2,4,6-trimethyl-5-nitro-1,3-dioxane | 63275-14-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二恶烷
• 英文名称: 2,4,6-trimethyl-5-nitro-1,3-dioxane
• 英文别名: 2,4,6-Trimethyl-5-nitro-[1,3]dioxan
• CAS: 63275-14-9
• 化学式: C₇H₁₃NO₄
• 分子量: 175.185
• InChiKey: JYVNPSHCVNFQCG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  64.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  3-硝基-2,4-戊二醇 、 乙醛 在 硫酸 作用下， 以 苯 为溶剂， 反应 0.5h， 以71%的产率得到2,4,6-trimethyl-5-nitro-1,3-dioxane
  参考文献：
  名称：

  Aryl-NNO-azoxy-?-nitroalkanes

  摘要：

  Two methods of synthesis of aryl-NNO-azoxy-alpha-nitroalkanes bearing either one or two reactive hydrogen atoms alpha to the azoxy and nitro groups are described. These methods involve protection of the latter by easily removable groupings, those used being acetoxy-methyl and acetal fragments. The regiochemical nature of the diazene oxide groupings in aryl-NNO-azoxy-alpha-nitroalkanes obtained by oxidation of the appropriate diazenes has been established by heteronuclear NMR and x-ray structural examination. Some of the chemical properties of these diazene oxides have been examined.

  DOI：

  10.1007/bf00863827

文献信息

• Eckstein; Urbanski, Roczniki Chemii, 1952, vol. 26, p. 571,584, 585
  作者：Eckstein、Urbanski

  DOI：——

  日期：——
• Aryl-NNO-azoxy-?-nitroalkanes
  作者：O. A. Luk'yanov、Yu. B. Salamonov、A. G. Bass、V. S. Bogdanov、Yu. A. Strelenko、V. S. Kuz'min、Yu. T. Struchkov、Yu. N. Burtsev

  DOI：10.1007/bf00863827

  日期：1992.10

  Two methods of synthesis of aryl-NNO-azoxy-alpha-nitroalkanes bearing either one or two reactive hydrogen atoms alpha to the azoxy and nitro groups are described. These methods involve protection of the latter by easily removable groupings, those used being acetoxy-methyl and acetal fragments. The regiochemical nature of the diazene oxide groupings in aryl-NNO-azoxy-alpha-nitroalkanes obtained by oxidation of the appropriate diazenes has been established by heteronuclear NMR and x-ray structural examination. Some of the chemical properties of these diazene oxides have been examined.