Tetratert-butylazanium

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Tetratert-butylazanium
• 化学式: C16H36N+
• 分子量: 242.46
• InChiKey: FIAACKZFQSUQEN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

文献信息

• Use of an ionic liquid for storing hydrogen
  申请人：VTU Holding GmbH

  公开号：EP2623457A1

  公开（公告）日：2013-08-07

  Method of storing hydrogen by forming a first ionic liquid by inducing a borohydride in a second ionic liquid comprising a cation and an anion comprising borate, and forming the second ionic liquid by releasing the hydrogen out of the first ionic liquid by using water and/or a catalyst, which method is characterized in that the first and the second ionic liquid are both water miscible and the second ionic liquid is separated, particularly is salted out, from solution in water by adding a separation inducer; certain ionic liquids for storing and releasing hydrogen comprising a borohydride or for preparing a ionic liquid for storing and releasing hydrogen comprising a borate; and a process for preparing ionic liquids for storing and releasing hydrogen comprising a borohydride.

  通过在包含阳离子和包含硼酸盐的阴离子的第二离子液体中引入硼氢化物形成第一离子液体的方法来存储氢气，并通过使用水和/或催化剂从第一离子液体释放氢气形成第二离子液体，该方法的特征在于第一和第二离子液体均与水相溶，并且通过添加分离诱导剂从水溶液中分离第二离子液体，特别是通过盐析；某些用于存储和释放氢气的离子液体，包括硼氢化物，或用于制备含硼酸盐的存储和释放氢气的离子液体；以及用于制备含硼氢化物的存储和释放氢气的离子液体的过程。
• Fast-curing benzoxazine compounds
  申请人：Henkel AG & Co. KGaA

  公开号：EP2314579A1

  公开（公告）日：2011-04-27

  The present invention relates to a specific benzoxazine compound A of formula (I), wherein q is an integer from 1 to 4, M is hydrogen, a monovalent cation, or an equivalent of a polyvalent cation, Z is selected from the group consisting of a direct bond (when q is 2), hydrogen (when q is 1), alkyl (when q is 1), alkylene (when q is 2 to 4), carbonyl (when q is 2), oxygen (when q is 2), thiol (when q is 1), sulfur (when q is 2), sulfoxide (when q is 2), and sulfone (when q is 2), R6 is a linear or branched divalent alkylene group, comprising 1 to 15 carbon atoms, which may be interrupted by one or more heteroatom(s), selected from oxygen, nitrogen and sulfur, and R5 is selected from hydrogen, halogen, alkyl, alkenyl or R5 is a divalent residue creating a naphthoxazine residue out of the benzoxazine structure. A further object of the present invention is a polymerizable composition and a cured product obtained from the polymerizable composition, wherein said composition comprises at least one benzoxazine compound A and at least one benzoxazine compound B, which is different from benzoxazine compound A.

  本发明涉及一种特定的苯并噁啉化合物A，其化学式为(I)，其中q为1到4的整数，M为氢、一价阳离子或多价阳离子的等价物，Z选自以下组成的一组：直接键（当q为2时）、氢（当q为1时）、烷基（当q为1时）、烷烃（当q为2到4时）、酰基（当q为2时）、氧（当q为2时）、硫醇（当q为1时）、硫（当q为2时）、亚砜（当q为2时）和砜（当q为2时），R6为线性或支链的二价烷基烷基，包括1到15个碳原子，可以被一个或多个氧、氮和硫等杂原子打断，R5选自氢、卤素、烷基、烯基或R5是一个二价残基，使苯并噁啉结构变为萘噁啉残基。本发明的另一个目的是一种可聚合的组合物和从该可聚合组合物获得的固化产物，其中所述组合物至少包括一种苯并噁啉化合物A和至少一种与苯并噁啉化合物A不同的苯并噁啉化合物B。
• USE OF AN IONIC LIQUID FOR STORING HYDROGEN
  申请人：VTU HOLDING GMBH

  公开号：US20150048275A1

  公开（公告）日：2015-02-19

  Method of storing hydrogen by forming a first ionic liquid by inducing a borohydride in a second ionic liquid comprising a cation and an anion comprising borate, and forming the second ionic liquid by releasing the hydrogen out of the first ionic liquid by using water and/or a catalyst, which method is characterized in that the first and the second ionic liquid are both water miscible and the second ionic liquid is separated, particularly is salted out, from solution in water by adding a separation inducer; certain ionic liquids for storing and releasing hydrogen comprising a borohydride or for preparing a ionic liquid for storing and releasing hydrogen comprising a borate; and a process for preparing ionic liquids for storing and releasing hydrogen comprising a borohydride.

  通过在含有阳离子和含硼酸盐的阴离子的第二种离子液体中引入硼氢化物形成第一种离子液体的方法，通过使用水和/或催化剂从第一种离子液体中释放氢并形成第二种离子液体，该方法的特点在于第一种和第二种离子液体均可溶于水，而第二种离子液体通过添加分离诱导剂从水溶液中分离，特别是盐析；用于储存和释放氢的某些含硼氢化物的离子液体，或用于制备含硼酸盐的储存和释放氢的离子液体；以及制备含硼氢化物的储存和释放氢的离子液体的方法。
• Soluble aniline conducting polymers
  申请人：NITTO CHEMICAL INDUSTRY CO., LTD.

  公开号：EP0662694A2

  公开（公告）日：1995-07-12

  A soluble aniline conducting polymer characterized in that said conductive polymer comprises as a repeating unit an alkoxyl group-substituted aminobenzenesulfonic acid, its alkali metal salts, ammonium salts and/or substituted ammonium salts, and is a solid having a weight average molecular weight of about 1900 or more at room temperature, a conductive composition and electric conductor comprising the same, and a method for producing a soluble aniline conducting polymer having a weight average molecular weight of 10,000 t 3,240,000 characterized by polymerizing at least one compound (1) selected from the group consisting of an acidic group-substituted aniline, its alkali metal salts, ammonium salts and substituted ammonium salts in a solution containing a basic compound (2) using an oxidizing agent.

  一种可溶性苯胺导电聚合物，其特征在于所述导电聚合物包括作为重复单元的烷氧基基取代的氨基苯磺酸、其碱金属盐、铵盐和/或取代铵盐，并且是一种在室温下重量平均分子量约为 1900 或更高的固体，导电组合物和电导体由其组成、以及一种生产可溶性苯胺导电聚合物的方法，该聚合物的重量平均分子量为 10,000 t 3,240,000 ，其特征在于至少一种选自酸性基团取代的苯胺、其碱金属盐、铵盐和取代铵盐组成的化合物(1)在含有碱性化合物(2)的溶液中使用氧化剂聚合。
• Method for producing soluble conductive polymer having acidic groups
  申请人：NITTO CHEMICAL INDUSTRY CO., LTD.

  公开号：EP0834885A2

  公开（公告）日：1998-04-08

  A method for producing a soluble conductive polymer having acidic groups, which comprises subjecting to electrolytic polymerization (a) at least one compound selected from the group consisting of acidic group-substituted anilines, acidic group-substituted pyrroles, acidic group-substituted thiophenes, acidic group-substituted furans, acidic group-substituted selenophenes, acidic group-substituted tellurophenes, acidic group-substituted isothianaphthenes, acidic group-substituted isobenzofurans, acidic group-substituted isoindolines, acidic group-substituted isobenzoselenophenes, acidic group-substituted isobenzotellurophenes, and their metal salts, ammonium salts and substituted ammonium salts in a solution containing (b) a basic compound.

  一种生产具有酸性基团的可溶性导电聚合物的方法，该方法包括将 (a) 至少一种选自由酸性基团取代的苯胺、酸性基团取代的吡咯、酸性基团取代的噻吩、酸性基团取代的呋喃、酸性基团取代的硒吩组成的组中的化合物进行电解聚合； (b) 至少一种选自由酸性基团取代的苯胺、酸性基团取代的吡咯、酸性基团取代的噻吩、酸性基团取代的呋喃、酸性基团取代的硒吩组成的组中的化合物进行电解聚合、酸性基团取代的碲苯酚、酸性基团取代的异噻吩、酸性基团取代的异苯并呋喃、酸性基团取代的异吲哚啉、酸性基团取代的异苯并硒吩、酸性基团取代的异苯并呋喃，以及它们的金属盐、铵盐和取代铵盐，在含有 (b) 碱性化合物的溶液中。