1-(p-aminostyryl)naphthalene | 88909-87-9

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 1-(p-aminostyryl)naphthalene
• 英文别名: 4-[trans-2-(naphthyl-(1))-vinyl]-aniline；4-[trans-2-(Naphthyl-(1))-vinyl]-anilin；4-[(E)-2-naphthalen-1-ylethenyl]aniline
• CAS: 88909-87-9
• 化学式: C₁₈H₁₅N
• 分子量: 245.324
• InChiKey: VGVOEBVZADFNAQ-DHZHZOJOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  19
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-(p-aminostyryl)naphthalene 、 乙酸酐 反应 1.0h， 以92%的产率得到1-(p-acetylaminostyryl)naphthalene
  参考文献：
  名称：

  Synthesis of Aminochrysenes by the Oxidative Photocyclization of Acetylaminostilbenes.

  摘要：

  在碘和空气存在下，通过乙酰氨基二苯乙烯的氧化光环化反应，然后进行水解，合成了氨基二苯乙烯衍生物。

  DOI：

  10.1248/cpb.41.1853
• 作为产物：
  描述：

  1-萘基甲基膦酸二乙酯 在 palladium on activated charcoal sodium hydride 、 肼 作用下， 以 乙醇 为溶剂， 反应 2.75h， 生成 1-(p-aminostyryl)naphthalene
  参考文献：
  名称：

  Synthesis of Aminochrysenes by the Oxidative Photocyclization of Acetylaminostilbenes.

  摘要：

  在碘和空气存在下，通过乙酰氨基二苯乙烯的氧化光环化反应，然后进行水解，合成了氨基二苯乙烯衍生物。

  DOI：

  10.1248/cpb.41.1853

文献信息

• REMARKS ON THE SYNTHESIS OF SUBSTITUTED STILBENES AND DIPHENYLBUTADIENES
  作者：FELIX BERGMANN、MISS ZIPORAH WEINBERG

  DOI：10.1021/jo01201a013

  日期：1941.1
• ORGANIC EL DEVICE
  申请人：Nishimura Kazuki

  公开号：US20100044689A1

  公开（公告）日：2010-02-25

  A phosphorescent-emitting layer contains a phosphorescent host and a phosphorescent dopant for providing phosphorescence, and a fluorescent-emitting layer contains a fluorescent host and a fluorescent dopant for providing fluorescence. A charge blocking layer blocks electrons injected into the fluorescent host of the fluorescent-emitting layer from being injected toward the charge blocking layer from the fluorescent-emitting layer, and also injects holes into the fluorescent-emitting layer from the phosphorescent-emitting layer. A triplet energy gap Eg PD of the phosphorescent dopant of the phosphorescent-emitting layer, a triplet energy gap Eg EB of the charge blocking layer and a triplet energy gap Eg FH of the fluorescent host of the fluorescent-emitting layer satisfy the following formula (1). Eg PD
• ORGANIC EL ELEMENT AND ORGANIC EL MATERIAL-CONTAINING SOLUTION
  申请人：Nishimura Kazuki

  公开号：US20100270539A1

  公开（公告）日：2010-10-28

  An organic EL device ( 1 ) includes an anode ( 3 ), a cathode ( 4 ) and an organic thin-film layer ( 5 ) provided between the anode ( 3 ) and the cathode ( 4 ). The organic thin-film layer ( 5 ) includes a single-layered mixed-color emitting layer ( 51 ) for providing mixed-color emission. The mixed-color emitting layer ( 51 ) contains a host, a fluorescent dopant for blue fluorescent emission and a phosphorescent dopant for red or green phosphorescent emission.
• ORGANIC EL DEVICE AND ANTHRACENE DERIVATIVE
  申请人：NISHIMURA Kazuki

  公开号：US20130187143A1

  公开（公告）日：2013-07-25

  An organic EL device includes: an anode for injecting holes; a phosphorescent-emitting layer; a fluorescent-emitting layer; and a cathode for injecting electrons. The phosphorescent-emitting layer contains a phosphorescent host and a phosphorescent dopant for phosphorescent emission. The fluorescent-emitting layer contains a fluorescent host and a fluorescent dopant for fluorescent emission. The fluorescent host is at least one of an asymmetric anthracene derivative represented by a formula (1) below and a pyrene derivative represented by a formula (2) below.
• US8207526B2
  申请人：——

  公开号：US8207526B2

  公开（公告）日：2012-06-26