1-(4-tert-butylstyryl)-naphthalene | 129623-11-6

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 1-(4-tert-butylstyryl)-naphthalene
• 英文别名: 1-[2-(4-Tert-butylphenyl)ethenyl]naphthalene；1-[2-(4-tert-butylphenyl)ethenyl]naphthalene
• CAS: 129623-11-6
• 化学式: C₂₂H₂₂
• 分子量: 286.417
• InChiKey: ZIEMJMJLAJUAQM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  22
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  萘酚 在 4-二甲氨基吡啶 、 1,1'-双(二苯基膦)二茂铁 、 bis(1,5-cyclooctadiene)nickel (0) 、 potassium phosphate 、 三乙胺 作用下， 以 二氯甲烷 、 甲苯 为溶剂， 反应 55.0h， 生成 1-(4-tert-butylstyryl)-naphthalene
  参考文献：
  名称：

  Nickel(0)-Catalyzed Heck Cross-Coupling via Activation of Aryl C–OPiv Bonds

  摘要：

  Using a Ni(dppf) catalyst generated in situ, Heck cross-coupling of aryl pivalates with a variety of olefin partners has been accomplished. This method represents one of the first examples of a C C cross-coupling via activation of a strong C-O bond with a nonorganometallic coupling partner. It enables the transformation of phenol-based substrates into styrenyl products without generation of a halogenated byproduct or the use of expensive triflate groups.

  DOI：

  10.1021/ol203322v

文献信息

• DEUTERATED COMPOUNDS FOR LUMINESCENT APPLICATIONS
  申请人：E I DU PONT DE NEMOURS AND COMPANY

  公开号：US20130299801A1

  公开（公告）日：2013-11-14

  This invention relates to deuterated compounds that are useful in electroluminescent applications. It also relates to electronic devices in which the active layer includes such a deuterated compound.

  本发明涉及到在电致发光应用中有用的氘代化合物。它还涉及到电子器件，其中活性层包括这样的氘代化合物。
• Deuterated compounds for luminescent applications
  申请人：E I DU PONT DE NEMOURS AND COMPANY

  公开号：US09166174B2

  公开（公告）日：2015-10-20

  This invention relates to deuterated compounds that are useful in electroluminescent applications. It also relates to electronic devices in which the active layer includes such a deuterated compound.

  本发明涉及到在电致发光应用中有用的氘代化合物。它还涉及到电子器件，其中活性层包括这样的氘代化合物。
• Nickel(0)-Catalyzed Heck Cross-Coupling via Activation of Aryl C–OPiv Bonds
  作者：Andrew R. Ehle、Qi Zhou、Mary P. Watson

  DOI：10.1021/ol203322v

  日期：2012.3.2

  Using a Ni(dppf) catalyst generated in situ, Heck cross-coupling of aryl pivalates with a variety of olefin partners has been accomplished. This method represents one of the first examples of a C C cross-coupling via activation of a strong C-O bond with a nonorganometallic coupling partner. It enables the transformation of phenol-based substrates into styrenyl products without generation of a halogenated byproduct or the use of expensive triflate groups.