methyl-(1-methyl-1-[1]naphthyl-ethyl)-ether | 171117-17-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: methyl-(1-methyl-1-[1]naphthyl-ethyl)-ether
• 英文别名: 1-(α-Methoxy-isopropyl)-naphthalin；2-Methoxy-2-(naphthyl-(1))-propan；Methyl-(1-methyl-1-[1]naphthyl-aethyl)-aether；1-(1-Methoxy-1-methylethyl)naphthalene；1-(2-Methoxypropan-2-yl)naphthalene
• CAS: 171117-17-2
• 化学式: C₁₄H₁₆O
• 分子量: 200.28
• InChiKey: MRPVSELWLNGKSI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  methyl-(1-methyl-1-[1]naphthyl-ethyl)-ether 在 potassium Sodium 、 乙醚 作用下， 生成 2-methyl-2-[1]naphthyl-propionic acid
  参考文献：
  名称：

  New Compounds. Oxime of Furfuralacetone

  摘要：

  DOI：

  10.1021/ja01857a077
• 作为产物：
  描述：

  2-萘-1-基丙-2-醇 在 1,4-二氧六环 、 sodium amide 作用下， 生成 methyl-(1-methyl-1-[1]naphthyl-ethyl)-ether
  参考文献：
  名称：

  New Compounds. Oxime of Furfuralacetone

  摘要：

  DOI：

  10.1021/ja01857a077

文献信息

• Conformational Studies by Dynamic NMR. 64.¹ Stereomutations of Atropisomers and of Conformational Enantiomers in Ethers of Hindered Naphthylcarbinols
  作者：Daniele Casarini、Lodovico Lunazzi、Andrea Mazzanti、Elisabetta Foresti

  DOI：10.1021/jo9804801

  日期：1998.7.1

  Methyl or ethyl ethers of 1-naphthyl carbinols ArCR2OR' (Ar = 1-naphthyl, R' = Me, Et) can occur in a range of rotational conformations whose population varies with the nature of the substituents R. The passage between such conformation minima is achieved by rotation, during which one group R or OR' passes either the 2- or the 8-position of the naphthalene, and depending on the nature of R and OR', some of these interconversions are slow on the NMR time scale. Dynamic NMR experiments, supported by molecular mechanics calculations, show that different minima are preferred as the R group changes. These conformations are identified, their populations are determined, and the barriers to their interconversions are measured. In particular when R is a tert-butyl group, two atropisomers (with the OMe moiety near the 2- or 8-position) could be physically separated and their structures determined by NOE experiments in solution and X-ray diffraction in the solid state. Each of these exists as a pair of stereolabile enantiomers, with a barrier of 9-10 kcal mol(-1) for interconversion.
• RESIST UNDERLAYER FILM COMPOSITION, PROCESS FOR FORMING RESIST UNDERLAYER FILM, PATTERNING PROCESS AND FULLERENE DERIVATIVE
  申请人：Watanabe Takeru

  公开号：US20110195362A1

  公开（公告）日：2011-08-11

  There is disclosed a resist underlayer film composition of a multilayer resist film used in lithography including (A) a fullerene derivative having a carboxyl group protected by a thermally labile group and (B) an organic solvent. There can be a resist underlayer film composition of a multilayer resist film used in lithography for forming a resist underlayer in which generation of wiggling in substrate etching can be highly suppressed and the poisoning problem in forming an upper layer pattern using a chemically amplified resist can be avoided, a process for forming the resist underlayer film, a patterning process and a fullerene derivative.
• US5955509A
  申请人：——

  公开号：US5955509A

  公开（公告）日：1999-09-21
• US8835092B2
  申请人：——

  公开号：US8835092B2

  公开（公告）日：2014-09-16
• New Compounds. Oxime of Furfuralacetone
  作者：Richard Kleene

  DOI：10.1021/ja01857a077

  日期：1941.12