2,5-pyrazenylbis(imidazo[4,5-f][1,10]phenanthroline) | 1268159-40-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: 2,5-pyrazenylbis(imidazo[4,5-f][1,10]phenanthroline)
• 英文别名: 2-[5-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)pyrazin-2-yl]-1H-imidazo[4,5-f][1,10]phenanthroline
• CAS: 1268159-40-5
• 化学式: C₃₀H₁₆N₁₀
• 分子量: 516.524
• InChiKey: AFNDRPFMRNCIJB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  40
• 可旋转键数：
  2
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  135
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  2,5-pyrazenylbis(imidazo[4,5-f][1,10]phenanthroline) 、 ruthenium(II)(1,10-phenethroline)2Cl2*2H2O 、 sodium perchlorate 、 水 、 丙酮 以 乙醇 、 水 为溶剂， 以61%的产率得到[di(ruthenium(II)bis(phenanthroline))(μ-2,5-pyrazenylbis(imidazo[4,5-f][1,10]phenanthroline))](ClO4)4*0.5(CH3)2CO*6H2O
  参考文献：
  名称：

  Metal–metal communication in diruthenium complexes of the bridging ligand bis(imidazo[4,5-f][1,10]phenanthroline)

  摘要：

  A series of diruthenium complexes incorporating bis(imidazo[4,5-f][1,10] phenanthroline) bridging structures were synthesized and their electrochemical properties were investigated. Upon changing the ancillary ligands of one diruthenium complex from 2,2'-bipyridine (bpy) to 1,10-phenanthroline (phen), electrochemical experiments revealed behavior that suggested through-bridge, metal-to-metal communication. By changing the inductive properties of the bridging ligand, the degree of communication could be controlled. The results point toward a hole-type superexchange electron transport mechanism. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.10.016

文献信息

• Metal–metal communication in diruthenium complexes of the bridging ligand bis(imidazo[4,5-f][1,10]phenanthroline)
  作者：P. Srinivasan、R.H. Mason、J.R.G. MacNeil、B.J. MacLean

  DOI：10.1016/j.ica.2010.10.016

  日期：2011.1

  A series of diruthenium complexes incorporating bis(imidazo[4,5-f][1,10] phenanthroline) bridging structures were synthesized and their electrochemical properties were investigated. Upon changing the ancillary ligands of one diruthenium complex from 2,2'-bipyridine (bpy) to 1,10-phenanthroline (phen), electrochemical experiments revealed behavior that suggested through-bridge, metal-to-metal communication. By changing the inductive properties of the bridging ligand, the degree of communication could be controlled. The results point toward a hole-type superexchange electron transport mechanism. (C) 2010 Elsevier B.V. All rights reserved.