(E)-4-methyl-2-(prop-1-enyl)phenol | 65001-69-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: (E)-4-methyl-2-(prop-1-enyl)phenol
• 英文别名: (E)-4-Methyl-2-propenyl-phenol；P-cresol, 2-propentyl-；4-methyl-2-[(E)-prop-1-enyl]phenol
• CAS: 65001-69-6
• 化学式: C₁₀H₁₂O
• 分子量: 148.205
• InChiKey: WPHPAOKIUGOXMM-ONEGZZNKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (E)-4-methyl-2-(prop-1-enyl)phenol 在 (isomerization) 作用下， 以 癸烷 为溶剂， 生成 2-propenyl-4-methylphenol
  参考文献：
  名称：

  2-乙烯基和2-烯丙基苯酚中芳香族氢的转移

  摘要：

  2-乙烯基和2-烯丙基苯酚的芳香性向氢转移

  DOI：

  10.1002/hlca.19770600624
• 作为产物：
  描述：

  2-烯丙基-4-甲基苯酚 在 氢氧化钾 作用下， 以 甲醇 为溶剂， 生成 (E)-4-methyl-2-(prop-1-enyl)phenol
  参考文献：
  名称：

  2-乙烯基和2-烯丙基苯酚中芳香族氢的转移

  摘要：

  2-乙烯基和2-烯丙基苯酚的芳香性向氢转移

  DOI：

  10.1002/hlca.19770600624

文献信息

• One-Pot Synthesis of Functionalized Fused Furans via a BODIPY-Catalyzed Domino Photooxygenation
  作者：Audrey Mauger、Jonathan Farjon、Pierrick Nun、Vincent Coeffard

  DOI：10.1002/chem.201706087

  日期：2018.4.3

  Six‐membered ring fused furans containing a tetrasubstituted tertiary carbon were prepared in an unprecedented one‐pot BODIPY‐catalyzed domino photooxygenation/reduction process. A series of functionalized furans was synthesized from readily available 2‐alkenylphenols and mechanistic studies were performed to account for the domino photosensitized oxygenation.

  通过前所未有的一锅BODIPY催化的多米诺骨牌光氧合/还原工艺制备了含有四取代叔碳的六元环稠合呋喃。从容易获得的2-烯基酚合成了一系列功能化的呋喃，并进行了机理研究以说明多米诺骨牌光敏性氧合作用。
• Process for producing encapsulated product, and encapsulated product
  申请人：Miyabayashi Toshiyuki

  公开号：US20080039550A1

  公开（公告）日：2008-02-14

  The present invention provides a method for producing an encapsulated product in which a core substance having an electric charge on its surface is coated with a wall material comprising a polymer as a main component, the production method comprising at least the following steps (1) to (4): (1) a step of adding an ionic polymerizable surfactant A containing an ionic group having the opposite electric charge to the electric charge on the surface of the core substance, a hydrophobic group and a polymerizable group to an aqueous solvent containing the core substance, followed by mixing, thereby adsorbing the ionic polymerizable surfactant A to the surface of the core substance; (2) a step of adding, after said step (1), an ionic polymerizable surfactant B containing an ionic group having the same or opposite electric charge to the electric charge on the surface of the core substance, a hydrophobic group and a polymerizable group, followed by mixing; (3) a step of adding, after said step (2), a hydrophobic monomer and an oil-soluble polymerization initiator, followed by mixing; and (4) a step of polymerizing the ionic polymerizable surfactant A, the ionic polymerizable surfactant B and the hydrophobic monomer to form the polymer. Also, an encapsulated product obtained by this production method is disclosed.
• Production method of encapsulated material, and encapsulated material
  申请人：Miyabayashi Toshiyuki

  公开号：US20080182917A1

  公开（公告）日：2008-07-31

  A method for producing an encapsulated material in which a core substance having an electric charge on its surface is coated with a wall material mainly comprising a polymer, wherein the wall material polymer is formed by a specific process.
• Encapsulation product, process for producing the same, and ink composition
  申请人：Miyabayashi Toshiyuki

  公开号：US20090062462A1

  公开（公告）日：2009-03-05

  An object of the present invention is to provide an encapsulated product having excellent properties, for example, the core substance is not limited. An encapsulated product comprising a core substance encapsulated with a wall material mainly comprising a polymer, wherein the polymer contacts the core substance through an ionic surfactant a and comprises at least (1) a repeating structural unit derived from an ionic polymerizable surfactant B and/or ionic monomer and (2) a repeating structural unit derived from an ionic polymerizable surfactant C having an electric charge the same as or opposite the electric charge of the ionic surfactant; or an encapsulated product comprising a core substance encapsulated with a wall material mainly comprising a polymer, wherein the polymer comprises a repeating structural unit comprising a hydrophobic monomer and is present between (1) an ionic surfactant b and (2) an ionic surfactant c.
• A METHOD FOR PREPARING A PARTICULATE CATHODE MATERIAL, AND THE MATERIAL OBTAINED BY SAID METHOD
  申请人：LIANG Guoxian

  公开号：US20100323245A1

  公开（公告）日：2010-12-23

  Disclosed are a method for preparing a complex oxide particle composition, the so-prepared particle composition and its use as electrode material. This composition comprises complex oxide particles having a non powdery conductive carbon deposit on at least part of their surface. Its method of preparation comprises nanogrinding complex oxide particles or particles of complex oxide precursors, wherein an organic carbon precursor is added to the oxide particles or oxide precursor particles before, during or after nanogrinding, and pyrolysing the mixture thus obtained; a stabilizing agent is optionally added to the oxide particles or oxide precursor particles before, during or after nanogrinding; and the nanogrinding step is performed in a bead mill on particles dispersed in a carrier solvent.

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