N-乙基全氟辛基磺酰胺基乙基丙烯酸酯 | 423-82-5

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 中文名称: N-乙基全氟辛基磺酰胺基乙基丙烯酸酯
• 中文别名: 2-(N-乙基全氟辛烷磺胺)乙基丙烯酸酯；2-丙烯酸-2-[乙基[(十七氟辛基)-磺酰(基)氨基]-乙基酯]
• 英文名称: 2-(N-ethylperfluorooctanesulfonamido)ethyl acrylate
• 英文别名: N-ethyl perfluorooctane sulfonamidoethyl acrylate；2-[ethyl(1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluorooctylsulfonyl)amino]ethyl prop-2-enoate
• CAS: 423-82-5
• 化学式: C₁₅H₁₂F₁₇NO₄S
• mdl: MFCD00080737
• 分子量: 625.303
• InChiKey: ZAZJGBCGMUKZEL-UHFFFAOYSA-N

物化性质

• 沸点：
  363.6±52.0 °C(Predicted)
• 密度：
  0,793 g/cm3
• 稳定性/保质期：
  在常温常压下稳定，应避免与强氧化剂接触。<?xml:namespace prefix = o ns = "urn:schemas-microsoft-com:office:office" /><o:p></o:p>

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  38
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  72.1
• 氢给体数：
  0
• 氢受体数：
  22

安全信息

• 危险品标志：
  Xi
• 危险类别码：
  R36/37/38
• 安全说明：
  S26,S36/37/39

SDS

Name:	2-(N-Ethylperfluorooctanesulfonamido)ethyl acrylate stabilized Material Safety Data Sheet
Synonym:	2-Propenoic acid, 2-[ethyl[(heptadecafluorooctyl)sulfonyl]amino]ethyl ester; 2-(Ethyl((heptadecafluorooctyl)sulfonyl)amino)ethyl acrylate; monomer for incorporating perfluoroalkyl groups in polymers
CAS:	423-82-5

Section 1 - Chemical Product MSDS Name:2-(N-Ethylperfluorooctanesulfonamido)ethyl acrylate stabilized Material Safety Data Sheet
Synonym:2-Propenoic acid, 2-[ethyl[(heptadecafluorooctyl)sulfonyl]amino]ethyl ester; 2-(Ethyl((heptadecafluorooctyl)sulfonyl)amino)ethyl acrylate; monomer for incorporating perfluoroalkyl groups in polymers

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Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
423-82-5	2-(N-Ethylperfluorooctanesulfonamido)e	100	207-031-0

Hazard Symbols: None Listed.
Risk Phrases: None Listed.

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Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin. The toxicological properties of this material have not been fully investigated.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. May be harmful if inhaled.
Chronic:
No information found.

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Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

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Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Polymerizes readily if not inhibited; heat can initiate reaction.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.

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Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions. Provide ventilation. Do not let this chemical enter the environment.

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Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep refrigerated. (Store below 4C/39F.)

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Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 423-82-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

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Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 0.793
Molecular Formula: C15H12F17NO4S
Molecular Weight: 625.29

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Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures. This material is a monomer and may polymerize under certain conditions if the stabilizer is lost.
Conditions to Avoid:
High temperatures, dust generation, loss of inhibitor.
Incompatibilities with Other Materials:
Strong oxidizing agents, polymerizing initiators.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, oxides of sulfur, carbon dioxide, hydrogen fluoride gas.
Hazardous Polymerization: May occur.

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Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 423-82-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2-(N-Ethylperfluorooctanesulfonamido)ethyl acrylate - Not listed by ACGIH, IARC, or NTP.

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Section 12 - ECOLOGICAL INFORMATION
Other No information available.

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Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

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Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:

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Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 423-82-5: 2
Canada
CAS# 423-82-5 is listed on Canada's NDSL List.
CAS# 423-82-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 423-82-5 is listed on the TSCA inventory.

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为产物：
  描述：

  N-乙基全氟辛基磺酰胺乙醇 、 丙烯酰氯 在 4-二甲氨基吡啶 、 三乙胺 作用下， 以 乙醚 为溶剂， 反应 3.0h， 以78%的产率得到N-乙基全氟辛基磺酰胺基乙基丙烯酸酯
  参考文献：
  名称：

  一种N-乙基全氟辛基磺酰胺基乙基丙烯酸酯 及其制备方法

  摘要：

  本发明涉及含氟表面活性剂制作技术领域，尤其是一种N‑乙基全氟辛基磺酰胺基乙基丙烯酸酯及其制备方法，通过采用廉价易得的N‑乙基全氟辛基磺酰胺乙醇为原料，并加丙烯酰氯进行一步催化酰化反应获得N‑乙基全氟辛基磺酰胺基乙基丙烯酸酯，其产品产率最优能够达到78％，且工艺流程简单，合成路线短，成本低。

  公开号：

  CN106631917B

文献信息

• ANTIMICROBIAL COMPOSITIONS
  申请人：Chisholm Bret Ja

  公开号：US20110195041A1

  公开（公告）日：2011-08-11

  Provided are antimicrobial compositions including at least one biocide covalently bound to a polyurethane. The biocide moiety may comprise triclosan, a triclosan derivative, or a quaternary ammonium salt. Further provided are methods of reducing biofilm formation or microbial growth on a surface, the method including applying to the surface an antimicrobial composition including at least one biocide covalently attached to a polyurethane.

  提供了抗微生物组合物，其中至少包括一种生物杀灭剂共价结合到聚氨酯上。生物杀灭剂部分可以包括三氯生、三氯生衍生物或季铵盐。此外，还提供了一种减少生物膜形成或表面微生物生长的方法，该方法包括将至少一种生物杀灭剂共价连接到聚氨酯的抗微生物组合物涂布到表面。
• Compositions for providing abherent coatings; poly (fluorooyalkylene) urethane acrylates
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0040923A2

  公开（公告）日：1981-12-02

  Radiation-curable compositions for providing solvent-resistant adhesive coatings. The coating comprises a polyfluorinated acrylate or methacrylate, a polyethylenically unsaturated crosslinking agent and a film-forming organic polymer. Several of the poly(fluoro-oxyalkylene)urethane acrylate compounds are novel. Also disclosed is a method of transferring indicia produced by printing, silk-screening, stenciling, electrography, electrophotography or xerography from a support coated with a release agent to virtually any receiver surface. The release agent is a cured composition of the present invention. The indicia are removed with adhesive tape, which is then applied to the receiver, providing a protected image.

  用于提供耐溶剂粘合涂层的辐射固化组合物。涂层由聚氟丙烯酸酯或甲基丙烯酸酯、聚乙烯不饱和交联剂和成膜有机聚合物组成。其中有几种聚（氟氧烷基）聚氨酯丙烯酸酯化合物是新型的。还公开了一种方法，可将通过印刷、丝网印刷、模版印刷、电雕刻、电照相术或 Xerography 技术制作的标识从涂有脱模剂的支撑物转移到几乎任何接收表面。脱模剂是本发明的固化组合物。然后用胶带将标记撕下，再将胶带贴在接收器上，从而提供受保护的图像。
• Antifouling coating for polymerisation reactors
  申请人：Crown Berger Limited

  公开号：EP0307074A2

  公开（公告）日：1989-03-15

  To reduce fouling on reactor surfaces, the surfaces are coated with a protective film of polymeric material of surface energy of less than 15 dynes/cm. The preferred coating materials are polymers of one or more monomer chosen from the 2-(N-alkylperfluorosulphonamido)) alkyl (meth)acrylates or the fluorochemical polymer known as Fluorad (Registered Trade Mark of the 3M company) FC-721.

  为了减少反应器表面的污垢，在表面涂上一层表面能小于 15 达因/厘米的聚合材料保护膜。首选的涂层材料是一种或多种单体的聚合物，这些单体选自 2-（N-烷基全氟磺酰胺）烷基（甲基）丙烯酸酯或称为 Fluorad（3M 公司的注册商标）FC-721 的氟化学聚合物。
• Abrasive elements
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0433031A1

  公开（公告）日：1991-06-19

  An abrasive element comprising a substrate having on a surface thereof particles of an abrasive material secured by a non-metallic binding medium wherein at least the surface of the element between the particles of abrasive material contains a fluorochemical selected from the group consisting of compounds comprising a fluorinated aliphatic group attached to a polar group or moiety and fluoropolymers having a molecular weight of at least 750 and comprising a non-fluorinated polymeric backbone having a plurality of pendant fluorinated aliphatic groups, said aliphatic groups comprising the higher of (a) a minimum of three C-F bonds, or (b) in which 25% of the C-H bonds have been replaced by C-F bonds such that the fluorochemical comprises at least 15% by weight of fluorine. The fluorochemical may be applied as a layer coated over the existing layers of an abrasive element or it may be incorporated into at least the coating formulation which will form the outermost layer of the binding medium. The abrasive elements may be in the form of sheets, blocks, discs, pads, belts etc. The presence of the fluorochemical serves to reduce the loading of the abrading surface in use, thereby extending the working life of the abrasive element.

  一种研磨元件，包括基底，基底表面有由非金属结合介质固定的研磨材料颗粒，其中在研磨材料颗粒之间的元件表面至少含有一种氟化合物，该氟化合物选自以下几组化合物：由连接到极性基团或分子上的含氟脂肪族基团组成的化合物，以及分子量至少为 750 的含氟聚合物，该聚合物由具有多个悬垂含氟脂肪族基团的非含氟聚合物骨架组成，所述脂肪族基团包括以下较高者 (a) 至少三个 C-F 键，或 (b) 其中 25% 的 C-H 键已被 C-F 键取代，因此按重量计，氟化合物中至少含有 15% 的氟。含氟化学品可以是涂覆在现有研磨元件层上的一层，也可以至少与涂层配方结合在一起，形成结合介质的最外层。研磨元件可以是片状、块状、盘状、垫状、带状等。氟化合物的存在可减少使用中研磨表面的负荷，从而延长研磨元件的工作寿命。
• Hydrophobic polymeric membrane composites
  申请人：MILLIPORE CORPORATION

  公开号：EP0561277A1

  公开（公告）日：1993-09-22

  A composite porous membrane is formed from a porous polymeric substrate having its entire surface modified with a cross-linked polymer which results in a hydrophobic and oleophobic surface. The composite membrane retains substantially all of its other original properties. The cross-linked polymer is formed in situ on the polymeric substrate from a reactant system comprising an ethylenically unsaturated monomer having at least one fluoroalkyl group, a cross-linker, and, if needed, a polymerization initiator, dissolved in a nonpolar and or weakly polar solvent system. The membrane substrate saturated with the reactant system is exposed to a suitable energy source to effect polymerization and cross linking of the monomer.

  一种复合多孔膜由多孔聚合物基材形成，该基材的整个表面用交联聚合物改性，从而形成疏水疏油表面。复合膜基本上保留了其原有的所有特性。交联聚合物是由反应体系在聚合物基材上就地形成的，反应体系包括至少有一个氟烷基的乙烯不饱和单体、交联剂和聚合引发剂（如需要），溶解在非极性或弱极性溶剂体系中。饱和反应物体系的膜基质暴露在合适的能量源下，以实现单体的聚合和交联。