2-hydrazono-3-methyl-2,3-dihydrobenzothiazole-6-sulfonic acid

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻唑类
• 英文名称: 2-hydrazono-3-methyl-2,3-dihydrobenzothiazole-6-sulfonic acid
• 英文别名: 2-hydrazinyl-3-methyl-1,3-benzothiazol-3-ium-6-sulfonate
• 化学式: C₈H₉N₃O₃S₂
• 分子量: 259.31
• InChiKey: VIXNDJFXFKTXAR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  16
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  130
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2-hydrazono-3-methyl-2,3-dihydrobenzothiazole-6-sulfonic acid 、 在 potassium carbonate 、 硫酸二甲酯 作用下， 以 乙腈 为溶剂， 反应 12.0h， 生成 3-methyl-2-{[3-(4-vinylbenzyl)-3H-benzothiazol-2-ylidene]hydrazono}-2,3-dihydrobenzothiazole-6-sulfonic acid
  参考文献：
  名称：

  Two Polymerizable Derivatives of 2,2‘-Azino-bis(3-ethylbenzthiazoline-6-sulfonic acid)

  摘要：

  A versatile strategy for the synthesis of polymerizable derivatives of the redox-active indicator dye 2,2'-azino-bis(3-ethylbenzthiazoline-6-sulfonic acid) (ABTS) is reported. Two products are shown to illustrate how the final step in the synthetic strategy can be used to alter the physical properties of the product. Both products were characterized spectroscopically and electrochemically. The hydrophilic monomer (sABTS) was polymerized, and the utility of this polymer (polyABTS) is demonstrated in the context of bioelectrocatalysis.

  DOI：

  10.1021/ol0513443

文献信息

• Two Polymerizable Derivatives of 2,2‘-Azino-bis(3-ethylbenzthiazoline-6-sulfonic acid)
  作者：Jiangfeng Fei、Amit Basu、Fengtian Xue、G. Tayhas R. Palmore

  DOI：10.1021/ol0513443

  日期：2006.1.1

  A versatile strategy for the synthesis of polymerizable derivatives of the redox-active indicator dye 2,2'-azino-bis(3-ethylbenzthiazoline-6-sulfonic acid) (ABTS) is reported. Two products are shown to illustrate how the final step in the synthetic strategy can be used to alter the physical properties of the product. Both products were characterized spectroscopically and electrochemically. The hydrophilic monomer (sABTS) was polymerized, and the utility of this polymer (polyABTS) is demonstrated in the context of bioelectrocatalysis.