1,4-dimethylperhydro-1,4-diazepine-2,3-dithione | 78134-12-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂卓
• 英文名称: 1,4-dimethylperhydro-1,4-diazepine-2,3-dithione
• 英文别名: 1,4-Diazepine-2,3-dithione, 1,4-dimethylperhydro-；1,4-dimethyl-1,4-diazepane-2,3-dithione
• CAS: 78134-12-0
• 化学式: C₇H₁₂N₂S₂
• 分子量: 188.318
• InChiKey: GQXMHPUJSWSLQY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  70.7
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  N,N'-二甲基-1,3-丙二胺 在 劳森试剂 作用下， 以 甲苯 为溶剂， 反应 82.0h， 生成 1,4-dimethylperhydro-1,4-diazepine-2,3-dithione
  参考文献：
  名称：

  Isaksson, Roland; Liljefors, Tommy; Sandstroem, Jan, Journal of Chemical Research, Miniprint, 1981, # 2, p. 664 - 700

  摘要：

  DOI：

文献信息

• ISAKSSON R.; LILJEFORS T.; SANDSTROEM J., J. CHEM. RES. SYNOP., 1981, NO 2, 43, (M 664-682)
  作者：ISAKSSON R.、 LILJEFORS T.、 SANDSTROEM J.

  DOI：——

  日期：——
• Method For Recovery Of Palladium
  申请人：Deplano Paola

  公开号：US20070202025A1

  公开（公告）日：2007-08-30

  Due to its ability to activate small molecules, palladium is increasingly used mainly in catalysis. For example in 2002 the world demand for Pd for the production of catalytic converters for motor vehicles was 64% of the total, equal to 3.08 million oz. Its high cost coupled with the environmental impact of disposal of these spent materials focuses attention on its quantitative recovery by means of economically advantageous industrial processes with low environmental impact. The present invention makes available a method which is easy to apply on an industrial scale for the recovery of palladium in one single step and in mild conditions that meets the above-mentioned industrial requirements. The method uses adducts of N,N′-dialkyl-perhydrodiazepine-2,3-dithione.