[Ag(2-pyS)]_n | 29419-28-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氮杂环化合物
• 英文名称: [Ag(2-pyS)]_n
• 英文别名: (silver(I) pyridine-2-thiolate)n；silver pyridine-2-thiolate；Ag(2-SPy)
• CAS: 29419-28-1
• 化学式: Ag*C₅H₄NS
• 分子量: 218.028
• InChiKey: OLMKPKFMHPVWEJ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.98
• 重原子数：
  8.0
• 可旋转键数：
  0.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  12.89
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  [Ag(S-2-py)(PPh₃)₃] 以 氯仿 为溶剂， 以100%的产率得到[Ag(2-pyS)]_n
  参考文献：
  名称：

  Hemilabile silver(i) complexes containing pyridyl chalcogenolate (S, Se) ligands and their utility as molecular precursors for silver chalcogenides

  摘要：

  使用[AgCl(PPh3)3]和[Ag2(μ-Cl)2(PPh3)4]，合成了一系列含有吡啶硫氧酸盐(S，Se)配体的银三苯基膦配合物。

  DOI：

  10.1039/c5ce00626k

文献信息

• Tunable polymerization of silver complexes with organosulfur ligand: counterions effect, solvent- and temperature-dependence in the formation of silver(I)-thiolate(and/or thione) complexes
  作者：Weiping Su、Maochun Hong、Jiabao Weng、Yucan Liang、Yingjun Zhao、Rong Cao、Zhongyuan Zhou、Albert S.C Chan

  DOI：10.1016/s0020-1693(01)00745-9

  日期：2002.3

  MeCN gave rise to polymeric compounds [Ag(HPyS)2}2(BF4)2]n (1) and [Ag(HPyS)2}2(ClO4)2]n (2) (HPyS=pyridine-2-thione), respectively, while the similar reaction of pyridine-2-thiol with AgNO3 resulted in a polymeric compound [Ag4(HPyS)6}(NO3)4]n (3). X-ray single-crystal diffraction analyses showed that the cations of both 1 and 2 possess a single-metal-atom chain structure but that of 3 is a double-metal-atom

  摘要吡啶-2-硫醇与AgBF4和Ag 在MeCN中的反应生成了高分子化合物[Ag（HPyS）2} 2（BF4）2] n（1）和[Ag（HPyS）2} 2（ClO4） ）2] n（2）（HPyS =吡啶-2-硫酮），而吡啶-2-硫醇与Ag 的相似反应生成了高分子化合物[Ag4（HPyS）6}（NO3）4] n （3）。X射线单晶衍射分析表明1和2的阳离子均具有单金属原子链结构，而3的阳离子均具有双金属原子链结构。1（或2）和3之间的差异表明银-硫酮化合物的聚合反应具有抗衡离子作用。在水的存在下，于0°C在DMF中用 在吡啶中处理吡啶-2-硫醇，生成了一种类似石墨层状的高分子化合物[Ag（SPy）] n（4）（SPy =吡啶-2-硫醇盐）数组的银离子。通过在DMF中浸泡1个月，化合物4可以转化为其异构体[Ag6（SPy）6] n（5）。但是，在室温下，MeCN–H2O（v：v
• Mercapto derivatives of triorganotin Y,C,Y-pincer complexes: Role of Y,C,Y-chelating ligands in a new coordination mode of organotin compounds
  作者：Jana Martincová、Libor Dostál、Jan Taraba、Aleš Růžička、Roman Jambor

  DOI：10.1016/j.jorganchem.2007.04.006

  日期：2007.7

  We report the use of triorganotin fragments R2L1-2ST, containing N,C,N and O,C,O-Iigands L1-2 (L-1 = C6H3(Me2NCH2)(2)-2,6(-), L-2 = C6H3 ((BuOCH2)-Bu-l)(2)-2,6(-)) on stabilization of both thiol-form in R2L1-2 Sn-2-SPy (2-SPy = pyridine-2-thiolate) and thione-form in R2L1-2 Sn(mimt) (mimt = 1-methylimidazole-2-thiolate) of the polar groups. Treatment of ionic organotin compounds [(Me2LSn)-Sn-1](+)[Cl](-)(1) and [Ph2L2 Sn](+)[OTf](-) (2) with appropriate sodium salts Na-2-SPy and Na(mimt) resulted in the isolation of (Me2LSn)-Sn-1-2-SPy (3), Ph2L2 Sn-2-SPy (4), (Me2LSn)-Sn-1(mimt) (5), (Ph2LSn)-Sn-2(mimt) (6). While polar group 2-SPy exists in its thiol-tautomeric form in compounds 3 and 4, the second polar group (mimt) has been stabilized as the thione-tautomeric form by triorganotin fragments R2L1-2 Sn in compounds 5 and 6. The products were characterized by H-1, C-13 and Sn-119 NMR and IR spectroscopy, ESI/MS, elemental analyses and structures of 3, 6 were determined by X-ray diffraction study. The reactivity of compound 4 containing non-coordinated nitrogen atom of 2-SPy polar group towards CuCl and AgNO3 is also reported. The reactions led to isolation of organotin compounds Ph2L2 SnCl (7) and Ph2L2 SnNO3 (8) as the result of polar group transfer. The mechanism of this reaction has been investigated and compounds Ph3Sn-2-SPy (9) and Ph2L2 Sn-4-SPy (10) (4-SPy = pyridine-4-thic late) have been prepared for this purpose. (c) 2007 Elsevier B.V. All rights reserved.
• 10.1002/1521-3773(20000818)39:16<2911::aid-anie2911>3.0.co;2-#
  作者：Su, Weiping、Hong, Maochun、Weng, Jiabao、Cao, Rong、Lu, Shaofang

  DOI：10.1002/1521-3773(20000818)39:16<2911::aid-anie2911>3.0.co;2-#

  日期：——
• Controlled Assembly Based on Multibridging Thiolate Ligands:  New Polymeric Silver(I) Complexes with One-Dimensional Chain and Three-Dimensional Network Structures
  作者：Maochun Hong、Weiping Su、Rong Cao、Wenjian Zhang、Jiaxi Lu

  DOI：10.1021/ic980367t

  日期：1999.2.1

  The polymeric silver(I) thiolate complexes of [Ag-6(mu(3)-SC5H4N)(4)(mu(4)-SC5H4N)(2)](n) (1) and [Ag(mu(2)-SC5H4NH)Cl](n) (2) have been prepared from the controlled assembling reactions of silver chloride and 2-mercaptopyridine. X-ray diffraction analyses show that I has one-dimensional chain structure and 2 has three-dimensional network structure. The coordination geometry of each Ag(I) in 1 is a distorted tetrahedron of S3N, while that in 2 is a tetrahedron of S2Cl2. The sulfur atom of the thiolate ligand in I exhibits either mu(3) or mu(4) bridge linking three or four silver centers.