3,15-Bis(tetradec-1-ynyl)-12,24-dithiahexacyclo[11.11.0.02,11.04,9.014,23.016,21]tetracosa-1(13),2,4,6,8,10,14,16,18,20,22-undecaene | 1422031-98-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 3,15-Bis(tetradec-1-ynyl)-12,24-dithiahexacyclo[11.11.0.02,11.04,9.014,23.016,21]tetracosa-1(13),2,4,6,8,10,14,16,18,20,22-undecaene
• 英文别名: 3,15-bis(tetradec-1-ynyl)-12,24-dithiahexacyclo[11.11.0.02,11.04,9.014,23.016,21]tetracosa-1(13),2,4,6,8,10,14,16,18,20,22-undecaene
• CAS: 1422031-98-8
• 化学式: C₅₀H₆₀S₂
• 分子量: 725.158
• InChiKey: NHXRQBAVSJEVDS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  20.5
• 重原子数：
  52
• 可旋转键数：
  22
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.48
• 拓扑面积：
  56.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1-十四炔 在 正丁基锂 、 bis-triphenylphosphine-palladium(II) chloride 、 二氯(N,N,N',N'-四甲基乙二胺)锌(II) 作用下， 以 正己烷 、 甲苯 为溶剂， 反应 12.0h， 以12.2%的产率得到3,15-Bis(tetradec-1-ynyl)-12,24-dithiahexacyclo[11.11.0.02,11.04,9.014,23.016,21]tetracosa-1(13),2,4,6,8,10,14,16,18,20,22-undecaene
  参考文献：
  名称：

  EP2740735

  摘要：

  公开号：

文献信息

• TWI580683
  申请人：——

  公开号：——

  公开（公告）日：——
• CONDENSED POLYCYCLIC AROMATIC COMPOUND, AROMATIC POLYMER, AND METHOD FOR SYNTHESIZING AROMATIC COMPOUND
  申请人：Ikeda Yoshinori

  公开号：US20140187792A1

  公开（公告）日：2014-07-03

  Provided is a condensed polycyclic aromatic compound that can be used as a precursor for synthesizing a condensed polycyclic aromatic compound having relatively high solubility. Also provided is a method for synthesizing and using such a novel condensed polycyclic aromatic compound. The condensed polycyclic aromatic compound is represented by formula (II): (II) (where X 1 and X 2 are each independently selected from the group consisting of a hydrogen atom, halogen atom, alkyl group, and the like, but at least one of X 1 and X 2 is a halogen atom; B is a condensed ring having at least one benzene ring moiety; each Y is independently selected from chalcogens; and A 1 through A 4 are each independently selected from the group consisting of hydrogen atoms, halogen atoms, alkyl groups, and the like and two adjacent atoms or groups can bond together to form an aromatic group.)
• ORGANIC SEMICONDUCTOR SOLUTION AND ORGANIC SEMICONDUCTOR FILM
  申请人：TEIJIN LIMITED

  公开号：US20150236269A1

  公开（公告）日：2015-08-20

  The present invention provides an organic semiconductor solution that can produce an organic semiconductor film having acceptable semiconductor properties while endowed with improved film-forming properties due to substantial polymer content. This organic semiconductor solution contains an organic solvent as well as a polymer and an organic semiconductor precursor dissolved in the organic solvent. The proportion of the polymer in relation to the total of the polymer and the organic semiconductor precursor is equal to or greater than 3 mass %. The organic semiconductor precursor has a structure in which a dienophile-type alkene is eliminably bonded through a double bond thereof to the benzene ring of an organic semiconductor compound represented by formula I) (where A 1 to A 8 and E 1 to E 4 are independently selected from the group consisting of hydrogen atoms, halogen atoms, C 1 to C 20 alkyl groups, and the like, and Y represents sulfur or selenium).
• US8829202B2
  申请人：——

  公开号：US8829202B2

  公开（公告）日：2014-09-09
• EP2740735
  申请人：——

  公开号：——

  公开（公告）日：——