N-(1-甲基丙基)-1,4-苯二胺 | 10029-30-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: N-(1-甲基丙基)-1,4-苯二胺
• 英文名称: N-sec-butyl-p-phenylenediamine
• 英文别名: N-sec-Butyl-p-phenylendiamin；4-N-butan-2-ylbenzene-1,4-diamine
• CAS: 10029-30-8
• 化学式: C₁₀H₁₆N₂
• 分子量: 164.25
• InChiKey: CMBRHCVQODXRRS-UHFFFAOYSA-N

物化性质

• 沸点：
  294.5±13.0 °C(Predicted)
• 密度：
  1.019±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  38
• 氢给体数：
  2
• 氢受体数：
  2

安全信息

• 海关编码：
  2921590090

反应信息

• 作为反应物：
  描述：

  N-(1-甲基丙基)-1,4-苯二胺 、 2,3-丁二酮 在 copper oxide-chromium oxide 、 苯 作用下， 170.0 ℃ 、9.81 MPa 条件下， 生成 N,N'-bis-(4-sec-butylamino-phenyl)-1,2-dimethyl-ethanediyldiamine
  参考文献：
  名称：

  Anti-ozidants

  摘要：

  公开号：

  US02705224A1
• 作为产物：
  描述：

  N-(4-(sec-butylamino)phenyl)acetamide 在 acid 作用下， 生成 N-(1-甲基丙基)-1,4-苯二胺
  参考文献：
  名称：

  Anti-ozidants

  摘要：

  公开号：

  US02705224A1

文献信息

• [EN] NOVEL LIGHT STABILIZERS<br/>[FR] NOUVEAUX STABILISANTS LUMIÈRE
  申请人：BASF SE

  公开号：WO2015004580A1

  公开（公告）日：2015-01-15

  The present invention relates to symmetric diesters of hydroxyalkyl-4-hydroxy- tetraalkylpiperidine compounds and their use as light stabilizers. They are compatible with and soluble in coating formulations of different polarity.

  本发明涉及羟基烷基-4-羟基-四烷基哌啶化合物的对称二酯及其作为光稳定剂的用途。它们与不同极性的涂料配方相容且可溶。
• Hindered amine light stabilizers based on multi-functional carbonyl compounds and methods of making same
  申请人：——

  公开号：US20020099218A1

  公开（公告）日：2002-07-25

  Compounds and methods of preparing compounds of the formula: RZ—CO—CR a R b —(CR c R d ) n —NH—(Y) m —CO—A  (I) wherein n is an integer from 1 to 15, m is either 0 or 1; R a , R b , R c , and R d are each a hydrogen or a hydrocarbyl group; Y is CO—(CR e R f ) p , wherein R e and R f are each a hydrogen or hydrocarbyl group and p is zero or an integer from 1 to 20 or CO—C 6 H 4 —, wherein the substitution pattern on the phenylene group is an ortho, meta, or para substitution pattern and one or more of the hydrogens of the phenylene group may be substituted by a hydrocarbyl group or a functional group; Z is —O— or —NG—, wherein G is H, C 1 -C 12 alkyl or the radical R; wherein R is 1 wherein R 1 is hydrogen, C 1 -C 18 alkyl, O, OH, CH 2 CN, C 1 -C 18 alkoxy, C-C 18 hydroxyalkoxy, C 5 -C 12 cycloalkoxy, C 5 -C 12 hydroxycycloalkoxy, C 3 -C 6 alkenyl, C 1 -C 18 alkynyl, C 7 -C 9 phenylalkyl, unsubstituted or substituted on the phenyl with 1, 2 or 3 C 1 -C 4 alkyls, or an aliphatic C 1 -C 8 acyl; R 2 is hydrogen, C 1 -C 8 alkyl, or benzyl; R 3 , R 4 , R 5 , and R 6 are each a hydrogen, C 1 -C 8 alkyl, benzyl or phenethyl, or two geminal R moieties, which together with the carbon to which they are attached form a C 5 -C 10 cycloalkyl; and A is either ZR or a hydrocarbyl group, which are useful for stabilizing polymer compositions against photo- and thermal degradation.

  该公式的化合物及其制备方法：RZ—CO—CRaRb—(CRcRd)n—NH—(Y)m—CO—A（I）其中n是1到15之间的整数，m为0或1；Ra、Rb、Rc和Rd分别是氢或烃基团；Y是CO—(CReRf)p，其中Re和Rf分别是氢或烃基团，p为0或1到20之间的整数，或CO—C6H4—，其中苯环上的取代模式为邻位、间位或对位取代模式，苯环的一个或多个氢原子可能被烃基团或功能基团取代；Z是—O—或—NG—，其中G是H、C1-C12烷基或基团R；其中R是1其中R1是氢、C1-C18烷基、O、OH、CH2CN、C1-C18甲氧基、C-C18羟基甲氧基、C5-C12环氧基、C5-C12羟基环氧基、C3-C6烯基、C1-C18炔基、C7-C9苯基烷基，苯基上未取代或取代1、2或3个C1-C4烷基，或脂肪族C1-C8酰基；R2是氢、C1-C8烷基或苄基；R3、R4、R5和R6分别是氢、C1-C8烷基、苄基或苯乙基，或两个共轭的R基，与它们附着的碳形成C5-C10环烷基；A是ZR或烃基团，可用于稳定聚合物组合物对光和热降解的影响。
• [EN] STERICALLY HINDERED AMINE STABILIZER<br/>[FR] AGENT STABILISANT AMINÉ STÉRIQUEMENT ENCOMBRÉ
  申请人：BASF SE

  公开号：WO2011029744A1

  公开（公告）日：2011-03-17

  The present invention relates to oxygen-substituted sterically hindered amines of the formulae I or II: (II), wherein, for example, F2, R3, R5, R6, R8, R9, R11, R12, R13, R14 are n-butyl; Z1 to Z10 are propoxy and R1, R4, R7, R10, R13 are 2,2,6,6-tetramethyl-1 -propoxy-piperidin-4-yl. Compositions comprising compounds of formulae I or Il and an organic material, which is susceptible to oxidative, thermal or light- induced degradation, are further disclosed. Optionally, further additives are contained.

  本发明涉及具有以下式I或II的含氧受位阻胺类化合物：(II)，其中，例如，F2、R3、R5、R6、R8、R9、R11、R12、R13、R14为正丁基；Z1至Z10为丙氧基，R1、R4、R7、R10、R13为2,2,6,6-四甲基-1-丙氧基-哌啶-4-基。还公开了包含具有式I或II的化合物和易于氧化、热降解或光诱导降解的有机材料的组合物。可选地，还包含进一步添加剂。
• [EN] TRIAZINE, PIPERIDINE AND PYRROLIDINE BASED HINDERED AMINE LIGHT STABILIZERS<br/>[FR] STABILISANTS OPTIQUES À AMINE ENCOMBRÉE À BASE DE TRIAZINE, PIPÉRIDINE ET PYRROLIDINE
  申请人：BASF SE

  公开号：WO2015055563A1

  公开（公告）日：2015-04-23

  A compound of the formula (I), wherein R1 and R2 independently of one another are hydrogen, C1-C22alkyl, -Ο·, -OH, -CH2CN, C1-C18alkoxy, C2-C18alkoxy substituted by -OH; C5-C12cycloalkoxy, C3-C6alkenyl, C3-C6alkenyloxy, C7-C9phenylalkyl unsubstituted or substituted on the phenyl by 1, 2 or 3 C1-C4alkyl; or C1-C8acyl; and R3 and R4 independently of one another are C1-C22alkyl or a group of the formula (la), wherein R0 has one of the meanings of R1 and R2.

  式(I)的化合物，其中R1和R2彼此独立地为氢、C1-C22烷基、-Ο·、-OH、-CH2CN、C1-C18烷氧基、被-OH取代的C2-C18烷氧基；C5-C12环烷氧基、C3-C6烯基、C3-C6烯氧基、未被取代或被1、2或3个C1-C4烷基取代的C7-C9苯基烷基；或C1-C8酰基；以及R3和R4彼此独立地为C1-C22烷基或具有式(la)的基团，其中R0具有R1和R2的含义之一。
• [EN] LUBRICANT COMPOSITION<br/>[FR] COMPOSITION LUBRIFIANTE
  申请人：BASF SE

  公开号：WO2017040965A1

  公开（公告）日：2017-03-09

  A lubricant composition includes a base oil present in an amount of greater than 70 parts by weight per 100 parts by weight of the lubricant composition and an antioxidant. The antioxidant has the structure: wherein each X is independently CH or N, so long as at least one X is N, wherein Y is CRR', NR", PR", S, or O, each R, R' and R" is independently H, alkyl or aryl, and R" is alkyl, aryl, alkoxy or aryloxy. Each A is independently an electron donating group. The electron donating group (1) has an atom having at least one lone pair of electrons that is bonded directly to the aromatic ring, (2) is an aryl or alkyl group, or (3) is a hydrogen atom.

  润滑剂组合物包括基础油，其在每100份润滑剂组合物中以大于70份的重量存在，以及抗氧化剂。抗氧化剂具有以下结构：其中每个X独立地为CH或N，只要至少一个X为N，其中Y为CRR'，NR"，PR"，S或O，每个R，R'和R"独立地为H，烷基或芳基，且R"为烷基，芳基，烷氧基或芳氧基。每个A独立地为电子给体基团。电子给体基团（1）具有至少一个孤对电子直接键合到芳香环的原子，（2）是芳基或烷基团，或（3）是氢原子。