N.N.N-Trimethyl-1-aminoadamantyl-kation | 46244-96-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N.N.N-Trimethyl-1-aminoadamantyl-kation
• 英文别名: 1-Adamantyl(trimethyl)ammonium；1-adamantyl(trimethyl)azanium
• CAS: 46244-96-6
• 化学式: C₁₃H₂₄N
• 分子量: 194.34
• InChiKey: KKXBPUAYFJQMLN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  14
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

文献信息

• [EN] METHOD FOR PREPARING 1 -ADAMANTYLTRIMETHYLAMMONIUM HYDROXIDE<br/>[FR] PROCÉDÉ DE PRÉPARATION D'HYDROXYDE DE 1-ADAMANTYLTRIMÉTHYLAMMONIUM
  申请人：JOHNSON MATTHEY PLC

  公开号：WO2014155118A1

  公开（公告）日：2014-10-02

  A method for preparing 1 -adamantyltrimethylammonium hydroxide is disclosed. The method comprises reacting 1 -adamantyldimethylamine with dimethyl carbonate to produce 1 -adamantyltrimethylammonium methylcarbonate, which is then reacted with calcium hydroxide or magnesium hydroxide in the presence of water to produce 1 - adamantyltrimethylammonium hydroxide.

  揭示了一种制备1-金刚烷基三甲基铵羟化物的方法。该方法包括将1-金刚烷基二甲胺与碳酸二甲酯反应，产生1-金刚烷基三甲基铵甲基碳酸盐，然后在水的存在下将其与氢氧化钙或氢氧化镁反应，生成1-金刚烷基三甲基铵羟化物。
• Oxypentafluorosulfate compositions and processes for making them
  申请人：Syvret Robert George

  公开号：US20080033164A1

  公开（公告）日：2008-02-07

  Novel compositions are provided containing a compound represented by the formula YOSF 5 or ZOSF 5 , where: (a) Y is: (i) an organic cation other than (Me 2 N) 3 S + or (ii) an inorganic cation, provided that when Y is the inorganic cation, the composition further includes a complexing agent; and (b) Z is C 1-20 alkyl, aryl, cycloalkyl, combinations thereof, or analogues thereof containing at least one heteroatom, provided that the compound represented by the formula ZOSF 5 is a molecular compound. Processes of making the cationic compounds are disclosed as are processes for using the compositions containing cationic compounds in nucleophilic replacement reactions to prepare the compositions containing molecular compounds including the OSF 5 group.

  提供含有由公式YOSF5或ZOSF5表示的化合物的小说组合物，其中：(a) Y是：(i) 除(Me2N)3S+之外的有机阳离子，或者(ii) 无机阳离子，但是当Y是无机阳离子时，组合物还包括络合剂；和(b) Z是C1-20烷基，芳香族，环烷基，它们的组合物，或者至少含有一个杂原子的类似物，但是由公式ZOSF5表示的化合物是一个分子化合物。公开了制备阳离子化合物的方法，以及使用含有阳离子化合物的组合物进行亲核取代反应以准备含有OSF5基团的分子化合物的方法。
• METHOD FOR PRODUCING OXIDIZED COMPOUND
  申请人：Kawabata Tomonori

  公开号：US20110282082A1

  公开（公告）日：2011-11-17

  A method for producing an oxidized compound according to the present invention comprises reacting an organic compound with an oxidizing agent in the presence of titanosilicate (I) or a silylated form thereof, the titanosilicate (I) being obtained by contacting titanosilicate (II) with a structure-directing agent, and the titanosilicate (II) having an X-ray diffraction pattern reproduced in the form of interplanar spacings d of 1.24±0.08 nm, 1.08±0.03 nm, 0.9±0.03 nm, 0.6±0.03 nm, 0.39±0.01 nm and 0.34±0.01 nm.

  根据本发明，生产氧化物的方法包括在钛硅酸盐(I)或其硅烷化形式的存在下，将有机化合物与氧化剂反应，所述钛硅酸盐(I)是通过将钛硅酸盐(II)与结构定向剂接触而获得的，所述钛硅酸盐(II)具有以1.24±0.08纳米、1.08±0.03纳米、0.9±0.03纳米、0.6±0.03纳米、0.39±0.01纳米和0.34±0.01纳米的间隙距离形式再现的X射线衍射图案。
• METHOD FOR PRODUCING TITANOSILICATE
  申请人：Kawabata Tomonori

  公开号：US20110237810A1

  公开（公告）日：2011-09-29

  The present invention relates to a method for producing a Ti-MWW precursor comprising: a first step of heating a mixture to prepare a solid, said mixture comprising a structure-directing agent, a compound containing a Group 13 element of the periodic table, a titanium-containing compound (1), a silicon-containing compound and water; and a second step of contacting the solid with a titanium-containing compound (2) and an inorganic acid.

  本发明涉及一种生产Ti-MWW前体的方法，包括以下步骤：第一步，加热混合物以制备固体，所述混合物包括结构指向剂、周期表中含有第13族元素的化合物、含钛化合物（1）、含硅化合物和水；第二步，将固体与含钛化合物（2）和无机酸接触。
• Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins
  申请人：Cao Guang

  公开号：US20070100185A1

  公开（公告）日：2007-05-03

  The synthesis of a crystalline material, in particular, a high silica zeolite, comprising a chabazite-type framework molecular sieve is conducted in the presence of an organic directing agent having the formula: [R 1 R 2 R 3 N—R 4 ] + Q − wherein R 1 and R 2 are independently selected from hydrocarbyl groups and hydroxy-substituted hydrocarbyl groups having from 1 to 3 carbon atoms, provided that R 1 and R 2 may be joined to form a nitrogen-containing heterocyclic structure, R 3 is an alkyl group having 2 to 4 carbon atoms and R 4 is selected from a 4- to 8-membered cycloalkyl group, optionally, substituted by 1 to 3 alkyl groups each having from 1 to 3 carbon atoms; and a 4- to 8-membered heterocyclic group having from 1 to 3 heteroatoms, said heterocyclic group being, optionally, substituted by 1 to 3 alkyl groups each having from 1 to 3 carbon atoms and the or each heteroatom in said heterocyclic group being selected from the group consisting of O, N, and S, or R 3 and R 4 are hydrocarbyl groups having from 1 to 3 carbon atoms joined to form a nitrogen-containing heterocyclic structure; and Q − is a anion.

  在有机引导剂的存在下进行晶体材料的合成，特别是高硅沸石，包括一个以Chabazite类型骨架分子筛为主的结构。该有机引导剂的化学式为：[R1R2R3N—R4]+Q−，其中R1和R2分别选择具有1至3个碳原子的烃基和羟基取代的烃基，前提是R1和R2可以结合形成含氮的杂环结构，R3是具有2至4个碳原子的烷基，而R4则选择一个4至8个成员的环烷基，可选地，由1至3个每个具有1至3个碳原子的烷基取代;和一个具有1至3个杂原子的4至8个成员的杂环基，该杂环基可选地由1至3个每个具有1至3个碳原子的烷基取代，而且该杂环基中的每个杂原子来自于O、N和S的群组，或者R3和R4是具有1至3个碳原子的烃基，结合形成含氮的杂环结构；Q−是一个阴离子。