

  公开（公告）日：2020-11-04

  An object of the present invention is to provide a novel production method of a poly(ester)carbonate. The present invention relates to a production method of a poly(ester)carbonate, including subjecting a diol and a carbonate ester to a transesterification reaction in the presence of a catalyst, wherein the catalyst comprises aluminum or a compound thereof, and a phosphorus compound.

  本发明的目的是提供一种新型聚（酯）碳酸酯的生产方法。 本发明涉及一种聚（酯）碳酸酯的生产方法，包括将二元醇和碳酸酯在催化剂存在下进行酯交换反应，其中催化剂包括铝或其化合物和磷化合物。
• POLYESTER RESIN OR POLYESTER CARBONATE RESIN, AND OPTICAL MEMBER USING SAID RESIN
  申请人：Teijin Limited

  公开号：EP3766913A1

  公开（公告）日：2021-01-20

  The purpose of the present invention is to provide a polyester resin or polyester carbonate resin, which has high refractive index, while achieving an excellent balance between heat resistance and low birefringence. A polyester resin or a polyester carbonate resin, which contains repeating units represented by the following formulae (1) and (2), and wherein the ratio of the repeating unit represented by formula (1) to the repeating unit represented by formula (2) is 15:85 to 85:15. (In formula (1), each of rings Z1 and Z2 represents a polycyclic aromatic hydrocarbon group having 9-20 carbon atoms; each of R1, R2, R7 and R8 independently represents a hydrocarbon group which may contain an aromatic group having 1-12 carbon atoms; each of R3-R6 and R9-R16 represents a hydrogen atom or an aliphatic or aromatic substituents; each of j, k, r and s independently represent an integer of 0 or more; and each of m, n, p and q independently represents 1 or 2) (In formula (2), each of R7, R8, R17 and R18 independently represent a hydrocarbon group which may contain an aromatic group having 1-12 carbon atoms; each of R9-R16 and R19-R26 represents a hydrogen atoms or an aliphatic or aromatic substituents; and each of r, s, t and u independently represents an integer of 0 or more.)

  本发明的目的是提供一种聚酯树脂或碳酸聚酯树脂，它具有高折射率，同时在耐热性和低双折射之间达到极佳的平衡。一种聚酯树脂或聚酯碳酸酯树脂，它含有下式（1）和（2）所代表的重复单元，其中式（1）所代表的重复单元与式（2）所代表的重复单元的比例为 15:85 至 85:15。(在式 (1) 中，环 Z1 和 Z2 各自代表具有 9-20 个碳原子的多环芳香烃基团；R1、R2、R7 和 R8 各自独立地代表可包含具有 1-12 个碳原子的芳香基团的烃基；R3-R6 和 R9-R16 各自代表氢原子或脂肪族或芳香族取代基；j、k、r 和 s 各自独立地代表 0 或以上的整数；式（2）中，R7、R8、R17 和 R18 各自独立地代表一个烃基，该烃基可包含一个具有 1-12 个碳原子的芳香族基团；R9-R16 和 R19-R26 各自独立地代表一个氢原子或一个脂肪族或芳香族取代基；r、s、t 和 u 各自独立地代表一个 0 或以上的整数。)
• Thermoplastic resin and optical member
  申请人：TEIJIN LIMITED

  公开号：US11261294B2

  公开（公告）日：2022-03-01

  The purpose of the present invention is to provide a thermoplastic resin that has a high refractive index and enables low birefringence and balanced heat resistance and moldability. This thermosetting resin includes repeating units represented by formula (1). (In the formula, the rings Z are the same or different and represent an aromatic hydrocarbon ring, R1 and R2 independently represent a C1-C12 hydrocarbon group optionally including a hydrogen atom, a halogen atom, and an aromatic group, Ar1 and Ar2 represent a C6-C10 aromatic group optionally having a substituent, L1 and L2 independently represent a divalent linking group, j and k independently represent an integer of 0 or more, m and n independently represent 0 or 1, and W is at least one selected from the groups represented by formulae (2) and (3).) (In the formula, X represents a divalent linking group.)

  本发明的目的是提供一种热塑性树脂，它具有高折射率，可实现低双折射，并兼顾耐热性和成型性。这种热固性树脂包括由式（1）表示的重复单元。(式中，环 Z 相同或不同，代表芳香烃环；R1 和 R2 独立地代表 C1-C12 烃基，可选地包括氢原子、卤素原子和芳香基；Ar1 和 Ar2 代表 C6-C10 芳香基，可选地具有取代基；L1 和 L2 独立地代表二价连接基；j 和 k 独立地代表 0 或以上的整数；m 和 n 独立地代表 0 或 1；W 至少选自式（2）和（3）所代表的基团中的一个）。(式中，X 代表二价连接基团）。
• [EN] POLYESTER RESIN OR POLYESTER CARBONATE RESIN, AND OPTICAL MEMBER USING SAID RESIN<br/>[FR] RÉSINE POLYESTER OU RÉSINE CARBONATE DE POLYESTER, ET ÉLÉMENT OPTIQUE UTILISANT LADITE RÉSINE<br/>[JA] ポリエステル樹脂またはポリエステルカーボネート樹脂、および該樹脂を用いた光学部材
  申请人：TEIJIN LTD

  公开号：WO2019176874A1

  公开（公告）日：2019-09-19

  本発明の目的は、高屈折率、かつ耐熱性、低複屈折のバランスに優れたポリエステル樹脂またはポリエステルカーボネート樹脂を提供することにある。　下記式（１）および（２）で表される繰り返し単位を含み、下記式（１）で表される繰り返し単位と下記式（２）で表される繰り返し単位の比が、１５：８５～８５：１５であるポリエステル樹脂またはポリエステルカーボネート樹脂。 （式（１）中、環Ｚ１、Ｚ２はそれぞれ炭素原子数９～２０の多環芳香族炭化水素基を示し、Ｒ１、Ｒ２、Ｒ７およびＲ８はそれぞれ独立に、炭素原子数１～１２の芳香族基を含んでいても良い炭化水素基を示し、Ｒ３～Ｒ６、Ｒ９～Ｒ１６は水素原子、脂肪族または芳香族の置換基を示し、ｊ、ｋ、ｒおよびｓはそれぞれ独立に０以上の整数を示し、ｍ、ｎ、ｐおよびｑはそれぞれ独立に１または２を示す。） （式（２）中、Ｒ７、Ｒ８、Ｒ１７およびＲ１８はそれぞれ独立に、炭素原子数１～１２の芳香族基を含んでいても良い炭化水素基を示し、Ｒ９～Ｒ１６、Ｒ１９～Ｒ２６は水素原子、脂肪族または芳香族の置換基を示し、ｒ、ｓ、ｔおよびｕはそれぞれ独立に０以上の整数を示す。）