摘要:
The two independent bis(3,5-dimethylpyrazole)silver(I) cations in crystalline [Ag(C5H7N2)(2)]NO3 display N-Ag-N angles of 175.51 (14) and 174.44 (13)degrees, and an average Ag-N distance of 2.124 (5) Angstrom. The nitrate anion is situated between [Ag(C5H7N2)(2)](+) units and interacts via hydrogen bonds with the NH groups. The two 3,5-dimethylpyrazole ligands are trans about the silver center. Only a small deviation from linearity is observed in the coordination around silver.