D-酰化氨基酸水解酶 | 65979-42-2

• 物质功能分类: 生物化工 - 酶及辅酶类
• 分子结构分类: 水解酶 - 作用于除肽键之外的碳-氮键 - 在线性酰胺中
• 中文名称: D-酰化氨基酸水解酶
• 中文别名: D-氨基酰化酶
• 英文名称: N-acyl-D-amino-acid deacylase
• 英文别名: D-aminoacylase
• CAS: 65979-42-2

反应信息

• 作为试剂：
  描述：

  对硝基苯甲醛 、 丙酮 在 咪唑 、 D-酰化氨基酸水解酶 作用下， 以 正辛烷 为溶剂， 反应 48.0h， 生成 4-(p-nitrophenyl)-3-butene-2-one 、 3-Methyl-5-(4-nitro-phenyl)-cyclohex-2-enon
  参考文献：
  名称：

  A tandem Aldol condensation/dehydration co-catalyzed by acylase and N-heterocyclic compounds in organic media

  摘要：

  A tandem Aldol condensation/dehydration of aldehydes and ketones could be performed under D-aminoacylase and N-heterocyclic compounds used as co-catalyst in organic media Some control experiments have been designed to demonstrate that either acylase or N-heterocyclic compounds could not catalyze the tandem reaction The acylase showed the highest activity in the presence of imidazole and has been used to catalyze the tandem Aldol condensation/dehydration between different aldehydes and ketones This method has provided a new strategy to perform the tandem Aldol condensation/dehydration and expanded the application of biocatalysts (c) 2010 Elsevier B V All rights reserved

  DOI：

  10.1016/j.molcatb.2010.09.014