trans-bis(N,N-dibutyl-N'-naphthoylthioureato)platinum(II) | 155239-65-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: trans-bis(N,N-dibutyl-N'-naphthoylthioureato)platinum(II)
• CAS: 155239-65-9
• 化学式: C₄₀H₅₀N₄O₂PtS₂
• 分子量: 878.075
• InChiKey: NQTQQRALVMQHLB-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  cis-bis(N,N-dibutyl-N'-naphthoylthioureato)platinum(II) 以 氯仿 为溶剂， 以0%的产率得到trans-bis(N,N-dibutyl-N'-naphthoylthioureato)platinum(II)
  参考文献：
  名称：

  Synthesis and crystal structure of trans-bis(N,N-dibutyl-N′-naphthoylthioureato) platinum(II). First example of trans chelation of N,N-dialkyl-N′-acylthiourea ligands

  摘要：

  N,N-Dibutyl-N'-naphthoylthiourea (HL1) reacted with [PtCl4]2- to yield a mixture of cis- (85%) and trans-[PtL12] (15%); the crystal structure of the latter has been determined and represents the first example of trans chelation of N,N-dialkyl-N'-acylthiourea ligands.

  DOI：

  10.1039/dt9940000785