9,9-二甲基-2,7-双[N-(1-萘基)-N-苯基氨基]芴 | 222319-05-3

• 物质功能分类: 材料化学
• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 9,9-二甲基-2,7-双[N-(1-萘基)-N-苯基氨基]芴
• 英文名称: N,N'-bis(naphthalen-1-yl)-N,N'-bis(phenyl)-2,7-diamino-9,9-dimethyl-fluorene
• 英文别名: N,N'-di(naphthalen-1-yl)-N,N'-bis(phenyl)-2,7-diamino-9,9-dimethylfluorene；N,N'-di(naphthalen-1-yl)-N,N'-diphenyl-2,7-diamino-9,9-dimethaneylfluorene；N,N'-di(naphthalene-1-yl)-N,N'-diphenyl-2,7-diamino-9,9-dimethylfluorene；N,N'-diphenyl-N,N'-di(1''-naphthyl)-2,7-diamino-9,9-dimethyl-9H-fluorene；N,N'-Bis(naphthalen-1-yl)-N,N'-diphenyl-2,7-diamino-9,9-dimethylfluoren；N,N'-di(naphthalen-1-yl)-N,N'-diphenyl-2,7-diamino-9,9-dimethylfluorene；9,9-Dimethyl-N,N'-di(1-naphthyl)-N,N'-diphenyl-9H-fluorene-2,7-diamine；2,7-bis[N-(1'-naphthyl)-N-phenylamino]-9,9-dimethylfluorene；9,9-dimethyl-2,7-bis[N-(1'-naphthyl)-N-phenylamino]fluorene；2,7-bis[N-phenyl-N-(1-naphthyl)amino]-9,9-dimethylfluorene；2,7-bis[N-(1-naphthyl)anilino]-9,9-dimethylfluorene；2,7-bis(naphthylphenylamino)-9,9-dimethylfluorene；2,7-di[naphthylphenyl-amino]-9,9-dimethylfluorene；9,9-Dimethyl-2,7-bis[n-(1-naphthyl)-N-phenylamino]fluorene；9,9-dimethyl-2-N,7-N-dinaphthalen-1-yl-2-N,7-N-diphenylfluorene-2,7-diamine
• CAS: 222319-05-3
• 化学式: C₄₇H₃₆N₂
• 分子量: 628.816
• InChiKey: KJEQVQJWXVHKGT-UHFFFAOYSA-N

物化性质

• 熔点：
  265-270°C
• 密度：
  1?+-.0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  13.4
• 重原子数：
  49
• 可旋转键数：
  6
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• WGK Germany：
  3

文献信息

• ORGANIC ELECTROLUMINESCENCE ELEMENT AND ELECTRONIC APPARATUS
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20210005826A1

  公开（公告）日：2021-01-07

  An organic electroluminescence device comprising a cathode, an anode and an organic layer disposed between the cathode and the anode, wherein the organic layer comprises a fluorescent emitting layer and the fluorescent emitting layer comprises a first compound, a second compound having a hole mobility larger than that of the first compound, and a dopant material showing a fluorescent spectrum with a half width of 30 nm or less; and an organic electroluminescence device comprising a cathode, an anode and an organic layer disposed between the cathode and the anode, wherein the organic layer comprises a fluorescent emitting layer and the fluorescent emitting layer comprises a first compound, a third compound having an affinity larger than that of the first compound, and a dopant material showing a fluorescent spectrum with a half width of 30 nm or less and the content of the third compound in the fluorescent emitting layer is less than that of the first compound in the fluorescent emitting layer are excellent in their performance.

  一种有机电致发光装置，包括阴极、阳极以及设置在阴极和阳极之间的有机层，其中所述有机层包括荧光发射层，且所述荧光发射层包括第一化合物、第二化合物和掺杂材料，所述第二化合物的空穴迁移率大于所述第一化合物，且所述掺杂材料显示的荧光光谱半宽为30纳米或更小；以及一种有机电致发光装置，包括阴极、阳极以及设置在阴极和阳极之间的有机层，其中所述有机层包括荧光发射层，且所述荧光发射层包括第一化合物、第三化合物和掺杂材料，所述第三化合物与所述第一化合物的亲和力更大，且所述掺杂材料显示的荧光光谱半宽为30纳米或更小，且所述第三化合物在荧光发射层中的含量小于所述第一化合物在荧光发射层中的含量，这些装置的性能都十分出色。
• AROMATIC AMINE DERIVATIVES AND ELECTROLUMINESCENCE DEVICE USING THE SAME
  申请人：Kawamura Masahiro

  公开号：US20070029927A1

  公开（公告）日：2007-02-08

  An aromatic amine derivative with a specific structure and an organic electroluminescence device which comprises at least one organic thin film layer comprising a light emitting layer sandwiched between a pair of electrode consisting of an anode and a cathode, wherein at least one of the organic thin film layer comprises the aromatic amine derivative singly or as its mixture component. The organic electroluminescence device which exhibits an enhanced current efficiency of light emission and emits blue light with a prolonged lifetime is realized.

  一种具有特定结构的芳香胺衍生物和一种有机电致发光器件，该器件至少包括一个有机薄膜层，其中包括夹在由阳极和阴极组成的一对电极之间的发光层，其中至少一个有机薄膜层包括该芳香胺衍生物单独或作为其混合组分。实现了一种具有增强的发光电流效率并且发出蓝光并具有延长寿命的有机电致发光器件。
• Compound, organic electric element using the same, and an electronic device thereof
  申请人：DUK SAN NEOLUX CO., LTD.

  公开号：US10026905B2

  公开（公告）日：2018-07-17

  A compound represented by Formula 1. An organic electric element includes a first electrode, a second electrode, and an organic material layer including the compound of Formula 1. The organic material layer include a light emitting layer, a hole transport layer including a compound represented by Formula 2, and an emission-auxiliary layer including the compound represented by Formula 1. When the organic electric element includes the compound in the organic material layer, luminous efficiency, color purity, and life span can be improved.

  由公式1表示的化合物。一种有机电元件包括第一电极、第二电极和包括公式1所表示的化合物的有机材料层。有机材料层包括发光层、包括公式2所表示的化合物的空穴传输层，以及包括公式1所表示的化合物的发射辅助层。当有机电元件包括有机材料层中的该化合物时，可以改善发光效率、色彩纯度和寿命。
• ORGANIC COMPOUND, LIGHT EMITTING DIODE AND LIGHT EMITTING DEVICE HAVING THE COMPOUND
  申请人：LG Display Co., Ltd.

  公开号：US20200199090A1

  公开（公告）日：2020-06-25

  An organic compound having a tetraphenyl moiety and at least one fused hetero aryl moiety having at least one oxygen and/or sulfur on a ring and bonded to the tetraphenyl moiety directly or indirectly, and a light emitting diode and a light emitting device having the organic compound are disclosed. The organic compound has excellent thermal resistance property and hole mobility property. The organic compound can be incorporated into a hole transfer layer, an electron blocking layer and/or a charge generation layer of the light emitting diode. Therefore, the light emitting diode and light emitting device according to the present invention have decreased driving voltage and enhanced luminous efficiency.

  本发明公开了一种具有四苯基基团和至少一个融合的杂环芳基团的有机化合物，该杂环芳基团在环上至少含有一个氧和/或硫，并直接或间接地与四苯基基团结合，以及具有该有机化合物的发光二极管和发光器件。该有机化合物具有优异的热阻性能和空穴迁移性能。该有机化合物可以被纳入发光二极管的空穴传输层、电子阻挡层和/或电荷生成层中。因此，根据本发明的发光二极管和发光器件具有降低的驱动电压和增强的发光效率。
• Novel organic electroluminescent compounds and organic electroluminescent device using the same
  申请人：Gracel Display Inc.

  公开号：EP2098532A1

  公开（公告）日：2009-09-09

  The present invention relates to novel organic electroluminescent compounds exhibiting high luminous efficiency, and organic electroluminescent devices comprising the same. The organic electroluminescent compounds according to the invention are characterized in that they are represented by Chemical Formula (1):

  本发明涉及一种表现出高发光效率的新型有机电致发光化合物，以及包括它们的有机电致发光装置。本发明的有机电致发光化合物的特点在于它们由化学式（1）所表示：