N-丙基-N-(2,3-二羟丙基)全氟正辛基磺酰胺 | 2262-49-9

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 中文名称: N-丙基-N-(2,3-二羟丙基)全氟正辛基磺酰胺
• 中文别名: N-(2,3-二羟基丙基)-N-丙基-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-十七氟-1-辛烷氨磺酸；N-(2,3-二羟基丙基)-N-丙基-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-比氟-1-辛烷氨磺酸；N-正丙基-N-(2,3-二羟丙基)全氟辛基磺酰胺
• 英文名称: N-propyl-N-(2,3-dihydroxypropyl)perfluoro-n-octylsulfonamide
• 英文别名: N-(2,3-dihydroxypropyl)-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-N-propyloctane-1-sulfonamide
• CAS: 2262-49-9
• 化学式: C₁₄H₁₄F₁₇NO₄S
• 分子量: 615.308
• InChiKey: JBUOTOPAJZUSGM-UHFFFAOYSA-N

物化性质

• 沸点：
  150-157 °C(Press: 0.5 Torr)
• 密度：
  1.635±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  37
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  86.2
• 氢给体数：
  2
• 氢受体数：
  22

安全信息

• 危险品标志：
  C,F
• 安全说明：
  S16,S26,S36/37/39,S45
• 危险类别码：
  R11,R34
• 包装等级：
  II
• 危险类别：
  3

文献信息

• MULTIFUNCTIONAL (METH)ACRYLATE MANUFACTURING METHOD
  申请人：TOAGOSEI CO., LTD.

  公开号：US20170204044A1

  公开（公告）日：2017-07-20

  [Problem] The purpose of the present invention is to obtain a multifunctional (meth)acrylate with good yield by an ester exchange reaction of a polyhydric alcohol such as pentaerythritol or dipentaerythritol with a monofunctional (meth)acrylate. [Solution] A multifunctional (meth)acrylate manufacturing method characterized in that when manufacturing a multifunctional (meth)acrylate by an ester exchange reaction of a polyhydric alcohol with a monofunctional (meth)acrylate, catalyst (A) and catalyst (B) are used together. Catalyst (A): One or more kinds of compounds selected from a group consisting of cyclic tertiary amines with an azabicyclo structure or salts or complexes thereof, amidines or salts or complexes thereof, and compounds with a pyridine ring or salts or complexes thereof. Catalyst (B): One or more kinds of compounds selected from a group consisting of zinc-containing compounds.

  [问题] 本发明的目的是通过多元醇（如戊三醇或二戊三醇）与单官能基（甲基）丙烯酸酯的酯交换反应，获得产率高的多功能（甲基）丙烯酸酯。[解决方案] 一种多功能（甲基）丙烯酸酯制备方法，其特征在于，在通过多元醇与单官能基（甲基）丙烯酸酯的酯交换反应制备多功能（甲基）丙烯酸酯时，同时使用催化剂（A）和催化剂（B）。催化剂（A）：选自具有氮杂双环结构的环三胺或其盐或络合物、酰胺或其盐或络合物以及吡啶环或其盐或络合物组成的群中的一种或多种化合物。催化剂（B）：选自含锌化合物组成的群中的一种或多种化合物。
• Multifunctional (meth)acrylate manufacturing method
  申请人：TOAGOSEI CO., LTD.

  公开号：US10035752B2

  公开（公告）日：2018-07-31

  [Problem] The purpose of the present invention is to obtain a multifunctional (meth)acrylate with good yield by an ester exchange reaction of a polyhydric alcohol such as pentaerythritol or dipentaerythritol with a monofunctional (meth)acrylate. [Solution] A multifunctional (meth)acrylate manufacturing method characterized in that when manufacturing a multifunctional (meth)acrylate by an ester exchange reaction of a polyhydric alcohol with a monofunctional (meth)acrylate, catalyst (A) and catalyst (B) are used together. Catalyst (A): One or more kinds of compounds selected from a group consisting of cyclic tertiary amines with an azabicyclo structure or salts or complexes thereof, amidines or salts or complexes thereof, and compounds with a pyridine ring or salts or complexes thereof. Catalyst (B): One or more kinds of compounds selected from a group consisting of zinc-containing compounds.

  [问题]本发明的目的是通过季戊四醇或季戊四醇等多元醇与单官能团（甲基）丙烯酸酯的酯交换反应，获得收率高的多官能团（甲基）丙烯酸酯。 [解]一种多功能（甲基）丙烯酸酯的制造方法，其特征在于通过多元醇与单官能（甲基）丙烯酸酯的酯交换反应制造多功能（甲基）丙烯酸酯时，催化剂（A）和催化剂（B）一起使用。催化剂 (A)：一种或多种化合物，选自具有氮杂双环结构的环状叔胺或其盐或络合物、脒或其盐或络合物以及具有吡啶环的化合物或其盐或络合物组成的组。催化剂 (B)：一种或多种选自含锌化合物组的化合物。
• Curable composition
  申请人：TOAGOSEI CO., LTD.

  公开号：US10611856B2

  公开（公告）日：2020-04-07

  Provided is a method for making a curable composition that has low viscosity and rapid curing ability in the form of thin film, further has excellent resistance to emulsification and preservation stability, and has high hardness in the form of cured film, thereby achieving excellent alkali developability, which is preferably an active energy beam-curable composition, is provided. The made curable composition includes a mixture (A) of a compound having two or more (meth)acryloyl groups, and is obtained by conducting a transesterification reaction of diglycerin and/or glycerin and a compound having one (meth)acryloyl group under the presence of the following catalysts X and Y: catalyst X: a compound that is at least one member selected from the group consisting of cyclic tertiary amine having an azabicyclo structure or a salt or complex thereof, amidine or a salt or complex thereof, and a compound having a pyridine ring or a salt or complex thereof; and catalyst Y: a compound including zinc.

  本发明提供了一种固化组合物的制造方法，该固化组合物以薄膜的形式具有低粘度和快速固化能力，进一步具有优异的抗乳化性和保存稳定性，以固化薄膜的形式具有高硬度，从而实现优异的碱显影性，该固化组合物优选为活性能量束固化组合物。制成的可固化组合物包括具有两个或两个以上（甲基）丙烯酰基的化合物的混合物 (A)，该混合物是在以下催化剂 X 和 Y 的存在下，通过二甘油和/或甘油与具有一个（甲基）丙烯酰基的化合物进行酯交换反应而得到的：催化剂 X：至少一种选自以下组别的化合物：具有氮杂双环结构的环状叔胺或其盐或络合物、脒或其盐或络合物、具有吡啶环的化合物或其盐或络合物；以及催化剂 Y：包括锌的化合物。
• CURABLE COMPOSITION
  申请人：TOAGOSEI CO., LTD.

  公开号：US20180171038A1

  公开（公告）日：2018-06-21

  A curable composition that has low viscosity and rapid curing ability in the form of thin film, further has excellent resistance to emulsification and preservation stability, and has high hardness in the form of cured film, thereby achieving excellent alkali developability, which is preferably an active energy beam-curable composition, is provided. The provided is a curable composition, which includes a mixture (A) of a compound having two or more (meth)acryloyl groups that is obtained by conducting a transesterification reaction of diglycerin and/or glycerin and a compound having one (meth)acryloyl group under the presence of the following catalysts X and Y: catalyst X: a compound that is at least one member selected from the group consisting of cyclic tertiary amine having an azabicyclo structure or a salt or complex thereof, amidine or a salt or complex thereof, and a compound having a pyridine ring or a salt or complex thereof; and catalyst Y: a compound including zinc.
• US5514504A
  申请人：——

  公开号：US5514504A

  公开（公告）日：1996-05-07

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