四氰合硼酸钾 | 261356-49-4

• 物质功能分类: 化学试剂 - 有机试剂 - 硼酸
• 分子结构分类: 有机化合物 - 有机盐
• 中文名称: 四氰合硼酸钾
• 英文名称: Potassium tetracyanoborate
• 英文别名: potassium;tetracyanoboranuide
• CAS: 261356-49-4
• 化学式: C4BKN4
• 分子量: 153.98
• InChiKey: SQFZXQOCCKUPEC-UHFFFAOYSA-N

物化性质

• 熔点：
  430℃
• 溶解度：
  DMSO（少量溶解）、甲醇（少量溶解）、水（少量溶解）

计算性质

• 辛醇/水分配系数(LogP)：
  -3.31
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  95.2
• 氢给体数：
  0
• 氢受体数：
  5

安全信息

• 危险等级：
  6.1

反应信息

• 作为反应物：
  描述：

  bis(dimethylamino)dichloromethane 、 四氰合硼酸钾 在 ice 、 ice water 作用下， 以 水 为溶剂， 25.0~60.0 ℃ 、933.25 Pa 条件下， 反应 3.17h， 以giving 13.4 g of bis(dimethylamino)chlorocarbenium tetracyanoborate as an oil的产率得到Bis(dimethylamino)chlorocarbenium tetracyanoborate
  参考文献：
  名称：

  Process for the preparation of guanidinium salts

  摘要：

  本发明涉及一种制备公式（1）中R具有所述含义，A-为磺酸盐，烷基或芳基硫酸盐，氢硫酸盐，酰亚胺，甲基化合物，羧酸盐，磷酸盐，亚磷酸盐，膦酸盐，硼酸盐，硫氰酸盐，高氯酸盐，氟硅酸盐或硝酸盐的胍盐的两步法制备过程，并涉及该过程的中间化合物。

  公开号：

  US07439395B2

文献信息

• Cyanoborate, Fluoroalkylphosphate, Fluoroalkylborate or Imide Dyes
  申请人：Ignatyev Nikolai (Mykola)

  公开号：US20080275224A1

  公开（公告）日：2008-11-06

  The present invention relates to dyes of the general formula CAT + Y − (I), where Y − is an anion selected from the group of the cyanoborates, fluoroalkylphosphates, fluoroalkylborates or imidates and CAT + is a cation selected from the group of the azine, xanthene, polymethine, styryl, azo, tetrazolium, pyrylium, benzopyrylium, thiopyrylium, benzothiopyrylium, thiazine, oxazine, triarylmethane, diarylmethane, methine, acridine, quinoline, isoquinoline or quaternary azafluorenone dyes, for colouring plastics and plastic fibres, for the preparation of flexographic printing inks, as ball-point pen pastes, as stamp ink, for colouring leather and paper, for use in data acquisition systems, reprography, in ink microfilters, in photogalvanics, laser technology and the photo industry.

  本发明涉及一般公式CAT+Y-（I）的染料，其中Y-是从氰硼酸盐、氟烷基磷酸盐、氟烷基硼酸盐或咪唑盐组中选择的阴离子，CAT+是从吖嗪、黄色素、聚甲烯、苯乙烯、偶氮、四唑、吡啶杂环、苯并吡喃杂环、硫吡喃杂环、苯并硫吡喃杂环、噻吩、噁吩、三芳基甲烷、二芳基甲烷、甲烯、花菁、喹啉、异喹啉或季铵氮杂花菁染料组中选择的阳离子，用于染色塑料和塑料纤维，用于制备凹版印刷油墨，作为圆珠笔浆料、邮票墨水，用于染色皮革和纸张，用于数据采集系统、复印、油墨微滤器、光电镀、激光技术和照相产业。
• Use of ionic liquids with tetracyanoborate anions as a solvents for extraction of alcohols from aqueous solutions
  申请人：Pitner William-Robert

  公开号：US20110071324A1

  公开（公告）日：2011-03-24

  The invention relates to a method for the liquid-liquid extraction of alcohols from aqueous solutions using at least one ionic liquid containing a tetra-cyanoborate anion as solvent.

  本发明涉及一种使用至少含有四氰硼酸盐阴离子作为溶剂的离子液体的液液萃取方法，用于从水溶液中提取醇类物质。
• CYANOBORATE, FLUOROALKYLPHOSPHATE, FLUOROALKYLBORATE OR IMIDE DYES
  申请人：IGNATYEV Nikolai (Mykola)

  公开号：US20110190480A1

  公开（公告）日：2011-08-04

  The present invention relates to dyes of the general formula CAT + Y − (I), where Y − is an anion selected from the group of the cyanoborates, fluoroalkylphosphates, fluoroalkylborates or imidates and CAT + is a cation selected from the group of the azine, xanthene, polymethine, styryl, azo, tetrazolium, pyrylium, benzopyrylium, thiopyrylium, benzothiopyrylium, thiazine, oxazine, triarylmethane, diarylmethane, methine, acridine, quinoline, isoquinoline or quaternary azafluorenone dyes, for colouring plastics and plastic fibres, for the preparation of flexographic printing inks, as ball-point pen pastes, as stamp ink, for colouring leather and paper, for use in data acquisition systems, reprography, in ink microfilters, in photogalvanics, laser technology and the photo industry.

  本发明涉及一般式CAT+Y−（I）的染料，其中Y−是从氰硼酸盐、氟烷基磷酸盐、氟烷基硼酸盐或咪唑盐群中选择的阴离子，CAT+是从偶氮、黄色素、聚甲烯、苯乙烯、偶氮、四唑、吡啶、苯并吡喃、硫吡喃、苯并硫吡喃、噻吩、噁唑、三芳基甲烷、二芳基甲烷、甲烷、吖啶、喹啉、异喹啉或季铵氮芴酮染料群中选择的阳离子，用于着色塑料和塑料纤维，制备柔性版印刷油墨，作为圆珠笔膏、邮票墨水，用于着色皮革和纸张，用于数据采集系统，复印术，墨水微滤器，光电镀技术，激光技术和光学工业。
• Cyanoborate, fluoroalkylphosphate, fluoroalkylborate or imide dyes
  申请人：Merck Patent GmbH

  公开号：US07939644B2

  公开（公告）日：2011-05-10

  The present invention relates to dyes of the general formula CAT+ Y− (I), where Y− is an anion selected from the group of the cyanoborates, fluoroalkylphosphates, fluoroalkylborates or imidates and CAT+ is a cation selected from the group of the azine, xanthene, polymethine, styryl, azo, tetrazolium, pyrylium, benzopyrylium, thiopyrylium, benzothiopyrylium, thiazine, oxazine, triarylmethane, diarylmethane, methine, acridine, quinoline, isoquinoline or quaternary azafluorenone dyes, for colouring plastics and plastic fibres, for the preparation of flexographic printing inks, as ball-point pen pastes, as stamp ink, for colouring leather and paper, for use in data acquisition systems, reprography, in ink microfilters, in photogalvanics, laser technology and the photo industry.

  本发明涉及一般式CAT+ Y-（I）的染料，其中Y-是从氰硼酸盐，氟烷基磷酸盐，氟烷基硼酸盐或咪唑盐组中选择的阴离子，CAT+是从偶氮，黄色素，聚甲烷，苯乙烯，偶氮，四唑，吡啶杂环，苯并吡喃杂环，硫吡喃杂环，苯并硫吡喃杂环，噻吩，噁唑，三芳基甲烷，二芳基甲烷，甲烷，吖啶，喹啉，异喹啉或季铵氮杂花菖蒲素染料组中选择的阳离子，用于着色塑料和塑料纤维，用于制备凸版印刷油墨，作为圆珠笔浆料，作为邮票墨水，用于着色皮革和纸张，用于数据采集系统，复印术，油墨微过滤器，光电镀，激光技术和照相工业。