6-dibutylamino-4-oxa-10,15-diazadibenzo[a,de]naphthacene-12-carboxylic acid | 1048685-75-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并吡喃
• 英文名称: 6-dibutylamino-4-oxa-10,15-diazadibenzo[a,de]naphthacene-12-carboxylic acid
• 英文别名: 17-(Dibutylamino)-20-oxa-3,10-diazahexacyclo[11.11.1.02,11.04,9.014,19.021,25]pentacosa-1(25),2,4(9),5,7,10,12,14(19),15,17,21,23-dodecaene-7-carboxylic acid；17-(dibutylamino)-20-oxa-3,10-diazahexacyclo[11.11.1.02,11.04,9.014,19.021,25]pentacosa-1(25),2,4(9),5,7,10,12,14(19),15,17,21,23-dodecaene-7-carboxylic acid
• CAS: 1048685-75-1
• 化学式: C₃₁H₂₉N₃O₃
• 分子量: 491.59
• InChiKey: WROMOTXCQYGOAR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.3
• 重原子数：
  37
• 可旋转键数：
  8
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.26
• 拓扑面积：
  75.6
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  9-(dibutylamino)benzo[kl]xanthene-2,3-dione 、 3,4-二氨基苯甲酸 在 溶剂黄146 作用下， 反应 1.5h， 生成 6-dibutylamino-4-oxa-10,15-diazadibenzo[a,de]naphthacene-12-carboxylic acid 、 6-dibutylamino-4-oxa-10,15-diazadibenzo[a,de]naphthacene-13-carboxylic acid
  参考文献：
  名称：

  Photophysical properties and photostability of novel unsymmetric polycyclicphenazine-type D-π-A fluorescent dyes and the dye-doped films

  摘要：

  Structural isomers of unsymmetric polycyclicphenazine-type D-pi-A fluorescent dyes have been newly synthesized and characterized in both solution and polymer films. The dyes exhibited two strong absorption bands at around 328-401 rim and 516-532 nm, and an intense fluorescence band at around 595-629 nm (phi = 0.32-0.84) in 1,4-dioxane. The dye-doped polymer films showed good ability of wavelength conversion; the films can efficiently convert ultraviolet and green-yellow lights into red light (phi=0.43-0.86). Moreover, the photostability of the dyes-doped PS. PMMA. and PLA films has been investigated. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jphotochem.2011.12.009

文献信息

• Photophysical properties and photostability of novel unsymmetric polycyclicphenazine-type D-π-A fluorescent dyes and the dye-doped films
  作者：Haruka Egawa Ooyama、Akiko Hayashi、Toshiki Mamura、Takashi Ide、Toshihiko Hino、Takuya Tanigami、Katsuhira Yoshida

  DOI：10.1016/j.jphotochem.2011.12.009

  日期：2012.2

  Structural isomers of unsymmetric polycyclicphenazine-type D-pi-A fluorescent dyes have been newly synthesized and characterized in both solution and polymer films. The dyes exhibited two strong absorption bands at around 328-401 rim and 516-532 nm, and an intense fluorescence band at around 595-629 nm (phi = 0.32-0.84) in 1,4-dioxane. The dye-doped polymer films showed good ability of wavelength conversion; the films can efficiently convert ultraviolet and green-yellow lights into red light (phi=0.43-0.86). Moreover, the photostability of the dyes-doped PS. PMMA. and PLA films has been investigated. (C) 2011 Elsevier B.V. All rights reserved.