(4-Phenylmethoxy-2-propylphenyl) 6-prop-2-enoyloxynaphthalene-2-carboxylate | 886230-42-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: (4-Phenylmethoxy-2-propylphenyl) 6-prop-2-enoyloxynaphthalene-2-carboxylate
• CAS: 886230-42-8
• 化学式: C₃₀H₂₆O₅
• 分子量: 466.533
• InChiKey: POLBIYKDKOPBEB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.7
• 重原子数：
  35
• 可旋转键数：
  11
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  61.8
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  (4-Phenylmethoxy-2-propylphenyl) 6-prop-2-enoyloxynaphthalene-2-carboxylate 在 aluminum (III) chloride 、 盐酸 、 水 作用下， 以 苯甲醚 为溶剂， 反应 1.0h， 以65.6%的产率得到2-acryloyloxy-6-(2-propyl-4-hydroxyphenyl)oxycarbonylnaphthalene
  参考文献：
  名称：

  EP1944287

  摘要：

  公开号：
• 作为产物：
  描述：

  4-苯基甲氧基-2-丙基苯酚 、 Methylsulfonyl 6-prop-2-enoyloxynaphthalene-2-carboxylate 在 4-二甲氨基吡啶 作用下， 以 四氢呋喃 为溶剂， 反应 1.0h， 生成 (4-Phenylmethoxy-2-propylphenyl) 6-prop-2-enoyloxynaphthalene-2-carboxylate
  参考文献：
  名称：

  POLYMERIZABLE COMPOUND AND COMPOSITION CONTAINING THE POLYMERIZABLE COMPOUND

  摘要：

  公开号：

  EP1813594B1

文献信息

• NOVEL POLYMERIZABLE COMPOUNDS
  申请人：Irisawa Masatomi

  公开号：US20090247782A1

  公开（公告）日：2009-10-01

  A novel polymerizable compound of the present invention is represented by the following general formula (I). Due to the presence of a reactive phenolic hydroxyl group at the end of the molecule, it can be reacted easily with various functional compounds and is useful as a monomer and an intermediate for various functional materials, especially as an intermediate for a polymerizable liquid crystal material. wherein R 1 is a hydrogen atom, a methyl group or a halogen atom; R 2 is an optionally substituted alkyl group having 1 to 6 carbon atoms, an optionally substituted alkoxy group having 1 to 6 carbon atoms, a halogen atom or a cyano group; an alkylene group of each of the alkyl and the alkoxy group may be interrupted by an unsaturated bond, an ether bond, a thioether bond or an ester bond; n is an integer from 0 to 14; and m is 0 or 1.

  本发明的一种新型可聚合化合物由以下通式（I）表示。由于分子末端存在反应性酚羟基，因此可以与各种功能化合物容易地反应，作为各种功能材料的单体和中间体特别是作为可聚合液晶材料的中间体。 其中，R1是氢原子，甲基或卤素原子；R2是具有1至6个碳原子的可选取代烷基，具有1至6个碳原子的可选取代烷氧基，卤素原子或氰基；烷基和烷氧基的每个亚烷基可以通过不饱和键，醚键，硫醚键或酯键中断；n是从0到14的整数；m为0或1。
• EP1972612
  申请人：——

  公开号：——

  公开（公告）日：——
• POLYMERIZABLE LIQUID CRYSTAL COMPOUND HAVING FUSED RING AND HOMO- AND COPOLYMER OF THE POLYMERIZABLE LIQUID CRYSTAL COMPOUND
  申请人：Irisawa Masatomi

  公开号：US20090137761A1

  公开（公告）日：2009-05-28

  A polymerizable liquid crystal compound of formula (1). The compound has high optical (refractive index) anisotropy (Δn), exhibits a liquid crystal phase at room temperature (having a broad liquid crystal phase temperature range) without crystallization, has high solubility in cyclohexanone, methyl ethyl ketone or like organic solvents, exhibits excellent coating properties and orientation properties, and, after polymerization, has high transparency. wherein R 1 and R 2 each represent hydrogen, a methyl group or halogen; rings A to C each represent a benzene ring, a naphthalene ring, etc.; at least one of rings A to C is a fused ring; X, Y, and Z each represent a C1 to C6 alkyl group, etc.; L 1 L 2 , and L 3 each represent —COO—, —OCO—, —O(CH 2 ) j — (j=1 to 8), etc.; n is 0 or 1, and a to c are numbers such that the polymerizable liquid crystal compound may have at least one of X, Y, and Z.
• US7683203B2
  申请人：——

  公开号：US7683203B2

  公开（公告）日：2010-03-23
• US7754912B2
  申请人：——

  公开号：US7754912B2

  公开（公告）日：2010-07-13