苯,苯酚 | 100518-55-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 中文名称: 苯,苯酚
• 中文别名: 苯酚,加合苯(1:1)
• 英文名称: phenol-benzene
• 英文别名: phenol-benzene complex；phenol-benzene dimer；Phenol * Benzol；Benzene.phenol；benzene;phenol
• CAS: 100518-55-6
• 化学式: C₆H₆O*C₆H₆
• 分子量: 172.227
• InChiKey: RRTCFFFUTAGOSG-UHFFFAOYSA-N

物化性质

• 熔点：
  179 °C(Solv: ethanol (64-17-5))

计算性质

• 辛醇/水分配系数(LogP)：
  3.08
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  苯,苯酚 以 水 为溶剂， 生成 苯 、 苯酚
  参考文献：
  名称：

  苯酚二聚体在稀水溶液中的热力学性质

  摘要：

  苯和苯酚在水中的稀溶液在 15、25、35 和 45°C 下获得了精确的蒸气压溶解度测量值。所有结果都与质量作用模型一致，该模型将理想溶液行为的偏差归因于苯二聚体和苯与苯酚之间的异二聚体的形成。苯酚二聚体在 25°C 时吸热形成，具有非常大的负热容，并且在大约 35°C 时形成常数达到最大值 0.66 l-mol-1。报告了苯酚二聚体的热力学性质，并与认为主要通过疏水相互作用稳定的其他聚集体的热力学性质进行了比较。

  DOI：

  10.1007/bf01150440

文献信息

• TRANSITION METAL CATALYSTS FOR C-O HYDROGENOLYSIS AND HYDRODEOXYGENATION
  申请人：GOVERNORS OF THE UNIVERSITY OF ALBERTA

  公开号：US20140179954A1

  公开（公告）日：2014-06-26

  Phosphoranimide-metal catalysts and their role in C—O bond hydrogenolysis and hydrodeoxygenation (HDO) are disclosed. The catalysts comprise of first row transition metals such as nickel, cobalt and iron. The catalysts have a metal to anionic phosphoranimide ratio of 1:1 and catalyze C—O bond hydrogenolyses of a range of oxygen-containing organic compounds under lower temperature and pressure conditions than those commonly used in industrial hydrodeoxygenation.

  磷胺酰胺金属催化剂及其在C—O键氢解和脱氧（HDO）中的作用被披露。这些催化剂包括镍、钴和铁等第一行过渡金属。这些催化剂的金属与阴离子磷胺酰胺的比例为1:1，并且在比工业脱氧反应常用的温度和压力条件下，催化了一系列含氧有机化合物的C—O键氢解。
• METHODS OF USING PHENOLIC FATTY ACID COMPOUND ON A NON-PHENOLIC POLYMER
  申请人：SI GROUP, INC.

  公开号：US20170204559A1

  公开（公告）日：2017-07-20

  This invention relates to a process for making phenolic fatty acid compounds having a reduced phenolic ester content. The invention also relates to method for chemically bonding a phenolic resin with a non-phenolic polymer (e.g., a synthetic fabric). The method comprises contacting a phenolic fatty acid compound with a non-phenolic polymer to introduce a hydroxy phenyl functional group into the non-phenolic polymer; and reacting the hydroxy phenyl functional group contained in the non-phenolic polymer with a phenolic resin or a phenolic crosslinker composition capable of forming a phenolic resin, to chemically bond the phenolic resin with the non-phenolic polymer. The invention is particularly useful for making a synthetic fabric-reinforced article, such as synthetic fabric-reinforced rubber article, circuit board substrate, or fiberglass.

  本发明涉及一种制备酚脂肪酸化合物的方法，其具有降低酚酸酯含量的特点。本发明还涉及一种将酚树脂与非酚聚合物（例如合成织物）化学键合的方法。该方法包括将酚脂肪酸化合物与非酚聚合物接触，以将羟基苯基功能基引入非酚聚合物中；并使非酚聚合物中所含的羟基苯基功能基与能够形成酚树脂的酚树脂或酚交联剂组合物反应，以将酚树脂与非酚聚合物化学键合。本发明特别适用于制备合成织物增强的制品，如合成织物增强橡胶制品、电路板基板或玻璃纤维制品。
• Novel microorganism and method for producing oxygenous compounds with said microorganism
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0263403A2

  公开（公告）日：1988-04-13

  Novel Methylococcus sp. SIM-222 (FERM BP-1470) is capable of being grown in the presence of methane, using peptone or casamino acid as the nitrogen source. A method for producing oxygenous compounds is provided, wherein said Methylococcus sp. SIM-222 is brought into catalytic contact with an oxidiz­able organic compound containing at least two carbon atoms under aerobic conditions.

  新型甲基球菌SIM-222（FERM BP-1470）能够在甲烷存在下生长，使用蛋白胨或 casamino 酸作为氮源。提供了一种生产含氧化合物的方法，其中所述甲基球菌 SIM-222 在有氧条件下与至少含有两个碳原子的可氧化有机化合物进行催化接触。
• Process for preparing cation exchange resins having improved stability and cation exchange resins prepared therefrom
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0366258A1

  公开（公告）日：1990-05-02

  Cation exchange resins with improved stability prepared by treating the resins with an antioxidant are disclosed. Examples of the antioxidant are 2,b-di-t-­butyl-4-methylphenol and 2,b-di-t-butyl-α-dimethylamino-­p-cresol. The cation exchange resins of the present invention are useful for water treatment, purification of food and pharmaceutical products, catalysis and the like.

  本发明公开了通过用抗氧化剂处理树脂而制备的稳定性更好的阳离子交换树脂。抗氧化剂的例子有 2,b-二叔丁基-4-甲基苯酚和 2,b-二叔丁基-α-二甲基氨基对甲酚。本发明的阳离子交换树脂可用于水处理、食品和药品的净化、催化等。
• Diaryl ethers by dehydration of phenols using a catalyst comprising supported partially reduced tungsten (VI) oxide
  申请人：UOP

  公开号：EP0584415A1

  公开（公告）日：1994-03-02

  Diaryl ethers are prepared by dehyrating phenols or derivatives of phenol in the presence of a catalyst comprising a composite of partially reduced tungsten oxide on alumina, zirconia, or titania where the composite has been prepared by reduction with hydrogen at a temperature between 250 and 450oC and where the dehydration reaction is performed at a temperature of 350 to 550oC.

  二芳基醚的制备方法是：苯酚或苯酚衍生物在由氧化铝、氧化锆或二氧化钛上的部分还原氧化钨复合材料组成的催化剂存在下进行脱氢反应，该复合材料是在 250 至 450 摄氏度的温度下用氢气还原制备的，脱水反应在 350 至 550 摄氏度的温度下进行。