N-十四烷基-1,3-丙撑二胺 | 4317-79-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: N-十四烷基-1,3-丙撑二胺
• 中文别名: N-十四基丙二胺
• 英文名称: N-tetradecyl-propanediyldiamine
• 英文别名: N-Tetradecyl-propandiyldiamin；N-tetradecylpropane-1,3-diamine；N-n-tetradecyl-1,3-diaminopropane；N'-tetradecylpropane-1,3-diamine
• CAS: 4317-79-7
• 化学式: C₁₇H₃₈N₂
• 分子量: 270.502
• InChiKey: SSSZZOVUXFLWCQ-UHFFFAOYSA-N

物化性质

• 沸点：
  356.0±10.0 °C(Predicted)
• 密度：
  0.840±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  19
• 可旋转键数：
  16
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  38
• 氢给体数：
  2
• 氢受体数：
  2

安全信息

• 海关编码：
  2921290000

反应信息

• 作为反应物：
  描述：

  6-O-(2,3-Epoxypropyl)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose 、 N-十四烷基-1,3-丙撑二胺 在 氯化铵 作用下， 以 乙醇 为溶剂， 反应 24.0h， 以53%的产率得到6-O-[(R,S)-N-(2-tetradecylamino)(propylamino)propan-2-ol]-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose
  参考文献：
  名称：

  Synthesis and evaluation of antibacterial and antitumor activities of new galactopyranosylated amino alcohols

  摘要：

  Three series of D-galactose derivatives linked to a lipophilic aminoalcohol moiety were synthesized and their antibacterial activity was evaluated against Mycobacterium tuberculosis and representative species of Gram positive and Gram negative bacteria. Five out of the thirteen tested compounds displayed activity against M. tuberculosis, with a minimal inhibitory concentration (MIC) of 12.5 mu g/mL and seven compounds were active against the four bacterial strains tested. The best results were obtained for amino alcohols 10 and 11 against Staphylococcus epidermidis (MIC = 2 mu g/mL). The antitumor activity was evaluated against three tumor cell lines (MCF-7, HeLa and MO59J) and compared to the normal cell line GM07492A. The results showed that the lowest IC50 values were observed for the amino alcohol 16 against MCF-7 (11.9 mu M) and MO59J (10.0 mu M). (C) 2015 Elsevier Masson SAS. All rights reserved.

  DOI：

  10.1016/j.ejmech.2015.11.037
• 作为产物：
  描述：

  十四胺 在 乙醇 、 镍 作用下， 95.0 ℃ 、1.96 MPa 条件下， 生成 N-十四烷基-1,3-丙撑二胺
  参考文献：
  名称：

  Sakakibara et al., Yukagaku/Journal of Japan Oil Chemists' Society, 1957, vol. 6, p. 263,265

  摘要：

  DOI：

文献信息

• [EN] PROCESS FOR PREPARING GUANIDINO-FUNCTIONAL MONOMERS<br/>[FR] PROCÉDÉ POUR LA PRÉPARATION DE MONOMÈRES À FONCTION GUANIDINO
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2014204763A1

  公开（公告）日：2014-12-24

  A process for preparing guanidino-functional, free radically polymerizable compounds comprises (a) combining (1) an amine compound comprising (i) at least one primary aliphatic amino group and (ii) at least one secondary aliphatic amino group, primary aromatic amino group, or secondary aromatic amino group, and (2) a guanylating agent; (b) allowing or inducing reaction of the amine compound and the guanylating agent to form a guanylated amine compound; (c) combining (1) the guanylated amine compound, and (2) a reactive monomer comprising (i) at least one ethylenically unsaturated group and (ii) at least one group that is reactive with an amino group; and (d) allowing or inducing reaction of the guanylated amine compound and the reactive monomer to form a guanidino-functional, free radically polymerizable compound.

  制备胍基功能自由基聚合化合物的过程包括(a)结合(1)包含(i)至少一个主链脂肪氨基团和(ii)至少一个次级链脂肪氨基团、主链芳香胺基团或次级芳香胺基团的胺基化合物和(2)胍基化试剂；(b)允许或诱导胺基化合物和胍基化试剂发生反应以形成胍基化胺基化合物；(c)结合(1)胍基化胺基化合物和(2)包含(i)至少一个乙烯不饱和基团和(ii)至少一个与氨基反应的基团的反应单体；(d)允许或诱导胍基化胺基化合物和反应单体发生反应以形成胍基功能自由基聚合化合物。
• PROCESS FOR PREPARING GUANIDINO-FUNCTIONAL MONOMERS
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20160096802A1

  公开（公告）日：2016-04-07

  A process for preparing guanidino-functional, free radically polymerizable compounds comprises (a) combining (1) an amine compound comprising (i) at least one primary aliphatic amino group and (ii) at least one secondary aliphatic amino group, primary aromatic amino group, or secondary aromatic amino group, and (2) a guanylating agent; (b) allowing or inducing reaction of the amine compound and the guanylating agent to form a guanylated amine compound; (c) combining (1) the guanylated amine compound, and (2) a reactive monomer comprising (i) at least one ethylenically unsaturated group and (ii) at least one group that is reactive with an amino group; and (d) allowing or inducing reaction of the guanylated amine compound and the reactive monomer to form a guanidino-functional, free radically polymerizable compound.

  制备含有胍基官能团、自由基聚合化合物的过程包括：（a）混合（1）一种胺化合物，该胺化合物包括（i）至少一个一级脂肪族氨基团和（ii）至少一个二级脂肪族氨基团、一级芳香族氨基团或二级芳香族氨基团，以及（2）一种胍基化试剂；（b）使胺化合物和胍基化试剂发生反应形成胍基化胺化合物；（c）混合（1）胍基化胺化合物和（2）一种反应单体，该反应单体包括（i）至少一个乙烯基不饱和基团和（ii）至少一个与氨基反应的基团；（d）使胍基化胺化合物和反应单体发生反应形成含有胍基官能团、自由基聚合化合物。
• Dispersion of magnetic particles
  申请人：IMPERIAL CHEMICAL INDUSTRIES PLC

  公开号：EP0158406A1

  公开（公告）日：1985-10-16

  A dispersion of finely divided particles of a magnetic material in an organic liquid containing a dispersant comprising an amine carrying a poly(carbonylalkyleneoxy) chain (PCAO chain) in which the alkylene groups contain up to 8 carbon atoms, or an acid-salt thereof. The dispersion is useful for the preparation of magnetic recording media such as video, audio and computer recording tapes and discs. Certain of the dispersants are novel, especially a polyethyleneimine carrying at least two PCAO chains.

  一种磁性材料细粒在有机液体中的分散体，该液体含有一种分散剂，该分散剂包括一种带有聚（羰基烷氧基）链（PCAO 链）的胺，其中的烷基含有多达 8 个碳原子，或其酸盐。 该分散体可用于制备磁性记录介质，如视频、音频和计算机记录磁带和光盘。 某些分散剂很新颖，特别是一种带有至少两条 PCAO 链的聚乙烯亚胺。
• Thickening compositions and thickened aqueous acid solutions
  申请人：Akzo Nobel N.V.

  公开号：EP0276501A2

  公开（公告）日：1988-08-03

  The invention relates to a thickened aqueous composition incorporating an amine or diamine, carrying at least one nitrogen linked hydrocarbon group which represents a saturated or unsaturated linear or branched alkyl group having at least 10 carbon atoms and preferably 16-24 carbon atoms or an aryl, aralkyl or alkaryl group containing up to 24 carbon atoms, and wherein the optional other nitrogen linked groups are formed by optionally substituted alkyl groups, aryl groups or aralkyl groups or polyalkoxy groups, or wherein the amine is in the form of a heterocyclic ring, con­taining at least two nitrogen atoms, one of which being substituted by amino (lower) alkyl or hydroxy (lower) alkyl, while the ring is further bearing a linear or branched alkyl or alkenyl preferably reacted with fatty acids, or alkenyl group having at least 10 carbon atoms; cumene sulphonate, xylene sulphonate, toluene sulphonate or mixtures thereof, in their acid or salt form; and a weak acid having a pK value > 2,0; and water, wherein optionally one or more cleaning desinfecting and/or odourizing agents may be dissolved or dispersed. The invention also relates to premix compositions composed of above-men­tioned amines and sulphonates, from which the thickened aqueous composi­tions can be prepared by dilution with water or an aqueous solution or suspension and to a process for cleaning non-horizontal surfaces.

  本发明涉及一种含有胺或二胺的增稠水基组合物，胺或二胺含有至少一个氮连接烃基，该烃基代表饱和或不饱和的直链或支链烷基，至少含有 10 个碳原子，最好是 16-24 个碳原子，或芳基、芳烷基或烷芳基，最多含有 24 个碳原子，其中任选的其他氮连接基团由任选取代的烷基形成、其中胺为杂环形式，含有至少两个氮原子，其中一个氮原子被氨基（低级）烷基或羟基（低级）烷基取代，而环进一步含有线性或支链烷基或烯基，最好与脂肪酸反应，或含有至少 10 个碳原子的烯基； 以酸或盐形式存在的磺酸积甲苯酯、磺酸二甲苯酯、磺酸甲苯酯或它们的混合物；以及 pK 值大于 2.0 的弱酸；以及 水，其中可选择性地溶解或分散一种或多种清洁消毒剂和/或除臭剂。 本发明还涉及由上述胺类和磺酸盐组成的预混组合物，可通过用水或水溶液或悬浮液稀释来制备增稠的水性组合物，还涉及一种用于清洁非水平表面的工艺。
• LUBRICATING OIL COMPOSITION
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0394468A1

  公开（公告）日：1990-10-31

  A lubricating oil-composition which is obtained by compounding a base oil with a specific amine and at least one compound selected from among sulfonates, phenates and salicylates is disclosed. This composition is excellent in stain resistance and is favorably used for, particularly, working of bearings or super-finish working.

  本发明公开了一种润滑油组合物，它是由基础油与特定胺和至少一种选自磺酸盐、苯酸盐和水杨酸盐的化合物复合而成。这种组合物具有极佳的抗污性，尤其适用于轴承的加工或超精加工。