Mor-pholino-Biguanid

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Mor-pholino-Biguanid
• 英文别名: 1-(diaminomethylidene)-2-morpholin-4-ylguanidine
• 化学式: C₆H₁₄N₆O
• 分子量: 186.22
• InChiKey: WNGAJIBLMRTWND-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.6
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  115
• 氢给体数：
  3
• 氢受体数：
  3

文献信息

• CURABLE COMPOSITION AND CURED MATERIAL
  申请人：Kaneka Corporation

  公开号：EP2267083A1

  公开（公告）日：2010-12-29

  An object of the present invention is to provide a curable composition which is excellent in curability and storage stability without an organotin curing catalyst which is known to be toxic. In order to achieve this object, the present inventors have studied to find that a curable composition comprising: (A) an organic polymer having a silicon-containing group cross-linkable by siloxane bond formation (reactive silyl group); (B) a guanidine compound; and (C) a methyl ester group-containing compound is effective. In addition, the present inventors have found that a cured product of this curable composition has good physical properties. Thereby, the present inventors have completed the present invention.

  本发明的目的是提供一种固化组合物，该组合物不使用已知有毒的有机锡固化催化剂，而具有极佳的固化性和贮存稳定性。为了实现这一目标，本发明者经过研究发现，一种包含以下成分的可固化组合物是有效的：(A) 具有可通过硅氧烷键形成交联的含硅基团（活性硅基）的有机聚合物；(B) 一种胍类化合物；(C) 一种含甲酯基团的化合物。此外，本发明者还发现这种可固化组合物的固化产品具有良好的物理性能。因此，本发明者完成了本发明。
• ADHESIVE-BONDED STRUCTURE COMPRISING BOTH ADHESIVE COMPOSITION AND WOOD MATERIAL
  申请人：Kaneka Corporation

  公开号：EP2684690A1

  公开（公告）日：2014-01-15

  The present invention provides a bonded structure that includes a wood material and a curable composition prepared from a reactive silyl group-containing polymer and that has high strength and boiling water resistance. The reactive silyl group-containing polymer is an environmentally friendly material having less toxicity. The use of a reactive silyl group-containing organic polymer containing a (meth)acrylate polymer and a polyoxyalkylene polymer with specific structures provides a curable composition having high strength and a high modulus, leading to the formation of a bonded structure including the composition and a wood material, which is excellent in strength and boiling water resistance. Thus, the above problem can be solved.

  本发明提供了一种粘合结构，它包括木质材料和由含活性硅基聚合物制备的可固化组合物，具有高强度和耐沸水性。含活性硅基的聚合物是一种毒性较低的环保材料。使用含有具有特定结构的（甲基）丙烯酸酯聚合物和聚氧亚烷基聚合物的含反应性硅烷基有机聚合物，可获得具有高强度和高模量的可固化组合物，从而形成包括该组合物和木质材料的粘合结构，该结构具有优异的强度和耐沸水性。从而解决了上述问题。
• CURABLE COMPOSITION, AND CURED SYNTHETIC RESIN USING SAME
  申请人：Mie University

  公开号：EP2837660A1

  公开（公告）日：2015-02-18

  [Problem] To provide a curable composition having high stability and excellent curing properties. [Solution] The present invention relates to a curable composition, and a cured synthetic resin using same, that functions as a curing catalyst for a synthetic resin. The curable composition contains (A) a titanium alkoxide, (B) a bidentate organic chelating agent that stabilizes the titanium alkoxide and (C) a guanidine compound. The molar ratio of the titanium alkoxide (A), the bidentate organic chelating agent (B), and the guanidine compound (C) is 1:0.5-3:0.5-2.

  [问题]提供一种具有高稳定性和优异固化性能的固化组合物。 [解决方案] 本发明涉及一种可固化组合物和使用该组合物固化的合成树脂，该组合物可用作合成树脂的固化催化剂。固化组合物包含（A）氧化钛，（B）稳定氧化钛的双齿有机螯合剂和（C）胍类化合物。氧化钛（A）、双叉有机螯合剂（B）和胍化合物（C）的摩尔比为 1:0.5-3:0.5-2。
• POLYMER BLEND, COMPOSITION, SEALANT, AND SEALANT FOR TIRE
  申请人：KANEKA CORPORATION

  公开号：EP3936569A1

  公开（公告）日：2022-01-12

  Provided are: a polymer blend which includes an organic polymer having a reactive silicon-containing group and which can give cured objects excellent in terms of elongation property and stress relaxation; a composition comprising the polymer blend, a specific filler, and a curing catalyst; a sealant comprising the composition; and a sealant for tires. A polymer blend which includes an organic polymer having a bifunctional reactive silicon-containing group of a specific structure is mixed with given proportions of a polyoxyalkylene (A) which has a number-average molecular weight of 13,000 or higher and 100,000 or lower, has a reactive-silicon-containing-group equivalent Eqa of 0.010 mmol/g or more and 0.29 mmol/g or less, and contains more than one silicon-containing group per molecule and a polyoxyalkylene (B) which has a number-average molecular weight of 3,000 or higher and 25,000 or lower, has a reactive-silicon-containing group only at one end, and has a reactive-silicon-containing-group equivalent Eqb of 0.03 mmol/g or more and 0.58 mmol/g or less.

  本文提供了：一种聚合物混合物，其中包括一种具有含硅活性基团的有机聚合物，该聚合物混合物可使固化物具有优异的伸长性能和应力松弛性能；一种组合物，其中包括该聚合物混合物、一种特定填料和一种固化催化剂；一种密封剂，其中包括该组合物；以及一种轮胎密封剂。一种聚合物混合物，它包括具有特定结构的双官能团活性含硅基团的有机聚合物与给定比例的聚氧亚烷基 (A) 混合，聚氧亚烷基 (A) 的数均分子量为 13,000 或以上和 100,000 或以下，其活性含硅基团当量 Eqa 为 0.010 mmol/g 或以上和 0.29 mmol/g 或更低，且每个分子含有一个以上的含硅基团，以及聚氧亚烷基 (B) 的数均分子量为 3,000 或更高，25,000 或更低，仅在一端具有活性含硅基团，且活性含硅基团当量 Eqb 为 0.03 mmol/g 或更高，0.58 mmol/g 或更低。
• CURABLE COMPOSITION AND CURED PRODUCT THEREOF
  申请人：Kaneka Corporation

  公开号：EP4105262A1

  公开（公告）日：2022-12-21

  Provided is a non-organotin curable composition containing: (A) an organic polymer having a reactive silicon group-containing structure represented by at least one of specified formulae (1) to (6); (B) an amidine compound having a melting point lower than 23°C; and (C) an acid anhydride and/or a carboxylic acid having a pKa of 3 to 5. Preferably, the content of the amidine compound (B) is from 0.1 to 15 parts by weight and the content of the acid anhydride and/or carboxylic acid (C) is from 0.1 to 15 parts by weight per 100 parts by weight of the organic polymer (A).

  本发明提供了一种非有机锡固化组合物，该组合物含有：(A)一种有机聚合物，该聚 合物具有由指定式(1)至(6)中的至少一个所代表的含硅活性基团结构；(B)一种脒 化物，该化合物的熔点低于 23°C；以及(C)一种酸酐和/或一种 pKa 为 3 至 5 的羧酸。最好是每 100 重量份的有机聚合物（A）中，脒化合物（B）的含量为 0.1 至 15 重量份，酸酐和/或羧酸（C）的含量为 0.1 至 15 重量份。