6H-菲并[3,2-b]吡喃-3-醇,5,10-二氢-4,7-二甲氧基-10,10-二甲基-6-(1-甲基乙烯基)-,(6R)- | 138195-70-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 萘并吡喃类
• 中文名称: 6H-菲并[3,2-b]吡喃-3-醇,5,10-二氢-4,7-二甲氧基-10,10-二甲基-6-(1-甲基乙烯基)-,(6R)-
• 英文名称: cedrelin B
• 英文别名: (6R)-4,7-dimethoxy-10,10-dimethyl-6-prop-1-en-2-yl-5,6-dihydronaphtho[2,1-g]chromen-3-ol
• CAS: 138195-70-7
• 化学式: C₂₄H₂₆O₄
• 分子量: 378.468
• InChiKey: RMFYWBHJYRTCMB-MRXNPFEDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.48
• 重原子数：
  28.0
• 可旋转键数：
  3.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  47.92
• 氢给体数：
  1.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  重氮甲烷 、 (-)-cedrelin A 生成 (R)-6-Isopropenyl-3,4-dimethoxy-10,10-dimethyl-5,10-dihydro-6H-11-oxa-benzo[a]anthracen-7-ol 、 6H-菲并[3,2-b]吡喃-3-醇,5,10-二氢-4,7-二甲氧基-10,10-二甲基-6-(1-甲基乙烯基)-,(6R)- 、 (R)-6-Isopropenyl-3,4,7-trimethoxy-10,10-dimethyl-5,10-dihydro-6H-11-oxa-benzo[a]anthracene
  参考文献：
  名称：

  New dihydrophenanthrapyrans from cedrelinga catenaeformis

  摘要：

  Two new dihydrophenanthrapyrans 1 and 2 have been isolated from Cedrelinga catenaeformis Duke (Leguminoseae), and their structures and absolute configurations have been determined by NMR and CD spectroscopy; chemical correlation of them with paralycolin A, which had been obtained from Clusia paralycola, has led to revision of the structure of the latter compound.

  DOI：

  10.1016/0040-4039(91)85088-m

文献信息

• New dihydrophenanthrapyrans from cedrelinga catenaeformis
  作者：Katushi Ezaki、Motoyoshi Satake、Takenori Kusumi、Hiroshi Kakisawa

  DOI：10.1016/0040-4039(91)85088-m

  日期：1991.6

  Two new dihydrophenanthrapyrans 1 and 2 have been isolated from Cedrelinga catenaeformis Duke (Leguminoseae), and their structures and absolute configurations have been determined by NMR and CD spectroscopy; chemical correlation of them with paralycolin A, which had been obtained from Clusia paralycola, has led to revision of the structure of the latter compound.