butyl-didodecyl-amine | 52770-72-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: butyl-didodecyl-amine
• 英文别名: dilaurylbutyl-amine；N-butyldidodecylamine；n-Butyl-n-dodecyldodecan-1-amine
• CAS: 52770-72-6
• 化学式: C₂₈H₅₉N
• 分子量: 409.783
• InChiKey: AAYBEEVEVAWXAI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.7
• 重原子数：
  29
• 可旋转键数：
  25
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  正丁胺 、 alkaline earth salt of/the/ methylsulfuric acid 在 甲苯 作用下， 生成 N-butyldodecan-1-amine 、 butyl-didodecyl-amine
  参考文献：
  名称：

  Sekera; Marvel, Journal of the American Chemical Society, 1933, vol. 55, p. 348

  摘要：

  DOI：

文献信息

• Catalyst and process for preparing low-viscosity and color-reduced polyisocyanates containing isocyanurate groups
  申请人：DEGUSSA AG

  公开号：US20030187178A1

  公开（公告）日：2003-10-02

  A low-viscosity polyisocyanates and polyisocyanates of reduced color containing isocyanurate groups is prepared by a process comprising, partially trimerizing aliphatic and/or cycloaliphatic diisocyanates in the presence of 0.02 to 2% by weight, based on the weight of the diisocyanate starting material, of at least one trimerization catalyst of formula (I) 1 wherein and wherein substituents A, B, C, D, and E simultaneously or independently of one another are hydrogen, chloro, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, C 1 -C 4 -alkoxycarbonyl, hydroxyl, (R 5 ) 3 SiO—, (R 5 ) 2 N—, —COOH, (R 5 ) 2 N—CH 2 — or phenyl, it being 5 possible for any two adjacent radicals selected from the group A, B, C, D and E to form a conjoint 5- or 6-membered saturated or unsaturated ring which may also include nitrogen, sulfur or oxygen heteroatoms; F is hydrogen, methyl or fluoro; G is hydrogen, methyl or fluoro; R 2 and R 3 simultaneously or independently of one another are C 1 -C 18 -alkyl or R 1 ; R 4 is hydrogen, methyl, C 2 -C 18 -alkyl, C 3 -C 8 -cycloalkyl or C 2 -C 12 -alkoxy; R 5 is C 1 -C 18 -alkyl; Y − is R 6 COO − ; R 6 is hydrogen or a branched or unbranched aliphatic or araliphatic C 1 -C 12 -alkyl radical, and then removing excess diisocyanate from the reaction medium.

  通过部分三聚脂肪族和/或环脂肪族二异氰酸酯在至少一种式(I)的三聚催化剂的存在下进行部分三聚化反应，其中所述催化剂的重量为二异氰酸酯起始物的重量的0.02至2％。所述催化剂的式子如下：其中，取代基A、B、C、D和E可以同时或独立地是氢、氯、C1-C4-烷基、C1-C4-烷氧基、C1-C4-烷氧羰基、羟基、(R5)3SiO-、(R5)2N-、-COOH、(R5)2N-CH2-或苯基，其中任意相邻的两个基团A、B、C、D和E中选择的基团可以形成共轭的5-或6-成员饱和或不饱和环，该环还可以包括氮、硫或氧杂原子；F为氢、甲基或氟；G为氢、甲基或氟；R2和R3可以同时或独立地是C1-C18烷基或R1；R4为氢、甲基、C2-C18烷基、C3-C8环烷基或C2-C12烷氧基；R5为C1-C18烷基；Y-为R6COO-；R6为氢或支链或非支链的脂肪族或芳基脂肪族C1-C12烷基基团，然后从反应介质中去除多余的二异氰酸酯，从而制备含有异氰酸酯基团的低粘度聚异氰酸酯和降低颜色的聚异氰酸酯。
• Process for preparation of diacetal compounds
  申请人：NEW JAPAN CHEMICAL CO.,LTD.

  公开号：EP0421329A2

  公开（公告）日：1991-04-10

  Disclosed is a process for preparing a diacetal compound of the formula (I) such as a dibenzylidene sorbitol, comprising the steps of(i) condensing an aldehyde compound and a polyhydric alcohol in the presence of an acid catalyst and when required a lower alcohol in a hydrophobic organic solvent to give a reaction mixture containing a diacetal compound, (ii) neutralizing the reaction mixture, (iii) washing the mixture with water, (iv) removing the solvent from the mixture thus washed, and (v) drying the residual mass; the process being characterized in that an amine such as, for example, di(C₁₀-C₂₆ alkyl or alkenyl)amine substituted on the nitrogen atom with a C₁-C₄ alkyl group or with a group of the formula (̵C₂H₄O)qH wherein q is an integer of 1 to 4, or a (C₁₄-C₂₂ alkyl or alkenyl)amine substituted on the nitrogen atom with one or two groups of the formula (̵C₂H₄O)qH wherein q is 1 to 4, is added during the period from the formation of the reaction mixture to the completion of the drying step.

  本发明公开了一种制备式(I)的二缩醛化合物（如二亚苄基山梨醇）的工艺，包括以下 步骤：(i)在酸催化剂存在下，必要时在低级醇存在下，在疏水性有机溶剂中缩合醛化合物 和多元醇，得到含有二缩醛化合物的反应混合物；(ii)中和反应混合物；(iii)用水洗涤混合物； (iv)从这样洗涤的混合物中除去溶剂；(v)干燥残留物；该工艺的特征在于胺，例如在氮原子上被 C₁-C₄ 烷基或式 (̵C₂H₄O)qH 的基团取代的二(C₁₀-C₂₆ 烷基或烯基)胺，其中 q 为 1 至 4 的整数、或(C₁₄-C₂₂烷基或烯基)胺，在氮原子上被一个或两个式(̵C₂H₄O)qH（其中 q 为 1 至 4）的基团取代，在反应混合物形成至干燥步骤完成期间加入。
• Katalysator und Verfahren zur Herstellung von niedrigviskosen und farbreduzierten isocyanatgruppenhaltigen Polyisocyanaten
  申请人：Degussa AG

  公开号：EP1229016A2

  公开（公告）日：2002-08-07

  Katalysator und Verfahren zur Herstellung von niedrigviskosen und farbreduzierten isocyanuratgruppenhaltigen Polyisocyanaten.

  生产含有异氰尿酸酯基团的低粘度减色多异氰酸酯的催化剂和工艺。
• CARBON FIBER-REINFORCED THERMOPLASTIC RESIN COMPOSITION, MOLDING MATERIAL, PREPREG, AND METHODS FOR PRODUCING SAME
  申请人：Toray Industries, Inc.

  公开号：EP2765155A1

  公开（公告）日：2014-08-13

  Provided are a carbon fiber-reinforced thermoplastic resin composition excellent in interfacial adhesion between carbon fiber and a thermoplastic resin and excellent in dynamic characteristics, and a molding material, a prepreg, and a method for producing the same. The carbon fiber-reinforced thermoplastic resin composition includes the following components (A) and (B), carbon fiber and a thermoplastic resin; component (A): (A1) a bifunctional or higher functional epoxy compound and/or (A2) an epoxy compound which has a monofunctional or higher epoxy group and has one or more types of functional groups selected from a hydroxyl group, an amide group, an imide group, a urethane group, a urea group, a sulfonyl group and a sulfo group; and component (B): 0.1 to 25 parts by mass, based on 100 parts by mass of the component (A), of at least one reaction accelerator selected from the group consisting of [a] a specific tertiary amine compound (salt) (B1),[b] a specific quaternary ammonium salt (B2) and [c] a quaternary phosphonium salt and/or phosphine compound (B3).

  本发明提供了一种碳纤维增强热塑性树脂组合物，该组合物在碳纤维和热塑性树脂之间具有优异的界面粘合性和动态特性，还提供了一种成型材料、预浸料和生产方法。碳纤维增强热塑性树脂组合物包括以下组分（A）和（B）、碳纤维和热塑性树脂；组分（A）：（A1）双官能团或更高官能团的环氧化合物和/或（A2）具有单官能团或更高官能团的环氧化合物，该环氧化合物具有选自羟基、酰胺基、酰亚胺基、氨基甲酸酯基、脲基、磺酰基和磺酰基的一种或多种官能团；组分（B）：（A1）具有单官能团或更高官能团的环氧化合物，该环氧化合物具有选自羟基、酰胺基、酰亚胺基、氨基甲酸酯基、脲基、磺酰基和磺酰基的一种或多种官能团：以 100 重量份的组分（A）为基数，0.1 至 25 重量份的至少一种反应促进剂，该促进剂选 自以下组别：[a] 特定的叔胺化合物（盐）（B1）；[b] 特定的季铵盐（B2）；[c] 季鏻盐和/或膦化合物（B3）。
• CARBON FIBER MOLDING MATERIAL, MOLDING MATERIAL, AND CARBON FIBER-STRENGTHENING COMPOSITE MATERIAL
  申请人：Toray Industries, Inc.

  公开号：EP2789648A1

  公开（公告）日：2014-10-15

  Provided is a carbon fiber forming raw material having excellent interfacial adhesion between carbon fibers and a thermosetting resin and capable of giving a molded article having excellent mechanical characteristics. The carbon fiber forming raw material is a carbon fiber forming raw material (Z) as a prepreg including sizing agent-coated carbon fibers and a thermosetting resin or a carbon fiber forming raw material (Y) as a forming material that includes sizing agent-coated carbon fibers and has a woven fabric form or a braid form. The sizing agent includes components (A) and (B). The component (A) is an epoxy compound having two or more epoxy groups or two or more types of functional groups. The component (B) is one or more compounds selected from the group consisting of a tertiary amine compound, a tertiary amine salt, a quaternary ammonium salt, a quaternary phosphonium salt, and a phosphine compound. The component (B) is contained in an amount of 0.1 to 25 parts by mass relative to 100 parts by mass of the component (A).

  本发明提供了一种碳纤维成型原料，该原料在碳纤维和热固性树脂之间具有极佳的界面粘附性，并能使成型品具有极佳的机械特性。该碳纤维成型原料是一种碳纤维成型原料（Z），作为预浸料，包括上浆剂包覆的碳纤维和热固性树脂；或者是一种碳纤维成型原料（Y），作为成型材料，包括上浆剂包覆的碳纤维，并具有编织物或编织物的形态。上浆剂包括组分（A）和（B）。组分（A）是具有两个或两个以上环氧基团或两种或两种以上官能团的环氧化合物。组分（B）是一种或多种化合物，选自由叔胺化合物、叔胺盐、季铵盐、季鏻盐和膦化合物组成的组。相对于 100 重量份的组分（A），组分（B）的含量为 0.1 至 25 重量份。

表征谱图