1,4:2,3-Diepoxy-1,2,3,4-tetrahydronaphthalin | 585-19-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 四氢化萘
• 英文名称: 1,4:2,3-Diepoxy-1,2,3,4-tetrahydronaphthalin
• 英文别名: 10,12-Dioxatetracyclo[6.3.1.02,7.09,11]dodeca-2,4,6-triene
• CAS: 585-19-3
• 化学式: C₁₀H₈O₂
• 分子量: 160.172
• InChiKey: GHPWZPHGHQJKDD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.7
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  21.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,4:2,3-Diepoxy-1,2,3,4-tetrahydronaphthalin 以50%的产率得到
  参考文献：
  名称：

  LEWARS E. G.; YOUNG A. B., TETRAHEDRON LETT., 1979, NO 50, 4799-4800

  摘要：

  DOI：

文献信息

• [EN] SUBSTITUTED ALKENE DIOLS<br/>[FR] ALCENEDIOLS SUBSTITUES
  申请人：ISIS INNOVATION

  公开号：WO2003018521A1

  公开（公告）日：2003-03-06

  A process for preparing a substituted alkene diol, of the formula (I) wherein n is 0 to 4, R is an unsubstituted or substituted aliphatic or aromatic radical, R1 is hydrogen or an aliphatic or aromatic radical and each of R?2, R3, R4 and R5¿ which are the same or different, is hydrogen or an unsubstituted or substituted aliphatic or aromatic radical, or R?2 and R3¿ together form a divalent radical having 1 to 4 chain carbon atoms which comprises reacting an epoxide of the formula (II) wherein n, R?1, R2, R3, R4 and R5¿ are as defined above with an organolithium compound of the formula: RLi wherein R is as defined above is described. Some of the starting materials and final products are novel.