1-isobutyl-3,3-dimethylspiro[indole-2,3'-naphtho[1,2-b][1,4]oxazine] | 124956-65-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并恶嗪类
• 英文名称: 1-isobutyl-3,3-dimethylspiro[indole-2,3'-naphtho[1,2-b][1,4]oxazine]
• 英文别名: 1,3-dihydro-3,3-dimethyl-1-(2-methylpropyl)spiro[2H-indole-2,3'-[3H]-naphth[2,1-b][1,4]oxazine]；SOX；1,3-Dihydro-3,3-dimethyl-1-isobutylspiro[2H-indole-2,3'-3H-naphtho[2,1-b][1,4]oxazine ]；3',3'-Dimethyl-1'-(2-methylpropyl)spiro[benzo[f][1,4]benzoxazine-3,2'-indole]
• CAS: 124956-65-6
• 化学式: C₂₅H₂₆N₂O
• 分子量: 370.494
• InChiKey: FENQIFUKSPOVFJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  28
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  24.8
• 氢给体数：
  0
• 氢受体数：
  3

文献信息

• Photochromic Compositions and Light Transmissible Articles
  申请人：Evans Alexander Richard

  公开号：US20080006798A1

  公开（公告）日：2008-01-10

  The invention relates to a photochromic polymeric composition comprising a polymer matrix and a photochromic compound which is an adduct comprising a photochromic moiety and at least one pendant oligomer group to provide a rate of fade of the photochromic polymeric composition which is significantly changed when compared with the corresponding composition comprising the photochromic compound without said pendent oligomer. The invention also relates to a photochromic compound which is an adduct comprising a photochromic moiety and at least one pendent oligomer.

  本发明涉及一种光致变色聚合物组合物，包括聚合物基质和光致变色化合物。该化合物是一种加合物，包括光致变色基团和至少一个挂链寡聚物基团，以提供与不含上述挂链寡聚物的光致变色化合物相比，光致变色聚合物组合物的退色速率显著改变的速率。本发明还涉及一种光致变色化合物，它是一种加合物，包括光致变色基团和至少一个挂链寡聚物基团。
• Photo reactive material
  申请人：PILKINGTON PLC

  公开号：EP0600669A1

  公开（公告）日：1994-06-08

  A photo reactive material, such as a photochromic material, which has the following structure: where Ais a six membered carbocyclic or heterocyclic ring; each Ris alkyl, alkenyl, alkynyl, aryl, carbocyclic, heterocyclic, alkyl carbocyclic or alkyl heterocyclic or at least two of the R groups together form part of a carbocyclic or heterocyclic ring or one of the R groups is hydrogen with the other two being selected from the above; R*are independent of one another and are selected from branched or linear C₁-C₁₀ alkyls and carbocyclic or heterocyclic groups or both form part of a carbocyclic or heterocyclic ring; R⁺mis selected from alkyl alkoxy, amino, halogen, cyano, nitro, trifluoromethyl or aryl and m has a value between 0 and 4; R⁺nis selected from carbocyclic and heterocyclic groups which are fused to A and n has a value between 0 and 2. R'is selected from hydrogen, alkyl, alkoxy, amino, carbocylic or heterocyclic. R''is selected from hydrogen, alkyl, aryl, heteroaryl, alkenyl, alkynyl, alkoxy, aryloxy, amino, halogen, cyano, nitro, trifluoromethyl, imino, azo, carboxy ester or amide or is a carbocyclic or heterocyclic group fused to the moiety.

  光反应材料，如光致变色材料，其结构如下： 其中 A 是六分子碳环或杂环； 每个 Ris 烷基、烯基、炔基、芳基、 碳环、杂环、烷基碳环或烷基杂环 或至少两个 R 基团共同构成碳环或杂环的一部分 或其中一个 R 基团为氢，另外两个从上述基团中选出； R* 相互独立，选自支链或线性 C₁-C₁₀烷基和碳环或杂环基团，或两个基团共同构成碳环或杂环的一部分； R⁺m 选自烷基烷氧基、氨基、卤素、氰基、硝基、三氟甲基或芳基，且 m 的值在 0 至 4 之间； R⁺n 选自与 A 融合的碳环和杂环基团，n 的值在 0 和 2 之间。 R'选自氢、烷基、烷氧基、氨基、羰基或杂环。 R''选自氢、烷基、芳基、杂芳基、烯基、炔基、烷氧基、芳氧基、氨基、卤素、氰基、硝基、三氟甲基、亚氨基、偶氮、羧基酯或酰胺，或者是与分子融合的碳环或杂环基团。
• AN ARTICLE HAVING PHOTOCHROMIC PROPERTIES AND PROCESS FOR ITS MANUFACTURE
  申请人：Bayer MaterialScience LLC

  公开号：EP2067060B1

  公开（公告）日：2010-07-07
• Article having photochromic properties and process for its manufacture
  申请人：Archey L. Rick

  公开号：US20070259117A1

  公开（公告）日：2007-11-08

  A process for making an article molded of polymeric material, the article featuring photochromic properties is disclosed. To at least a portion of the surface of an article, molded of a composition that contains at least one transparent thermoplastic polymer or a transparent thermosetting composition there is applied a curable weatherable polyurethane coating. At least a portion of the coating is after curing brought into contact with a material system that contains (i) water, (ii) at least one carrier conforming to wherein R 1 is a radical selected from the group consisting of linear or branched C 1 -C 18 alkyl, benzyl, benzoyl and phenyl, R 2 is R 1 or H, n is 2, 3 or 4, and m is 1 to 35; (iii) a photochromic compound and (iv) a diol, under conditions calculated to bring about diffusion of said compound into the cured coating.
• US5446151A
  申请人：——

  公开号：US5446151A

  公开（公告）日：1995-08-29